Competition between hydrogen bonding and dispersion interactions in the indole···pyridine dimer and (indole)2···pyridine trimer studied in a supersonic jet

Structures of the indole···pyridine dimer and (indole)2···pyridine trimer have been investigated in a supersonic jet using resonant two-photon ionization (R2PI) and IR-UV double resonance spectroscopic techniques combined with quantum chemistry calculations. R2PI spectra of the dimer and the trimer recorded by electronic excitation of the indole moiety show that the red-shift in the band origin of the dimer with respect to the 0(0)(0) band of the monomer is larger compared to that of the trimer. The presence of only one conformer in the case of both the dimer and the trimer has been confirmed from IR-UV hole-burning spectroscopy. The structures of the dimer and the trimer have been determined from resonant ion dip infrared (RIDIR) spectra combined with ab initio as well as DFT/M05-2X and DFT/M06-2X calculations. It has been found that the dimer, observed in the experiment, has a V-shaped geometry stabilized by N–H···N and C–H···N hydrogen bonding interactions, as well as C–H···π and π···π dispersion interactions. The geometry of the trimer has been found to be a cyclic one stabilized by N–H···N, N–H···π, C–H···π, and C–H···N interactions. The most important finding of this current study is the observation of the mixed dimer and trimer, which are stabilized by hydrogen bonding as well as dispersion interactions.     

Bogomolov restriction theorem for Higgs bundles

Let (E,θ) be a stable Higgs bundle of rank r on a smooth complex projective surface X equipped with a polarization H. Let C⊂X be a smooth complete curve with [C]=n⋅H. If where , then we prove that the restriction of (E,θ) to C is a stable Higgs bundle. This is a Higgs bundle analog of Bogomolov's restriction theorem for stable vector bundles.     

Soliton interaction control through dispersion and nonlinear effects for the fifth-order nonlinear Schrödinger equation

Nonlinear Dynamics - Optical fiber communication has developed rapidly because of the needs of the information age. Here, the variable coefficients fifth-order nonlinear Schrödinger equation...     

Wobbling phenomena with logarithmic law nonlinear Schrödinger equations for incoherent spatial Gaussons

We apply the equivalence particle principle to several nonlinear Schrödinger equations (NLSEs) that model the propagation of a spatial beam with logarithmic law nonlinearity. Using this principle, expressions for acceleration, spatial frequency, spatial period and other variables for a spatial soliton can be derived from the solution of the homogenous NLSE with logarithmic law nonlinearity. These results agree well with numerical simulations of the perturbed NLSE. We show that if the expression of the acceleration is bounded this means the spatial soliton propagates with a swing effect.     

On symmetries,reductions, conservation laws and conserved quantities of optical solitons with inter-modal dispersion

This paper studies the compressional dispersive Alfvén (CDA) waves where Noether symmetries will be calculated from which the corresponding conservation laws will be obtained via Noether's theorem. Furthermore, one case of double reduction is performed via the association of a conserved vector with a Noether symmetry (with zero gauge). The conserved quantities of optical solitons in the presence of intermodal dispersion that is governed by the perturbed nonlinear Schrödinger's equation with Kerr law nonlinearity. The invariance-multiplier method is adopted to carry out the analysis, from which the conserved densities are then retrieved. Finally, the conserved quantities are obtained using the 1-soliton solution of the governing equation.     

Analysis of BPSK homodyne receivers based on modified balanced optical phase-locked loop in the presence of non-negligible loop propagation delay

Optical homodyne receivers based on modified balanced optical phase-locked loop is analyzed taking into account loop propagation delay. This modified loop contains all the components of a standard BOPLL in conjunction of an additional phase modulator. This modified loop offers a much improved tracking performance and also shows good improvements in the reduction performance over previously reported methods, like, relaxed line-width requirement and improved lock-in range. This study for the first time shows the imperfect-phase-recovery-induced power penalty as a function of laser line-width with the optimum phase deviations in the presence of non-negligible loop propagation delay. It is found that in order to maintain a 10⁻¹⁰ BER system performance with ξ = 1, R = 1 A/W, P_R = −53 dBm, Δυ = 1 MHz, phase modulator sensitivity K_PM = 10 rad/V and 10° phase deviation between the two transmitted bits, the loop delay must be kept below 3 ns. Further, the required line-width with the non-negligible loop delay time is evaluated and found to be (2.1 × 10⁻³)/τ, where τ (s) is the loop delay. This number corresponds to BER = 10⁻¹⁰, imperfect phase recovery power penalty of 1 dB and phase modulator sensitivity K_PM = 20 rad/V.     

Experimental gravity induced coexistence curve of methyl fluoride near the critical point

Abstract

The top part of the coexistence curve of methyl fluoride in the critical region has been determined first by direct observation of the disappearance of the meniscus of the fluid situated in a high-pressure light scattering cell and subsequently from the measured maximum depolarization ratio of an appreciable number of isochores close to the critical point. The experimental data obtained from direct observations yield a coexistence curve which nearly coincides with that found recently from pVT measurements. However, the data obtained from light scattering experiments describe a gravity induced coexistence curve which lies above the previous one and which shows a minimum at the critical point. The complete experimental data have been used to evaluate the critical parameters p_c, ρ_c and T_c and the critical exponent β.     

Ultraslow solitons due to large quintic nonlinearity in coupled quantum well structures driven by two control laser beams

In this paper, we have shown the existence of large amounts of quintic nonlinearity in asymmetric three-coupled quantum wells, which arise due to a probe pulse and two controlling laser beams. The possibilities of generation and propagation of ultraslow bright optical solitons in these systems have been examined in situations of both Kerr and quintic nonlinearities. We have also demonstrated numerically that these solitons are stable. The modulation instability of a continuous or quasi-continuous wave probe beam has been also investigated and the role of quintic nonlinearity in suppressing this instability has been addressed.     

Simple technique for alignment of a dispersive ring laser cavity

A simple technique for the alignment of a dispersive ring cavity consisting of a reflection-grating and two mirrors is described. Lasing on different rotational–vibrational transitions of CO₂ molecule is achieved in the ring configuration.     

Sub-barrier fission fragment angular distributions for the system19F+232Th

The measurements of fission fragment angular distributions for the system¹⁹F+²³²Th have been extended to the sub-barrier energies of 89.3, 91.5 and 93.6 MeV. The measured anisotropies, within errors are nearly the same over this energy region. However, the deviation of the experimental values of anisotropies from that of standard statistical model predictions increases as the bombarding energy is lowered.