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951.
Sulfur and Nitrogen Codoped Carbon Tubes as Bifunctional Metal‐Free Electrocatalysts for Oxygen Reduction and Hydrogen Evolution in Acidic Media 下载免费PDF全文
Tao Sun Prof. Qiang Wu Yufei Jiang Zhiqi Zhang Lingyu Du Prof. Lijun Yang Prof. Xizhang Wang Prof. Zheng Hu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(30):10261-10261
Invited for the cover of this issue is the group of Qiang Wu and Zheng Hu at Nanjing University. The image depicts sulfur and nitrogen codoped carbon tubes as bifunctional metal‐free electrocatalysts for oxygen reduction and hydrogen evolution in acidic media. Read the full text of the article at 10.1002/chem.201601535 . 相似文献
952.
Beam emittance plays an important role in any accelerator, and it is a main parameter to judge the performance of an accelerator. Emittance optimization is an indispensable part in conditioning and operation of the facility. For a laser-driven high brightness injector, different time structure of the laser pulse has different effects on transverse emittance. In order to compare Gaussian and flat-top laser pulse, systematic simulations of 500 pC have been done. From the simulation results, one can see that flat-top pulse laser will yield smaller minimal transverse beam size and transverse beam emittance than Gaussian pulse laser. 相似文献
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The sorption equilibria of carbon dioxide on three types of silica gel (SG) with different pore size distributions in the presence of water were studied experimentally using a volumetric method at 275?K with pressures from 0 to 3.7?MPa. Both the pore size distribution of the silica gel and the quantity of pre-sorbed water impact the formation of the CO2 hydrates. For wet silicon gel A(SG-A) with water loading ratio of 0.75, the highest CO2 sorption was about 2.5?mmol of CO2 per gram of dry sorbent at 275?K. Similarly, the highest sorption was about 2.7?mmol for wet SG-B with R w =0.81. However, CO2 hydrate did not form on the wet surface of SG-C due to its large pore sizes. 相似文献
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Cobalt‐based metal coordination polymers with 4,4′‐bipyridinyl groups: highly efficient catalysis for one‐pot synthesis of 3,4‐dihydropyrimidin‐2(1H)‐ones under solvent‐free conditions 下载免费PDF全文
Jin‐Hua Wang Gui‐Mei Tang Shi‐Chen Yan Yong‐Tao Wang Shi‐Jie Zhan E Zhang Yu Sun Yuan Jiang Yue‐Zhi Cui 《应用有机金属化学》2016,30(12):1009-1021
Three new metal coordination complexes, namely [Co(BPY)2(H2O)2](BPY)(BS)2(H2O)4 ( 1 ), [Co(BPY)2(H2O)4](ABS)2(H2O)2 ( 2 ) and [Co(BPY)(H2O)4](MBS)2 ( 3 ) (BPY = 4,4′‐bipyridine, BS = phenylsulfonic acid, ABS = p‐aminobenzenesulfonic acid, MBS = p‐methylbenzenesulfonic acid), were obtained under hydrothermal conditions. Complexes 1 , 2 , 3 were structurally characterized using single‐crystal X‐ray diffraction and infrared spectroscopy. All of them display low‐dimensional motifs: complex 1 displays a two‐dimensional structure; and complexes 2 and 3 exhibit a one‐dimensional tape structure. Through strong intermolecular hydrogen bonding interactions and weak packing interactions, all of them further stack to generate a three‐dimensional supramolecular architecture. Catalysts 1 , 2 , 3 were involved in the green synthesis of a variety of 3,4‐dihydropyrimidin‐2(1H)‐ones under solvent‐free conditions through Biginelli reactions. The corresponding catalytic product was obtained in quantitative yields (99%) under eco‐friendly synthesis conditions for the variety of reactions. Catalysts 1 , 2 , 3 exhibit excellent efficiency for the desired product, and their catalytic performance shows the following order: 2 > 1 ≈ 3 , which can be ascribed to the hydrophobic interactions of different phenylsulfonate groups. The catalytic performance for the Biginelli reaction is not only dependent on the selected solvents, but also inversely proportional to the polarities of the solvents. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献