漆树漆酶的催化氧化作用——Ⅳ.二茂铁及其衍生物的酶促氧化

In phosphate buffer-diethylene glycol monobutyl ether(DGBE), the oxidations of ferrocene and 15 derivatives were investigated in the presence of Rhus vernicifera laccase. The results showed that ferrocene and 11 derivatives can be oxidized. The mechanism of Laccase catalyzed oxidation of ferrocene was put forward.     

Undersampled Windowed Exponentials and Their Applications

We characterize the completeness and frame/basis property of a union of under-sampled windowed exponentials of the form

$$ {\mathcal{F}}(g): =\bigl\{ e^{2\pi i n x}: n\ge 0\bigr\} \cup \bigl\{ g(x)e^{2\pi i nx}: n< 0\bigr\} $$

for \(L^{2}[-1/2,1/2]\) by the spectra of the Toeplitz operators with the symbol \(g\). Using this characterization, we classify all real-valued functions \(g\) such that \({\mathcal{F}}(g)\) is complete or forms a frame/basis. Conversely, we use the classical non-harmonic Fourier series theory to determine all \(\xi \) such that the Toeplitz operators with the symbol \(e^{2\pi i \xi x}\) is injective or invertible. These results demonstrate an elegant interaction between frame theory of windowed exponentials and Toeplitz operators. Finally, we use our results to answer some open questions in dynamical sampling, and derivative samplings on Paley-Wiener spaces of bandlimited functions.

     

Periodic solutions of a second order forced sublinear differential equation with delay

In this paper, existence criteria are established for the existence of periodic solutions of a second order sublinear differential equation with delay and forcing function. Our method is based on careful a priori estimation and continuation theorems, and our sublinear condition is an improvement of the boundedness condition in some recent results.     

整体式固相微萃取搅拌棒-分光光度法测定孔雀石绿

以开发新型吸附萃取搅拌棒为目的,利用环氧树脂、二乙基三胺和聚乙二醇（PEG 1540）通过原位逐步聚合反应制备了内封磁芯的搅拌棒.以孔雀石绿（MG）为目标分析物,详细优化了该搅拌棒吸附萃取的实验条件.在搅拌棒转速为450r？min-1和pH值为7的条件下吸附30min,然后用体积比为7：3的乙腈：乙酸铵缓冲溶液（pH 4~5）作为解吸液解吸20min.以紫外-可见分光光度计为检测手段,测定解吸液中MG的含量.该方法在0.01~5μg？mL-1的浓度范围呈现较好的线性关系,精密度和回收率较为满意.     

作动器参数对结构性能的影响和调整受力状态的实施策略模拟

基于规划法研究了作动器各参数对自适应超静定桁架性能的影响。该规划法能够使结构工作状态更合理化。这一方法能够改善自适应结构的工作状态因而提高承载能力。以此为基础，研究了具有作动器的组合杆的有关参数诸如变形上限、刚度和承载力上限对于控制效果的影响。从而为作动器的合理选择提供了理论根据。对于调整作动器变形以控制结构强度的实施策略进行了模拟和分析。该策略包括3部分：1．模拟和分析了“加载、调控、卸载”重复循环直至调控的完成；2．不同作动器按比例同时放大变形直到调控实现；3．多次加载、调控同一次加载、调控结构的等价性。研究表明本文提出的使结构工作状态合理化的调控过程是安全、可靠和灵活的。     

非线性方程组的二次规划解法和应用

给出了非线性方程组的二次规划解法和应用 ,几个算例表明按拟牛顿法出现病态而不收敛 ,采用本法收敛极快。     

自适应结构多工况下强度控制的研究

对自适应超静定桁架结构的强度控制问题进行了研究，把模型从单一工况推广到了多工况，实现了理论的完整性，定义了结构工作状态系数， 分析了作动器的联入对结构强度的影响，利用超静定桁架的耦合特性和作动器的调节功能，把强度控制问题转化为数学规划问题，方法简单有效。