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The effect of different storage temperatures on the physical properties of pectin solutions and gels
Gordon A. Morris Jonathan Castile Gary G. Adams Stephen E. Harding 《Polymer Degradation and Stability》2010,95(12):2670-2673
The stability (in terms of viscosity and gel strength) of pectin solutions and gels potentially plays an important role in their behaviour and functional properties in a wide range of applications and therefore any changes over time must be understood. The gel strength of pectin gels and intrinsic viscosity of pectin solutions at different temperatures (4 °C, 25 °C and 40 °C) have been investigated using a “rolling ball” viscometer and a texture analyser respectively. Both the intrinsic viscosity ([η]) and gel strength decrease with increased storage time, although this more pronounced at elevated temperatures. The changes in intrinsic viscosity with storage time and temperature were used to determine the depolymerisation constant (k). Pectin storage conditions and particularly temperature have an influence on depolymerisation, particularly elevated storage temperatures, but whether or not this will be detrimental to its intended application will depend on the functional significance of the changes that occur. In this case based on the previous diffusion studies on a model drug (paracetamol) we conclude that the decreases in viscosity and gel strength within the range observed have no detrimental effect on the drug release properties. 相似文献
904.
Stephen G. Davies Ai M. Fletcher Gesine J. Hermann Giovanna Poce Paul M. Roberts Andrew D. Smith Miles J. Sweet James E. Thomson 《Tetrahedron: Asymmetry》2010,21(13-14):1635-1648
The doubly diastereoselective conjugate addition of the antipodes of lithium N-benzyl-N-(α-methylbenzyl)amide to a range of enantiopure N-enoyl oxazolidin-2-ones has been used as a mechanistic probe to determine that the reactive conformation is the anti-s-cis form. The β-amino carbonyl products resulting from these conjugate addition reactions are useful templates for further elaboration into an α,β,α-pseudotripeptide. 相似文献
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A method for fabricating infrared‐transmitting waveguides that yields low optical losses and strong confinement of light is presented. The method minimises the number of fabrication steps by exploiting the photosensitivity of arsenic trisulfide glass, using it both as a photoresist and as a waveguiding material. Controlled annealing/remelting of the waveguides minimises scattering due to fluctuations in refractive index at the interface between the waveguide and the surrounding medium, allowing low losses to be realised. Bends and Y‐splitter structures have been realised, as well as the longest As2S3 serpentine planar waveguides yet reported. 相似文献
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This paper describes a two-stage strategic planning model for determining the optimal R&D portfolio in the presence of both exploratory and developmental research projects. An example is illustrated in the context of energy research. Research portfolios are analysed using a Bayesian approach in which probability assessments are updated as new information generated by exploratory research becomes available. Useful insights are obtained through sensitivity analysis. It is found that exploratory research tends to exhibit a lumpy characteristic. 相似文献