An assessment of models for predicting refrigerant characteristics in adiabatic and non-adiabatic capillary tubes

Small vapor compression refrigeration systems incorporate a non-adiabatic capillary tube called a capillary tube-suction line heat exchanger (SLHX) in order to improve performance. The thermodynamic properties of the refrigerant in the capillary tube and suction pipe are influenced by associated phenomena. This study compares various relevant models. Based on the comparison recommended correlations were selected and the simulation results show that the friction factor model has the most dominant.     

Effects of B and P content on structural and magnetic properties of cast iron based amorphous alloys

Mössbauer spectroscopy, DSC and magnetic measurements have been used to study the influence of B and P on structural; magnetic properties and thermal stability of cast iron based alloys. Results reveal that addition of B and P affects appreciably: (1) the crystallization temperature and supercooled liquid region ranging between 690–781 and 53–81 K respectively; (2) the spin texture, disorder and (3) the obtained magnetization parameters. Coercive field values range between 10.09 and 16.37 A/m, with lowest value of 10.09 A/m obtained for Ci_87.82B_12.17. Saturation induction (B _s) values vary between 1.32 and 1.85 T. Highest B _s value of 1.85 T is obtained for the Ci_95.65B_4.32 alloy which is at the edge of glass forming ability, with only 4.32 at.% of boron was added to the cast iron composition. Losses (at 50 Hz and 0.32 kA/m) for the studied samples range between 0.43 and 0.82 W/kg. Lowest losses of 0.43 W/kg was obtained for the Ci_91.3P_4.35B_4.35 alloy. Phosphorous and boron additions, helps in the bulk glass forming ability, suggesting perspective applications of these cheap cast iron based soft magnetic alloys as a substitute of the conventional materials.     

Extension of the GHJW theorem for operator ensembles

The Gisin-Hughston-Jozsa-Wootters theorem plays an important role in analyzing various theories about quantum information, quantum communication, and quantum cryptography. It means that any purifications on the extended system which yield indistinguishable state ensembles on their subsystem should have a specific local unitary relation. In this Letter, we show that the local relation is also established even when the indistinguishability of state ensembles is extended to that of operator ensembles.     

Monolayer Co3O4 Inverse Opals as Multifunctional Sensors for Volatile Organic Compounds

Monolayers of periodic porous Co₃O₄ inverse opal (IO) thin films for gas‐sensor applications were prepared by transferring cobalt‐solution‐dipped polystyrene (PS) monolayers onto sensor substrates and subsequent removal of the PS template by heat treatment. Monolayer Co₃O₄ IO thin films having periodic pores (d≈500 nm) showed a high response of 112.9 to 5 ppm C₂H₅OH at 200 °C with low cross‐responses to other interfering gases. Moreover, the selective detection of xylene and methyl benzenes (xylene+toluene) could be achieved simply by tuning the sensor temperature to 250 and 275 °C, respectively, so that multiple gases can be detected with a single chemiresistor. Unprecedentedly high ethanol response and temperature‐modulated control of selectivity with respect to ethanol, xylene, and methyl benzenes were attributed to the highly chemiresistive IO nanoarchitecture and to the tuned catalytic promotion of different gas‐sensing reactions, respectively. These well‐ordered porous nanostructures could have potential in the field of high‐performance gas sensors based on p‐type oxide semiconductors.     

Quantum Spheres and Projective Spaces as Graph Algebras

 The C ^* -algebras of continuous functions on quantum spheres, quantum real projective spaces, and quantum complex projective spaces are realized as Cuntz-Krieger algebras corresponding to suitable directed graphs. Structural results about these quantum spaces, especially about their ideals and K-theory, are then derived from the general theory of graph algebras. It is shown that the quantum even and odd dimensional spheres are produced by repeated application of a quantum double suspension to two points and the circle, respectively. Received: 31 January 2001 / Accepted: 29 July 2002 Published online: 7 November 2002 RID="*" ID="*" Supported by grant No. R04–2001–000–00117–0 from the Korea Science & Engineering Foundation. RID="**" ID="**" Partially supported by the Research Management Committee of the University of Newcastle.     

Synthesis of novel D-2'-deoxy-2'-C-difluoromethylene-4'-thiocytidine as a potential antitumor agent

[reaction: see text] 2'-Deoxy-2'-C-difluoromethylene-4'-thiocytidine (4) as a potential antitumor agent was synthesized starting from L-xylose via 2-deoxy-2-C-difluoromethylene-4-thiosugar as a key intermediate. An elimination product, 8, was always formed as the major product during removal of the protecting groups under acidic or basic conditions. However, utilizing neutral reaction conditions to remove the protecting groups afforded the desired product 4 exclusively.     

Catalytic Intermolecular Pauson - Khand Reactions in Supercritical Ethylene

Ethylene is not only a substrate, but also a solvent: Catalytic intermolecular Pauson - Khand reactions of terminal alkynes were carried out in supercritical ethylene to provide 2-substituted cyclopentenones in moderate to high yields [Eq. (1)]. Under these conditions, even a low pressure of CO (5 atm) is sufficient for the reaction to take place.