A monostatic inverse scattering model based on polarization utilisation

The solution of the inverse problem of electromagnetic scattering by smooth, convex shaped, perfectly conducting, 3-dimensional scatterers is analysed. Certain geometrical as well as physical-optics approximations were used to incorporate the concepts of the “Minkowski problem” of differential geometry into the space-time integral solution of electromagnetic scattering to yield the formal solution for the recovery of the surface profile of the scatterer from the scattered field data. Although various efficient solutions for target identification are available, still information contained in polarization-depolarization characteristics of the scatterer is not yet exploited to its full extent. Therefore the underlying assumption in this investigation was based on the fact that the “depolarization characteristics” of the scattered field do necessarily contain information regarding the surface profile of the scatterer.     

2,6‐Diaryl‐4,4‐disubstituted‐4H‐thiopyran: Source for spiro heterocycles

The 1,5‐diaryl‐3,3‐disubstituted‐1,5‐pentanedione on reaction with ammonium acetate, phosphorus pentoxide and phosphorus pentasulfide gave respective 1,4‐dihydropyridine, 4H‐pyran and 4H‐thiopyran. Novel spiro heterocycles have been obtained by the cyclocondensation of 4H‐thiopyran with hydrazine, hydroxylamine, urea and thiourea.     

Estimation of adenosine and its major metabolites in brain tissues of rats using high-performance thin-layer chromatography-densitometry

A new, rapid and sensitive high-performance thin-layer chromatographic (HPTLC) method with densitometry was developed and validated for the concomitant estimation of purines like adenosine (Ade) and its major metabolites, inosine (Ino) and hypoxanthine (Hypoxan) in rat brain tissue preparations. The HPTLC method was chosen in order to generate better resolution and evade the tedious and prolonged sample preparation methods necessarily performed with HPLC methods when analyzing biological samples. In this method the planar chromatography was executed on aluminum plates pre-coated with silica gel 60 F(254). Elution was performed with a two-step gradient mobile phase consisting of solvent A [n-butanol/water/acetonitrile/10% ammonia solution/glacial acetic acid (5:2:4:1:0.5, v/v)] and solvent B [n-butanol/chloroform/acetonitrile/10% ammonia solution/glacial acetic acid (5:4:2:1:0.5, v/v)]. The quantitative analysis of purines was performed based on the peak areas obtained from the reflectance scanning densitometry, performed at 258nm. The spectral scan was done from 200 to 300nm which facilitated the spectral analysis of peaks for purity and spectral matching. The method was validated in terms of linearity, accuracy, precision, sensitivity, selectivity and repeatability. The method was successfully employed to estimate the endogenous purines in discrete regions of rat brain. A novel protocol developed for the tissue preparation utilizing 0.1M HCl and 0.15M NaOH solutions made in 60% (v/v) methanol resulted in well-resolved peaks and high component recoveries. The results for the first time show that this method established for the flexible estimation of Ade, Ino and Hypoxan by planar chromatography has good linearity, accuracy, precision, sensitivity, selectivity and is simple, rapid and moreover, economical to produce maximum resolution in brain tissue preparations.     

Understanding the Robustness of Dynamic model in Large Eddy Simulation

One of the main question faced by the large eddy simulation(LES) users is, why dynamic model works? Many authors have tried to answer this question with little sucess. In the present work we would like to show the insensitiveness of the dynamic model to the externaly introduced variation in the model coefficent, which proves the robustnessof the model. Analytical and physical reasoning for this behaviour is given by simulating the fully developed channel flow case. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

The effect of modeling of velocity fluctuations on prediction of collection efficiency of cyclone separators

The effect of modeling of velocity fluctuations on the prediction of collection efficiency of cyclone separators has been numerically investigated using the Reynolds stress turbulence model (RSTM) and large eddy simulation (LES). The Eulerian–Lagrangian modeling approach of CFD code Fluent 6.3.26 has been employed to simulate the three dimensional, unsteady turbulent gas–solid flows in a Stairmand high efficiency cyclone. The simulated results have been compared with experimental observations available in the literature. The analysis of results shows that the RSTM and the LES have adequately predicted the mean flow field. Results of the present study demonstrate that the LES has good performance on prediction of fluctuating flow field and collection efficiency for each and every particle size. However, the performance of the RSTM is found poor in terms of prediction of velocity fluctuations and collection efficiency, especially for small particles. This relates to the precessing of the vortex core phenomenon, which is resolved more accurately by LES as compared to the RSTM simulation. The results suggest that the prediction of collection efficiency, especially for small particles is greatly influenced by the simulation of velocity fluctuations in cyclones.     

Tribological properties of nanoparticle-laden ultrathin films formed by covalent molecular assembly

The tribological properties of ultrathin films containing nanoparticles encapsulated in immobilized dendrimers are investigated. The films were formed by covalent molecular assembly in supercritical carbon dioxide, and the Au nanoparticles were formed in aqueous solution. End-capping of the terminal amine groups of the dendrimer by fluorinated species resulted in a reduction in the size of the nanoparticles formed. The resulting film structure displayed a lower coefficient of friction when the nanoparticles were formed after fluorination. The observed improvement in the tribological properties is attributed to the reduction in agglomeration of the nanoparticles due to the presence of the fluorine moieties.     

Urea/Thiourea as Ammonia Surrogate: A Catalyst-Free Synthesis of 2-Substituted 2,3-Dihydroquinazolin-4(1H)-ones/Quinazoline-4(3H)-ones

Urea/thiourea have been identified as an effective ammonia surrogate in the construction of quinazolin-4(3H)-one ring. This strategy afforded a simple and catalyst-free synthesis of 2-substituted 2,3-dihydroquinazolin-4(1H)-ones and quinazolin-4(3H)-ones via the reaction of isatoic anhydride and aryl aldehydes in the presence of urea or thiourea in ethanol. The reaction proceeded well to afford the quinazolin-4(3H)-one or its dihydro derivative, depending on the nature of carbonyl compounds employed.