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81.
The time-differential perturbed angular correlation (TDPAC) experiments involving the 133–482 keV γ-γ cascade in181Ta have been performed in the presence of an external magnetic field along the quantization axis to measure the hyperfine magnetic field experienced by181Ta nuclei at the Hf site in the pseudobinary compounds HfFe2?xSix with x=0.1 and x=0.3. The hyperfine magnetic fields measured at 298 K are Hhf=133.1±12.0 kG in the cubic (C15) Laves phase compound HfFe1.9Si0.1 and Hhf=76.8±7.0 kG in the hexagonal (C14) Laves phase compound HfFe1.7Si0.3. The measured hyperfine fields are discussed within the framework of the Campbell-Blandin model. 相似文献
82.
Auerbach LB Burman RL Caldwell DO Church ED Cochran AK Donahue JB Fazely AR Garvey GT Gunasingha RM Imlay RL Kahrimanis G Louis WC Majkic R Malik A McIlhany KL Metcalf WJ Mills GB Rupnik D Sandberg VD Smith D Somodi RF Stancu I Strossman WD Sung M Tayloe R VanDalen GJ Vernon W Wadia N White DH Yellin S Yi H;LSND Collaboration 《Physical review letters》2004,92(9):091801
We observe a net beam excess of 8.7+/-6.3(stat)+/-2.4(syst) events, above 160 MeV, resulting from the charged-current reaction of nu(micro) and/or nu;(mu) on C and H in the LSND detector. No beam-related muon background is expected in this energy regime. Within an analysis framework of pi(0)-->nu(mu)nu;(mu), we set a direct upper limit for this branching ratio of Gamma(pi(0)-->nu(mu)nu;(mu))/Gamma(pi(0)-->all)<1.6 x 10(-6) at 90% confidence level. 相似文献
83.
Riaz N Anis I Malik A Ahmed Z Aziz-ur-rehman Muhammad P Nawaz SA Choudhary MI 《Chemical & pharmaceutical bulletin》2003,51(3):252-254
Paeonins A and B, new monoterpene galactosides have been isolated from the chloroform-soluble fraction of the roots of Paeonia emodi and showed potent lipoxygenase inhibitory activity. The structures of 1 and 2 have been assigned on the basis of spectral analysis including one- and two-dimensional NMR techniques. 相似文献
84.
85.
Afaq Shagufta Khan Sadia Kazmi Mehdi Hassan Fatima Itrat Malik Abdul Inamullah Farah Farhad Zahid Abbas Tanveer Tareen Rasool Bakhsh 《Chemistry of Natural Compounds》2021,57(2):269-273
Chemistry of Natural Compounds - Armatans A (1) and B (2), new isoflavans, have been isolated from the EtOAc-soluble fraction of the MeOH extract of Colutea armata Hemsl. & Lace, along with... 相似文献
86.
An algorithm has been developed for calculating radii, direction vectors, and coordination numbers (c.n.) for an arbitrary number of coordination spheres (CS) of the diamond lattice. It is established that the space of CS of the diamond lattice has imaginary CS in addition to real ones. The imaginary CS are defined by a direction vector, one of the components of which is an imaginary value. The coordination numbers of such CS are zero. For a great number of tabulated CS, we have studied the hierarchies of structural groups (motifs), forming in the space of coordination spheres and determining the X-ray spectra of lattice CS, the crystallomorphological growth forms of diamond crystals, and the forms of diamond fragmentation induced by thermal destruction and melting. 相似文献
87.
Priya Budhani Sayed Aftab Iqbal Suman Malik Mamta Bhattacharya Liviu Mitu 《Journal of Saudi Chemical Society》2010,14(3):281-285
The present paper deals with the synthesis and characterization of Schiff base complexes of pyrazinamide an antitubercular drug. Metals selected for complexation are copper, silver, gold, zinc, mercury, iron and cobalt. The complexes have been suitably synthesized and isolated in pure powdered form. Analytical data agrees with the compositions M(L), M′(L)2 and M″(L)2·2H2O, respectively where M = Ag, M′ = Cu, Au, Zn and Hg and M″ = Fe and Co, ligand metal ratios were also confirmed by monovariation method and Job’s method of continuous variation. Molar conductance values suggest the non ionic nature of the complexes. The tentative structure assigned to the complexes on the basis of stoichiometry and analytical data were further supported by spectral studies viz; IR, NMR, magnetic susceptibility and electronic spectra. A preliminary attempt has also been made to compare the potencies of metal complexes with parent drug. The Cu and Ag complexes are giving encouraging results. Particle size studies further suggest that the drug molecule undergoes reduction in size on complexation. 相似文献
88.
89.
A variety of phosphorodiamidate compounds were synthesized from the corresponding phosphorodichloridate intermediates and phosphorus oxychloride. These were completely characterized using different spectroscopic methods and single crystal X-ray diffraction studies on one of them. Studies revealed that water in the presence of a mild Lewis acid like ZnCl2 was found to assist the hydrolysis of the P–N linkage. The proof of this concept was effectively realized through the hydrolysis of hexamethylphosphoramide. 相似文献
90.
Magnetic susceptibility, heat capacity and electrical resistivity measurements have been carried out on a new ruthenate, La2RuO5 (monoclinic, space group P21/c) which reveal that this compound is a magnetic semiconductor with a high magnetic ordering temperature of 170 K. The entropy associated with the magnetic transition is 8.3 J/mol K close to that expected for the low spin (S=1) state of Ru4+ ions. The low temperatures specific heat coefficient γ is found to be nearly zero consistent with the semiconducting nature of the compound. The magnetic ordering temperature of La2RuO5 is comparable to the highest known Curie temperature of another ruthenate, namely, metallic SrRuO3, and in both these compounds the nominal charge state of Ru is 4+. 相似文献