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11.
B. Mukhopadhyay M. Nag S. Laskar S. Lahiri 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(2):415-418
Pleurotus citrinopileatus, a species of edible mushrooms, is widely accepted food component, especially in Indian subcontinent. The accumulating susceptibility
of this edible mushroom species towards long-lived radioisotopes of cesium was studied in controlled laboratory condition
using the 134Cs (T
1/2 = 2.06 y) radioisotope. It was observed that the experimental mushroom species accumulated 134Cs and maximum accumulation took place in the cap portion. The pileus (cap)/stipes (stem) ratio of each 134Cs accumulated mushroom sample was determined and found 2.22±0.74. The protein and fat fractions of the experimental mushroom
species were extracted separately after accumulation of radiocesium and it was found that most of the radiocesium accumulation
occurred in the protein fraction of the mushroom. The mushroom Pleurotus citrinopileatus which is white in color, turned completely black after radiocesium accumulation. The black mushroom so obtained was produced
upto fourth generation by tissue culture method without using any radiocesium further. All the successors were found to be
black indicating a permanent mutation of the mushroom species. 相似文献
12.
Solution polymerization of MMA, with pyridine as the solvent and BZ2O2 and AIBN as thermal initiators, was studied kinetically at 60°C. The monomer exponent varied from 0.45 to 0.91 as [BZ2O2] was increased from 1 × 10?2 to 30 × 10?2 mole/liter in a concentration range of 8.3-4.6 mole/liter for MMA. For AIBN-initiated polymerization the monomer exponent remained constant at 0.69 as [AIBN] varied from 0.4 × 10?2 to 1.0 × 10?2 mole/liter in the same concentration range for MMA. The k2p/kt Value increased in both cases with an increase in pyridine concentration in the system. This was explained in terms of an increase in the kp value, which was due presumably to the increased reactivity of the chain radicals by donor-acceptor interaction between the molecules of solvent pyridine and propagating PMMA radicals and in terms of lowering the kt value for the diffusion-controlled termination reaction due to an increase in the medium viscosity and pyridine content. 相似文献
13.
An estimate of error in an approximate wave function for a stationary state is put forward that does not require any information about the exact state. The measure is sensitive and direct. Parameters embedded in a trial wave function can be varied to minimize this error as well, leading to a variational principle. Such a scheme works nicely for bound states and the more so for Siegert states, for which the standard energy minimization principle does not apply. Pilot calculations on the anharmonic oscillator system and the radial Stark effect in the hydrogen atom reveal the worth of the endeavor. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2004 相似文献
14.
Kinetics of Bz2O2-initiated polymerization of VAC in pyridine at 60° were investigated. The polymerization was significantly retarded by pyridine. The monomer exponent decreased from 2.5 at a relatively low [Bz2O2] (1.0 × 10?2 M) to 2.0 at [Bz2O2] ? 4.0 × 10?2 M. The observed kinetic features were explained on the basis of degradative chain transfer and copolymerization with pyridine. 相似文献
15.
Double percolation effect on the electrical conductivity of conductive particles filled polymer blends 总被引:11,自引:0,他引:11
M. Sumita K. Sakata Y. Hayakawa S. Asai K. Miyasaka M. Tanemura 《Colloid and polymer science》1992,270(2):134-139
Electrical conductivity of carbon black (CB) filled polymer blends which are incompatible with each other was studied as a function of the polymer's blend ratio. Transmission electron microscope (TEM) analysis shows that CB distributes unevenly in each component of a polymer blend. TEM photographs of phase structure of solvent extracted HDPE/PMMA blend and solvent extraction experiments of PMMA/PP blend detect the blend ratio at which the structural continuity of filler rich phase is formed. The electrical conductivity of polymer blends is found to be determined by two factors. One is the concentration of CB in the filler rich phase and the other is the structural continuity of this phase. This double percolation affects the conductivity of conductive particle filled polymer blends. 相似文献
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Atri Mukhopadhyay Raj Kumar Moitra Debashis Mukherjee 《International journal of quantum chemistry》1975,9(3):545-554
We introduce here a new partitioning of the Hamiltonian in calculating pair-correlation energies using many-body perturbation theory, by which we are able to eliminate the off-diagonal particle–hole (p–h) ladders exactly to all orders in the perturbation expansion. In this formulation, the particle states turn out to be different for each distinct pair of hole states in the correlation energy calculation. We have also included the contributions of the diagonal particle–particle (p–p) and hole–hole ladders exactly to all orders. The effect of the off-diagonal p–p ladders has been estimated for each pair by computing the third-, foruth- and fifth-order energies. For highly symmetric systems the present partitioning yields in general symmetry-broken orbitals. Here one may use an average kind of partitioning for all the partners of the degenerate sets, which restores the symmetry and at the same time ensures cancellation of the p–h ladders exactly at the lowest order and approximately at the higher orders. Results are presented for a selection of 6π-electron conjugated systems. The correlation energy for each pair is in excellent agreement with that obtained from a partial CI calculation involving all double excitations from this pair. The advantages of implementing the present scheme in larger systems has been discussed. 相似文献
20.
We show that two simple semiclassical strategies, one based on the Wilson–Sommerfeld rule and the other on the uncertainty principle, yield the exact modified form of the virial theorem for confined systems. An alternative, easier quantum mechanical route to arrive at this result is also sketched. Pilot calculations on confined oscillators reveal decisive trends. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2005 相似文献