Characterisation of some sparse binary sequential arrays

A periodic binary array is said to besequential if and only if every line of the array is occupied by a given periodic binary sequence or by some cyclic shift or reversal of this sequence. This paper extends earlier results for arrays built on the square grid, characterising further sequential arrays with two ones per period, and those with three consecutive ones per period.     

Non-radiative recombination in chalcogenide glasses

Non-radiative recombination of electron-hole pairs in chalcogenide glasses is described using a mechanism of a strong electron-phonon coupling. Recombination proceeds through a transient bonding rearrangement that creates a defect similar to those giving localized electronic states. Incomplete recombination which leaves the defect in a metastable state explains the reversible photostructural change.     

An automated high precision calorimeter for the temperature range 200K–400K. Part 1: Design and performance

A fully automated calorimeter has been designed and tested over the temperature range 200K–400K. The system may be used for measurements with an absolute accuracy of 0.2% of samples of approximate mass 50g and thermal capacity 15 JK⁻¹. The temperature of the sample is determined by a quartz crystal thermometer of resolution 100 μK which is not in direct thermal contact with the sample. The performance of the system is illustrated by results obtained on high purity copper, distilled water and K₂PbCu(NO₂)₆ which exhibits very sharp first order phase transitions at about 273.4K and 281.8K.     

Stickstoffbestimmung

Ohne Zusammenfassung     

Design and synthesis of multi-component 18 pi annulenic fluorofullerene ensembles suitable for donor-acceptor applications

A series of trannulene (all-trans annulene) derivatives of [60]fullerene have been prepared by reacting C(60)F(18) with methanetricarboxylate esters that incorporate a range of photoactive functions. All the compounds have the intense emerald-green colour of fullerene trannulenes, characterised by strong bands at ca. 612 and 667 nm. Single crystal X-ray studies show that the packing varies with the nature of the addend, attributable to differing steric effects. UV/vis absorption spectra display transitions of the respective fullerene and addend models, indicating absence of electronic interactions between them in the ground state. These now provide an extensive series for testing photoactive (light-harvesting) properties, with the exceptional properties of having strong visible light absorption. Their exceptional stability is attributed to the 18[small pi] aromatic circuit, inability to undergo nucleophilic substitution without disrupting this circuit, and a curved cage region that is shielded to reagents by the three bulky addends.     

A.C. susceptibility and magnetisation measurements on polysulphur nitride, (SN)x

Measurements of the complex A.C. susceptibility and magnetization of crystals of polysulphur nitride, (SN)_x, are reported. At temperatures near 0.2K both the in-phase and quadrature components of the A.C. susceptibility show a marked change which can be related to the onset of superconductivity. However, changes in the sample magnetization could not be detected.     

Synthesis of conformationally constrained benzoylureas as BH3-mimetics

The design of small molecules that mimic the BH3 domain and bind to Bcl-2 proteins has emerged as a promising approach to discovering novel anti-cancer therapeutics. We reveal the design and synthesis of conformationally constrained benzoylurea scaffolds as conformational probes. Central to helix mimicry, the intramolecular hydrogen bond in the benzoylurea plays a key role in the pre-organisation of the acyclic substrates for cyclisation via ring closing metathesis, providing efficient access to the constrained mimetics.     

C2 isomers of C84F40 and C84F44 are cuboid and contain benzenoid and naphthalenoid aromatic patches

A 1:1 mixture of C84F40 and C84F44, both derived from the D2(IV) isomer, has been isolated from the fluorination of [84]fullerene with either MnF3 or CoF3 at 500 degrees C. The 1D and 2D COSY 19F NMR spectra showed that each derivative is cuboid, having benzenoid rings at four of the six octahedral sites; the two remaining sites have naphthalenoid rings for C84F40, and two slightly offset benzenoid rings for C84F44. The benzenoid rings each have six adjacent sp3-hybridised carbon atoms whilst the naphthalenoid moieties have eight, thus facilitating full delocalisation. In terms of the number and size of aromatic patches, C84F44 is the most aromatic fullerene derivative yet isolated.     

Flow visualization of a recirculating flow by rheoscopic liquid and liquid crystal techniques

Experiments were conducted in a three-dimensional lid-driven cavity flow to study the behavior of longitudinal Taylor-Görtler-like vortices. Flow visualization was accomplished by use of a rheoscopic liquid and of liquid crystals, together with laser-light and white-light sheets, respectively. Photographs of the lighted planes in the flow confirmed the existence of the vortices for a wide range of Reynolds numbers and for stable, neutrally-buoyant and buoyant global flow conditions. As usual the flow visualization revealed flow patterns not deducible by in situ measurements; the liquid crystal photographs give both flow pathlines and temperature distribution on any lighted plane.     

Maximum packings ofK n with copies ofK 4 − e

For eachn, we determine the maximum number of pairwise edge disjoint copies ofK ₄ – e inK _n , and all possible graphs that arise from the unused edges.