Synthesis and characterization of fullerene nanowhiskers by liquid-liquid interfacial precipitation: influence of C60 solubility

Fullerene nanowhiskers (FNWs) composed of C(60) fullerene molecules were prepared using the liquid-liquid interfacial precipitation (LLIP) method in the carbon-disulfide (CS(2)) and isopropyl alcohol (IPA) system. The electron microscopic images reveal the formation of non-tubular FNWs. The X-ray diffraction (XRD) pattern studies indicate the presence of fcc crystalline structure and unusual triclinic structure in the FNWs. The selected area electron diffraction pattern (SAED) analysis demonstrates the existence of triclinic and electron beam assisted fcc to tetragonal crystalline phase transformation. The formation of triclinic structure might be validated due to the partial polymerization of FNWs at C(60) saturated CS(2)-IPA interface. The high solubility of C(60) in CS(2) solvent system results in partial polymerization of FNWs. The polymerization of fullerene molecules in the FNWs has been further confirmed using Raman spectroscopy.     

Synthesis and optical properties of Co2+ and Ni2+ ions doped β-BaB2O4 nanopowders

Co²⁺ and Ni²⁺ ions doped β-BaB₂O₄ nanopowders have been prepared by co-precipitation method and their structural properties are studied by spectroscopic techniques. Powder XRD data reveals that the crystal structure belongs to monoclinic and the average crystallite size is calculated. Optical absorption spectra data reveal octahedral site symmetry for Co²⁺ and Ni²⁺ ions. Crystal field (Dq) and inter-electron repulsion (B and C) parameters are evaluated for Co²⁺ doped β-BaB₂O₄ nanopowders as Dq=960, B=900 and C=3850 cm^?1 and for Ni²⁺ doped β-BaB₂O₄ nanopowders, Dq=900, B=850 and C=3500 cm^?1. FT-IR spectra showed the characteristic vibrational bands related to BO₃ and BO₄ molecules. Photoluminescence spectra contain the emission bands in ultraviolet and blue regions.     

Copper-catalyzed formation of C-O bonds by direct α-C-H bond activation of ethers using stoichiometric amounts of peroxide in batch and continuous-flow formats

Peroxides and ethers in flow: 2-Carbonyl-substituted phenols and β-ketoesters react safely with ethers in a microreactor environment using a copper catalyst and an organic peroxide (TBHP). This protocol results in unsymmetrical acetal scaffolds not easily available otherwise (see scheme).     

cis‐Dioxomolybdenum(VI) complexes with unsymmetric linear tetradentate ligands: syntheses,structures and bromoperoxidase activities

Reactions of [MoO₂(acetylacetonate)₂], 2‐((2‐(2‐hydroxyethylamino)ethylamino)methyl)‐4‐R‐phenols (H₂Lⁿ, n = 1–5 for R = H, Me, OMe, Cl and Br, respectively) and KOH in 1:1:2 mole ratio in methanol afford a series of complexes having the general formula cis‐[MoO₂(Lⁿ)] ( 1 , 2 , 3 , 4 , 5 ) in 81–86% yields. The complexes have been characterized using elemental analysis, spectroscopy (infrared, UV–visible, and ¹H NMR, ¹³C NMR and ¹³C‐DEPT NMR) and electrochemical measurements. The molecular structures of 1 , 2 , 3 , 4 have been determined using single‐crystal X‐ray crystallography. In each of 1 , 2 , 3 , 4 , the ONNO‐donor 6,5,5‐membered fused chelate rings forming (Lⁿ)²⁻ and the two mutually cis oxo groups assemble a distorted octahedral N₂O₄ coordination sphere around the metal centre. In the crystal lattice, each of 1 , 2 , 3 , 4 forms a one‐dimensional infinite chain structure via intermolecular N  H⋅⋅⋅O hydrogen bonding interactions. In cyclic voltammograms, the diamagnetic complexes display an irreversible metal‐centred reduction in the potential range −0.73 to −0.88 V (vs Ag/AgCl). The physicochemical data are consistent with a very similar gross molecular structure for all of 1 , 2 , 3 , 4 , 5 . All the complexes exhibit decent bromoperoxidase activities and are also able to effectively catalyse benzoin and methyl(phenyl)sulfide oxidation reactions. Copyright © 2015 John Wiley & Sons, Ltd.     

Local surface skimming longitudinal wave velocity and residual stress mapping

Local variation in surface skimming longitudinal wave (SSLW) velocity has been measured using a scanning acoustic microscope. A very narrow width electrical impulse has been used to excite the transducer of the acoustic lens. This permits the separation of the SSLW signal from the direct reflected signal in the time domain. A simple method of measuring the time delay between the directly reflected signal and the SSLW signal at two defocuses has been utilized for the local measurement of SSLW velocity. The variation in the SSLW velocity measured over an area of the sample is scaled and presented as an image. The method has been implemented to image the variation of the SSLW velocity around a crack tip in a sample of Ti-6Al-4V. Since the SSLW velocity is known to change linearly with the stress, the SSLW velocity image is considered as a representation of the image of stress around the crack tip. Local stress variation in the same region of the crack tip is directly measured using x-ray diffraction. The SSLW velocity image is compared with the x-ray diffraction stress image. The contrast in the two images, spatial resolution, and the penetration depth into the sample of acoustic waves and x rays are discussed.     

On a continued fraction of order 12

We present some new relations between a continued fraction U(q) of order 12 (established by M. S. M. Naika et al.) and U(q ⁿ ) for n = 7, 9, 11, 13:     

Synthesis and molecular docking studies of novel 1,2,3-triazole ring-containing 4-(1,4,5-triphenyl-1H-imidazol-2-yl)phenol derivatives as COX inhibitors

Research on Chemical Intermediates - A series of novel 3-phenyl-1-(4-(4-((4-(1,4,5-triphenyl-1H-imidazol-2-yl)phenoxy)methyl)-1H-1,2,3-triazol-1-yl)phenyl)prop-2-en-1-one derivatives 6a–j...     

β,β′‐Bipyrrole Fusion‐Driven cis‐Bimetallic Complexation in Isomeric Porphyrin

An unprecedented cis‐bimetallic complex of dinaphthoporphycene (DNP), namely [Pd₂(μ‐DNP)(μ‐OAc)₂], is reported. The most striking feature of this complex is that two palladiums coordinate to the macrocycle on the same side and are closely held together (Pd? Pd: 2.67 Å) by two bridging acetate ligands exhibiting significant metal–metal bonding interaction (bond order 0.18 evaluated by NBO analysis). Interestingly, replacing acetate with acetylacetonate (acac) could stabilize an unusual mono‐palladium complex of DNP, where Pd coordinates unsymmetrically to two ring Ns above the macrocyclic plane, as well as coordinating with two Os of the acac ligand. Remarkably, the rigid DNP core displays enhanced complexation induced aromaticity (as per NICS and HOMA analysis), despite undergoing severe core deformation during complexation with metal ion(s) as noticed from their solid‐state structures.     

Bivariate q-Bernstein-Schurer-Kantorovich Operators

Results in Mathematics - The purpose of this paper is to construct a bivariate generalization of a new kind of Kantorovich type q-Bernstein-Schurer operators. We give the rate of convergence by...