Relating the generating functionals in field/antifield formulation through finite field dependent BRST transformation

We study the field/antifield formulation of pure Yang Mills theory in the framework of the finite field dependent BRST transformation. We show that the generating functionals corresponding to different solutions of the quantum master equation are connected through the finite field dependent BRST transformations. We establish this result with the help of several explicit examples.     

Isolation and Characterization of Oviduct-specific Glycoproteins from Ampulla and Isthmus Parts of Cyclic and Acyclic Buffalo for Studying Differential Microenvironment

The present study characterized the glycoproteins synthesized by buffalo oviduct. Scanning electron microscopy analyses of the ampullary and isthmic segments of cyclic and acyclic buffaloes showed ultrastructural variations in ciliated and nonciliated cells. Mucosal proteins were extracted by scrapping of different segments of oviduct and, after centrifugation, the remainder tissues were subjected to establish primary cell culture system of oviduct epithelial cells and conditioned media were prepared. Time- and concentration-dependent effects of trypsinization on the establishment of primary monolayer culture showed that 0.25% trypsin for 1–2 min at 37 °C were the optimal conditions. Total protein content in oviductal tissues and conditioned media was quantified and analyzed by SDS-PAGE which showed marked variation in different segments of the oviduct. Western blot analysis revealed five major oviduct-specific glycoproteins (OGPs) in cyclic oviduct (ampulla and isthmus) with Mw 180, 95, 75, 66 and 35 kDa in the oviduct extract and two glycoproteins with Mw 95 and 66 kDa in conditioned media. However, in acyclic oviduct (ampulla and isthmus), three glycoproteins were immunostained with Mw 180, 95 and 66 kDa in the oviduct extract and one glycoprotein with Mw 66 kDa in conditioned media. Indirect Enzyme-Linked Immuno Sorbent Assay (ELISA) results showed significant differences of OGPs in different segments of cyclic and acyclic buffaloes and, thus, indicative of segmental variation in the synthesis and secretion of glycoproteins. Oviductal extract secretes more amounts of OGPs as compared to the conditioned medium. The role of these OGPs may be defined and exploited for influencing the fertilization process and/or subsequent embryonic development.     

π-Hydrogen bonding wins over conventional hydrogen bonding interaction: a jet-cooled study of indole···furan heterodimer

In this study, we have explored the conformational landscape of the indole···furan dimer in a supersonic jet by using resonant two-photon ionization (R2PI) and IR-UV double-resonance spectroscopic techniques combined with dispersion-corrected density functional theory (DFT) calculations. Only one conformer of the dimer has been observed in the experiment. DFT/B97-D level calculation shows that N-H···π hydrogen-bonded conformer (T') is energetically more stable than the N-H···O hydrogen-bonded conformer (HB). Natural bond orbital (NBO) calculation also shows that the hydrogen-bonding interaction in the HB conformer is very weak. Finally, the structure of the observed dimer has been determined to be tilted T-shaped N-H···π hydrogen-bonded (T') from very excellent agreement between experimental and theoretical N-H stretch frequency. The most significant finding of this study is the first-time observation of a N-H···π bound conformer of a dimer, which wins over a conventional hydrogen-bonded conformer of the dimer.     

Enhancement of hydrogen gas permeability in electrically aligned MWCNT-PMMA composite membranes

The multi-walled carbon nanotube (MWCNT) dispersed polymethylmethacrylate (PMMA) composite membranes have been prepared for hydrogen gas permeation application. Composite membranes are characterized by Raman spectroscopy, optical microscopy, X-ray diffraction, electrical measurements and gas permeability measurements. The effect of electric field alignment of MWCNT in PMMA matrix on gas permeation has been studied for hydrogen gas. The permeability measurements indicated that the electrically aligned MWCNT in PMMA has shown almost 2 times higher permeability for hydrogen gas as compare to randomly dispersed MWCNT in PMMA. The enhancement in permeability is explained on the basis of well aligned easy channel provided by MWCNT in electrically aligned sample. The effect of thickness of membrane on the gas permeability also studied and thickness of about 30 μm found to be optimum thickness for fast hydrogen gas permeates.     

Some common fixed point theorems for Banach operator pairs with applications in best approximation

The ordered pair (T,I) of two self-maps of a metric space (X,d) is called a Banach operator pair if the set F(I) of fixed points of I is T-invariant i.e. T(F(I))⊆F(I). Some common fixed point theorems for a Banach operator pair and the existence of common fixed points of best approximation are presented in this paper. The results prove, generalize and extend some results of Al-Thagafi [M.A. Al-Thagafi, Common fixed points and best approximation, J. Approx. Theory 85 (1996) 318-323], Carbone [A. Carbone, Applications of fixed point theorems, Jnanabha 19 (1989) 149-155], Chen and Li [J. Chen, Z. Li, Common fixed points for Banach operator pairs in best approximations, J. Math. Anal. Appl. 336 (2007) 1466-1475], Habiniak [L. Habiniak, Fixed point theorems and invariant approximation, J. Approx. Theory 56 (1989) 241-244], Jungck and Sessa [G. Jungck, S. Sessa, Fixed point theorems in best approximation theory, Math. Japon. 42 (1995) 249-252], Sahab, Khan and Sessa [S.A. Sahab, M.S. Khan, S. Sessa, A result in best approximation theory, J. Approx. Theory 55 (1988) 349-351], Shahzad [N. Shahzad, Invariant approximations and R-subweakly commuting maps, J. Math. Anal. Appl. 257 (2001) 39-45] and of few others.     

Observation of surface layering in a nonmetallic liquid

Oscillatory density profiles (layers) have previously been observed at the free surfaces of liquid metals but not in other isotropic liquids. We have used x-ray reflectivity to study a molecular liquid, tetrakis(2-ethylhexoxy)silane. When cooled to T/Tc approximately 0.25 (well above the freezing point for this liquid), density oscillations appear at the surface. Lateral order within the layers is liquidlike. Our results confirm theoretical predictions that a surface-layered state will appear even in dielectric liquids at sufficiently low temperatures, if not preempted by freezing.     

Chemically Tailoring the Dopant Emission in Manganese-Doped CsPbCl3 Perovskite Nanocrystals

Doping in perovskite nanocrystals adopts different mechanistic approach in comparison to widely established doping in chalcogenide quantum dots. The fast formation of perovskites makes the dopant insertions more competitive and challenging. Introducing alkylamine hydrochloride (RNH₃Cl) as a promoting reagent, precise controlled doping of Mn^II in CsPbCl₃ perovskite nanocrystals is reported. Simply, by changing the amount of RNH₃Cl, the Mn incorporation and subsequent tuning in the excitonic as well as Mn d–d emission intensities are tailored. Investigations suggested that RNH₃Cl acted as the chlorinating source, controlled the size, and also helps in increasing the number of particles. This provided more opportunity for Mn ions to take part in reaction and occupied the appropriate lattice positions. Carrying out several reactions with varying reaction parameters, the doping conditions are optimized and the role of the promoting reagent for both doped and undoped systems are compared.