Perturbative Pion Wave Function in Coherent Pion-Nucleon Di-Jet Production

A perturbative QCD treatment of the pion wave function is applied to computing the scattering amplitude for coherent high relative momentum di-jet production from a nucleon.     

A Luminescent Zn(Ⅱ) Supramolecular Coordination Polymer Constructed from 3,4-Thiophenedicarboxylic Acid and Flexible Benzimidazole-based Connector

A new luminescent coordination polymer [Zn(tdc)(pbim)]n 1(tdc = 3,4-thiophenedicarboxylate, pbim = 1,3-bis(benzimidazol-1ˊ-yl)propane) has been synthesized under hydrothermal conditions. The compound crystallizes in monoclinic system, space group P21/c with a = 8.4840(9), b = 16.4913(17), c = 14.9234(16) A, β = 95.8870(10)°, V = 2077.0(4) A3, Z = 4, Mr = 511.84, Dc = 1.637 Mg/m3, μ = 1.324 mm-1, F(000) = 1048, the final R = 0.0361 and w R = 0.0824 for 3656 observed reflections with I 2(I). Structural analyses reveal that 1 exhibits a onedimensional(1D) double chain, which is further connected into a two-dimensional(2D) supramolecular architecture by π-π stacking interactions. The results indicate that H2 tdc and pbim ligand are effective building blocks in constructing polymers with diverse architecture. Solid state properties for 1, such as infrared spectroscopy, elemental analyses, thermal stability and luminescent property, have also been investigated.     

DFT Study on the Heterofullerene C48O12 with Rare Th Symmetry

The molecule with T_h symmetry is rare. A novel C60-like molecule C48O12 with rare Th symmetry has been studied at the B3LYP/6-31G(d) level of theory. Its structural, electronic, vibrational, NMR, and thermodynamic properties have been calculated at the B3LYP/6-31G(d) level of theory. Vibrational modes have been assigned according to their symmetry. There are 73 independent vibrational modes: 22 IR-active modes with T u symmetry and 37 Raman-active modes with Ag , Eg and Tg symmetry, respectively. The heat of formation has been calculated by using isodesmic reactions, 765.7 kJ mol-1 . According to the heat of formation and the HOMO-LUMO gap, C48O12 with rare Th symmetry is more stable than C60 .     

3,5-二硝基苯甲酸冰片酯的合成及结构表征

冰片在中药中被广泛应用。利用前药原理,对冰片母体进行修饰,以冰片和3,5-二硝基苯甲酸为原料,以对甲苯磺酸为催化剂,合成了3,5-二硝基苯甲酸冰片酯,目标化合物的结构经FT-IR、13C NMR、1H NMR和元素分析加以确证。该化合物具有一定的研究开发价值。     

静电陀螺仪MUM全姿态读取的原理及其误差分析

研究了采用同步解调法实现静电陀螺仪质量不平衡调制(MUM)全姿态读取的原理,讨论了影响读取精度的因素,分析了各电极轴转子位移测量电路比例因子不一致和电极轴不正交造成的读取误差.研究表明,某轴测量通道1%的比例因子偏差将造成约17′的读取姿态误差,电极轴不正交造成的读取误差与不正交的程度约在同一数量级.应用中必须通过建立读取误差补偿模型,并进行实时补偿来提高MUM全姿态读取的精度.     

电流比较仪电桥在静电陀螺转子位移测量中的应用

用耦合电感原理研究了电流比较仪电桥非平衡测量的原理及特性,导出了在不同激励信号(电压或电流)和不同输出信号(电压或电流)情况下电桥测量输出的表达式,并据此提出了现有静电陀螺转子位移测量电路的改进措施.研究表明,采用电流输出模式时,变压器的电感大小对检测结果没有影响,且能消除后续电路输入端寄生电容的影响;电流激励、电流输出模式具有最好的综合性能,但高精度交流恒流源的实现较为困难;电压激励、电流输出模式兼具两者的优点,是比较仪电桥较为理想的工作模式.     

Synthesis of Pure Silica Zeolites

Pure silica zeolite has become an important porous material in the chemical industry due to its excellent stability and hydrophobicity. However, there are still some problems in the synthesis process of pure silica zeolite, such as environmental pollution, complex operation and high cost. How to effectively and environmentally synthesize pure silica zeolite still remains a significant challenge. This review summarizes the pure silica zeolitetype frameworks that have been discovered currently, introduces the progresses achieved in the synthesis of pure silica zeolite and prospects the areas for future exploration in the synthesis and development of pure silica zeolite.     

离子液体[BMIM]PF6中铬的电沉积行为简

以一氯丁烷、N-甲基咪唑和KPF6为原料,合成了1-丁基-3-甲基咪唑六氟磷酸盐离子液体([BMIM]PF6),用红外光谱(IR)对产物进行了结构分析. 用循环伏安法测试该离子液体在85 ℃下的电化学窗口为4.7 V. 考察了[BMIM]PF6-Cr(Ⅲ)电解液的电化学行为,结果表明,在85 ℃下Cr(Ⅲ)的还原过程是受扩散控制的一步还原不可逆过程,Cr(Ⅲ)的传递系数α=0.023,阴极扩散系数D0=1.142×10-6 cm2/s. 在85 ℃和-1.5 V条件下,用恒电势法在铜片上电沉积Cr(Ⅲ),并通过扫描电子显微镜(SEM)观察了铜片上镀层的表面结构,发现该镀层呈颗粒状,且颗粒的体积随沉积时间的延长而增大. X射线能量色散谱(EDS) 和X射线粉末衍射(XRD)测试结果表明,该镀层为无定形的金属铬.     

The First Hybrid Wells-Dawson-type Polytungstate Monosupported by Cd-coordination Complex via Di-bridging O-atom

Polyoxometalates(POMs) with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block(polyanion) is generally established on terminal O-atoms, but scarcely via bridging O-atoms. By introducing liquid small organic molecule(pyridine, C5NH5) as assistant "structure-directing agent", we obtained a novel organic-inorganic hybrid polytungstate,(Hpy)4[Cd(phen)2(P2W18O62)]·nH2O(1, n ≈ 3, py = pyridine, phen = 1,10-phenanthroline), under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 is the first compound containing an asymmetric heteropolyanion, [Cd(phen)2(P2W18O62)]4–, a Wells-Dawson-type polyanion monosupported by Cd-coordination complex via di-bridging O-atoms.     

具有输入饱和因子的滞后关联大系统的分散控制

研究了一类具有饱和因子的滞后关联大系统的分散控制问题.首先对饱和因子进行了巧妙地处理,再通过构造Lyapunov泛函,利用(LMI)方法给出了分散控制状态反馈控制器的设计方法.控制器通过解线性矩阵不等式即可得到,计算简便.最后,数值例子和仿真说明了该设计方法的有效性.