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31.
An HPLC post column chemical derivatization procedure based on the interaction between an acridinium triflate and amines to form highly colored derivatives on-line is described for the determination of aromatic amines. Benzocaine and butesin, local anesthetic agents that contain the aromatic amine group, were used as model compounds. Reversed-phase HPLC conditions were developed for both the separation of analytes and the reaction between analytes and the acridinium triflate in the system. Three-dimensional knitted teflon shape coils and the internal diameter and length of the coils were important parameters in reducing band broadening and background noise.N-Methyl-9-chloroacridinium triflate was shown to be applicable to the determination of primary aromatic amines, selected secondary aromatic amines, hydrazides, and hydrazines. Application of the on-line chemical derivatization procedure to the analysis of pharmaceutical dosage forms containing procainamide (primary aromatic amine), isoniazid (hydrazide), and hydralazine (hydrazine) is also described. 相似文献
32.
Charles W. Stewart C. A. Von Frankenberg 《Journal of Polymer Science.Polymer Physics》1967,5(3):623-631
The thermodynamic properties of amorphous polyethylene are calculated from a model based on the method of significant structures. The motion of a molecule as a whole is described by the motion of segments, each segment moving independently of all others. It is assumed that on melting, holes appear in the solid lattice and the segments can move into these vacancies, obtaining some gaslike degrees of freedom. The complete frequency distribution for polyethylene is used for the solidlike degrees of freedom, while a corrected classical partition function is used for the gaslike degrees of freedom. The calculated thermodynamic properties are in reasonable agreement with experimentally determined values, assuming each gaslike segment to consist of 20 CH2 groups. 相似文献
33.
Miklos Kertesz Yong S. Lee James J. P. Stewart 《International journal of quantum chemistry》1989,35(2):305-313
It is shown that infinite long polyacene chains may have three energetically close but structurally distinct isomers (a symmetrical, sym, form and two lower symmetry forms: one with double bonds in a trans and another isomer with double bonds in a cis pattern). The energetics is based on solid state MNDO theory. We discuss that the symmetrical form has a substantial energy gap Eg in the Hartree–Fock approach owing to exact exchange terms, which are nonlocal. Broken symmetry Hartree–Fock (HF ) solutions for polyacene are also described. An angularly distorted structure suggested earlier on Jahn–Teller grounds is found to be energetically not favorable. 相似文献
34.
James J. P. Stewart 《Journal of computational chemistry》1991,12(3):320-341
Using a recently developed procedure for optimizing parameters for semiempirical methods,1 PM3 has been extended to a total of 28 elements. Average ΔHf errors for the newly parameterized elements are Be: 8.6, Mg: 8.4, Zn: 5.8, Ga: 14.9, Ge: 11.4, As: 8.5, Se: 11.1, Cd: 2.6, In: 11.3, Sn: 9.0, Sb: 13.7, Te: 11.3, Hg: 6.8, Tl: 6.5, Pb: 7.4, and Bi: 10.9 kcal/mol. For some elements the paucity of data has resulted in a method, which, while highly accurate, is likely to be only poorly predictive. 相似文献
35.
4-(4-Hydroxyphenyl)-2-phenylamino-1,8-naphthyridine was prepared via cyclisation of N-phenyl-N′-3-(4-hydroxyphenethen-1-yl)pyridin-2-ylthiourea in the presence of mercuric oxide. Derivatives of 4-methyl-2-aminoquinolines were prepared in a similar manner from 2-vinylphenylthioureas. 相似文献
36.
Hexamethylditin in methanol solution reacts rapidly with mercuric chloride to yield mercury and trimethyltin chloride. With alkylmercuric salts the reaction is complex, yielding tetraalkyltin and/or dialkylmercury, depending upon the reactivity of the alkylmercuric salt. An electrophilic substitution mechanism involving trimethylstannyl mercurials as transient intermediates is suggested. The reaction of hexaalkylditin with diarylmercury is suggested to follow a homolyric pathway. 相似文献
37.
Aalders MC Sterenborg HJ Stewart FA van der Vange N 《Photochemistry and photobiology》2000,72(4):521-525
In 75% of cases, ovarian carcinoma has already metastasized in the abdominal cavity at the time of diagnosis. For determination of the necessity for a supplementary therapy, in addition to surgical resection, it is important to localize and stage microscopical intraperitoneal metastases of the tumor. Intraperitoneal photodetection of tumor metastases is based on preferential tumor distribution of a fluorescent tumor marker. The time-dependent differences in drug concentration between tumor and normal (T/N) tissues can be used to visualize small tumors. We performed fluorescence measurements on abdominal organs and tumor in the peritoneal cavity of rats. 5-Aminolevulinic acid (ALA)-induced protoporphyrin IX (PpIX) was used as the fluorescent marker. Three different drug doses (100, 25 and 5 mg/kg) were used and PpIX fluorescence profiles were followed up to 24 h after intravenous administration. Maximum T/N ratios were found 2-3 h after administration of ALA with all drug doses. A significant T/N tissue contrast was obtained for all abdominal organs tested after administration of 5 mg/kg. 相似文献
38.
From the basic light microscope through high-end imaging systems such as multiphoton confocal microscopy and electron microscopes, microscopy has been and will continue to be an essential tool in developing an understanding of cardiovascular development, function, and disease. In this review we briefly touch on a number of studies that illustrate the importance of these forms of microscopy in studying cardiovascular biology. We also briefly review a number of imaging modalities such as computed tomography (CT), magnetic resonance imaging (MRI), ultrasound, and positron emission tomography (PET) that, although they do not fall under the realm of microscopy, are imaging modalities that greatly complement microscopy. Finally we examine the role of proper imaging system calibration and the potential importance of calibration in understanding biological tissues, such as the cardiovascular system, that continually undergo deformation in response to strain. 相似文献
39.
40.
B. D. Stewart J. W. McKlveen R. L. Glinski 《Journal of Radioanalytical and Nuclear Chemistry》1988,123(1):121-132
In order to establish baseline information for current and future mining operations, water samples from the Colorado River and its tributaries have been analyzed for Ra-226 and uranium isotopes. Ra-226 was separated by coprecipitation on BaSO4 followed by alpha spectrometry. Ba-133 was used as a tracer for yield determination. Uranium was separated by a combination of BaSO4 precipitation and solvent extraction followed by coprecipitation on CeF3 for alpha spectrometry.Results indicate that radium and uranium levels in the Colorado River and its tributaries, except the Little Colorado River, are below the EPA specifications [1] for drinking water of 185 mBq/liter (5 pCi/1) for Ra-226 and 433 mBq/liter (11.7 pCi/1) for U-238. However, the specific sources for elevated uranium and Ra-226 concentrations in the Little Colorado River should be identified, and the potential impacts from leaching of the naturally exposed mineralization inside the Grand Canyon should be investigated. 相似文献