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81.
82.
The observed frequency dependent optical response of hole doped cuprate La1.85Sr0.15CuO4 superconductors, has been theoretically analysed. Starting from an effective two-dimensional (2D) interaction potential for superlattice of hole doped cuprates treated as a layered electron gas, the spectral function is formulated. Calculations of the optical conductivity σ(ω) have been made within the two-component scheme: one is the coherent Drude carriers responsible for superconductivity and the other is incoherent motion of carriers from one site to other leads to a pairing between Drude carriers. The approach accounts for the anomalies reported (frequency dependence of optical conductivity) in the optical measurements for the normal state. Estimating the effective mass from specific heat measurement and ε∞ from band structure calculations for the low-energy charge density waves, the model has only one free parameter, the relaxation rate. The frequency dependent relaxation rates are expressed in terms of memory functions, and the coherent Drude carriers from the effective interaction potential lead to a sharp peak at zero frequency and a long tail at higher frequencies, i.e. in the infrared (IR) region. However, the hopping of carriers from one site to other (incoherent motion of doped carriers) yields a peak value in the optical conductivity centred at mid-IR (MIR) region. We find that both the Drude and hopping carriers in the superlattice of cuprates will contribute to the optical process of conduction in the CuO2 planes and shows similar results on optical conductivity in the MIR as well as IR frequency regions as those revealed from experiments. 相似文献
83.
Riaz N Anis I Malik A Ahmed Z Aziz-ur-rehman Muhammad P Nawaz SA Choudhary MI 《Chemical & pharmaceutical bulletin》2003,51(3):252-254
Paeonins A and B, new monoterpene galactosides have been isolated from the chloroform-soluble fraction of the roots of Paeonia emodi and showed potent lipoxygenase inhibitory activity. The structures of 1 and 2 have been assigned on the basis of spectral analysis including one- and two-dimensional NMR techniques. 相似文献
84.
Choudhary MI Nur-E-Alam M Akhtar F Ahmad S Baig I Ondögnii P Gombosurengyin P Atta-ur-Rahman 《Chemical & pharmaceutical bulletin》2001,49(10):1295-1298
Five new peltogynoids, irisoids A-E (1-5), have been isolated from the underground parts of Iris bungei. The structures of the new compounds were established on the basis of spectroscopic methods and were found to be 1,8,10-trihydroxy-9-methoxy-[1]benzopyrano-[3,2-c][2]-benzopyran-7(5H)-one (1), 1,8-dihydroxy-9,10-dimethoxy-[1]benzopyrano-[3,2-c][2]-benzopyran-7(5H)-one (2), 1,10-dihydroxy-8,9-dimethoxy-[1]benzopyrano-13,2-c][2]-benzopyran-7(5H)-one (3), 1,8-dihydroxy-9,10-methylenedioxy-[1]benzopyrano-[3,2-c][2]-benzopyran-7(5H)-one (4), and 1,8,11-trihydroxy-9,10-methylenedioxy-[1]benzopyrano-[3,2-c][2]-benzopyran-7(5H)-one (5). The structure of irisoid B (2) was established unambiguously by X-ray diffraction study. 相似文献
85.
D. Varshney R.N.P Choudhary C. Rinaldi R.S. Katiyar 《Applied Physics A: Materials Science & Processing》2007,89(3):793-798
The polycrystalline samples of Ba-modified Pb(Fe1/2Nb1/2)O3 (i.e., (Pb1-xBax)(Fe1/2Nb1/2)O3 PBFN, with x=0,0.05,0.07) were synthesized by a mechanosynthesis (i.e., high-energy ball milling) route followed by a mixed
oxide method. Structural analysis provides the information on formation of single-phase orthorhombic structure on substitution
of a small amount (x=0.07) of Ba at the Pb-site of Pb(Fe0.50Nb0.50)O3 (PFN). The ferroelectric–paraelectric phase transition in PFN was observed at 383 K, which decreases on increasing Ba-concentration
in PBFN. Detailed studies of dielectric properties of PBFW show the following: (i) diffuse phase transition, (ii) low loss
tangent, (iii) low activation energy, and (iv) low frequency dielectric dispersion. An anomaly in the ac conductivity was
found very close to phase transition temperature. The activation energy is found to decrease from 0.19 to 0.01 eV on increasing
Ba-concentration to 7% (x=0.07). Temperature field-dependent magnetization measurements of all the samples showed antiferromagnetic
transition at ∼15 K (for x=0.07). PBFN sample showed a slight increase in the coercivity (i.e., from 400 Oe (PFN) to 500 Oe
(PBFN, for x=0.07) at 2 K.
PACS 61.10.Nz; 68.37.Hk; 75.50.Ss; 75.60.Ej; 77.22.Ch; 77.22.Gm 相似文献
86.
One-pot three-component Kabachnik-Fields synthesis of α-aminophosphonates with high yields from the reaction between carbonyl compound, primary amine, and substituted phosphite can be carried out in a short period, using H-beta zeolite as a reusable catalyst. 相似文献
87.
Priya Budhani Sayed Aftab Iqbal Suman Malik Mamta Bhattacharya Liviu Mitu 《Journal of Saudi Chemical Society》2010,14(3):281-285
The present paper deals with the synthesis and characterization of Schiff base complexes of pyrazinamide an antitubercular drug. Metals selected for complexation are copper, silver, gold, zinc, mercury, iron and cobalt. The complexes have been suitably synthesized and isolated in pure powdered form. Analytical data agrees with the compositions M(L), M′(L)2 and M″(L)2·2H2O, respectively where M = Ag, M′ = Cu, Au, Zn and Hg and M″ = Fe and Co, ligand metal ratios were also confirmed by monovariation method and Job’s method of continuous variation. Molar conductance values suggest the non ionic nature of the complexes. The tentative structure assigned to the complexes on the basis of stoichiometry and analytical data were further supported by spectral studies viz; IR, NMR, magnetic susceptibility and electronic spectra. A preliminary attempt has also been made to compare the potencies of metal complexes with parent drug. The Cu and Ag complexes are giving encouraging results. Particle size studies further suggest that the drug molecule undergoes reduction in size on complexation. 相似文献
88.
Polycrystalline samples of Fe-modified PLZT (lead lanthanum zirconate titanate) are prepared by a mixed-oxide reaction technique.
The formation of the compound has been confirmed by X-ray powder diffraction studies. The unit cell structure of the material
has been found to be rhombohedral. Fourier-transform infrared reflection (FTIR) spectra have been recorded to correspond the
structural changes associated with the phase formation. The effects of Fe concentration on the microstructure and dielectric
constant of PLZT materials have been investigated. The ferroelectric phase transition of PLFZT materials is studied using
dielectric measurements, which shows a shift in the transition temperature towards the higher-temperature side with increased
Fe ion concentration. The piezoelectric constants of this system are investigated by the same way of changed contents of Fe
ion in the main PLZT compound. The optimum values of Qm, kp, and d33 are 73, 0.32 and 406. The electrical conductivity increases with the increase in Fe ion concentration.
PACS 77.80.Bh; 77.84.Dy; 77.22.Ch; 72.15.Eb; 06.60.Ei; 39.30.+w 相似文献
89.
90.