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951.
Syntheses,Structures, and Magnetic Behavior of New Azide Linked Compounds with One‐ and Two‐Dimensional Structures 下载免费PDF全文
Three azide based compounds were synthesized employing aliphatic amines as site blocking agents: [Ni(N3)(C6H16N2)2]ClO4 ( I ) [C6H16N2 = N,N′‐diethylethylenediamine (DEDA)], [Cu8(N3)16(C6H18N4)2] ( II ) [C6H18N4 = tris(2‐aminoethyl) amine (TREN)], and [Cu7(N3)14(C7H19N3)2] · 2H2O ( III ) [C7H19N3 = 3,3′‐diamino‐N‐methyldipropylamine (DMDA)]. The compounds I and II have one‐dimensional structure and III has a two‐dimensional structure. Compound I is a simple linear cationic Ni–azide chain and compound II has Cu6 azide units forming a column terminated by the copper‐metalloligand generated in‐situ during the course of the reaction. The charge compensation perchlorate anions occupy spaces in between the chains in I . Compound II packs in a herringbone arrangement, which is not commonly observed in low‐dimensional structures. Compound III has one‐dimensional copper‐azide chains connected through copper‐metalloligand forming the two‐dimensional structure. All the three compounds exhibit anti‐ferromagnetic behavior. 相似文献
952.
Sangani Jhansi Srivastava Antriksh Srinivasan Venkatraman 《Transport in Porous Media》2022,142(3):641-668
Transport in Porous Media - The proposed study is an attempt to perceive theoretically the heat transfer phenomenon in the flow of temperature-dependent viscous blood through microvessels... 相似文献
953.
954.
955.
Bikshandarkoil R. Srinivasan Santosh Y. Shetgaonkar Pallepogu Raghavaiah 《Journal of Chemical Sciences》2008,120(2):249-257
The aqueous reaction of barium carbonate with 2-nitrobenzoic acid (2-nbaH) results in the formation of a one-dimensional coordination
polymer, catena-poly[[hexa(aqua)dibarium(II)]bis[(μ
2-2-nitrobenzoate-O,O,O-NO2)(μ
2-2-nitrobenzoate-O,O,O′)]] 1. On heating at 100°C compound 1 is dehydrated to anhydrous barium bis(2-nitrobenzoate) 2. The anhydrous compound can be re-hydrated to 1 on exposure to water vapour. Compounds 1 and 2 were characterized by elemental analysis, IR and UV-Vis spectra, DSC thermograms, weight loss studies and the structure of
1 was determined. 1 and 2 can be thermally decomposed to BaCO3 by heating at 800°C. The polymer [[Ba(H2O)3]2(μ
2-2-nba-O,O,O-NO2)2 (μ
2-2-nba-O,O,O′)2]
n
1 crystallizes in the centrosymmetric triclinic space group Pī and all atoms are located in general positions. The polymeric
structure is based on a dimeric unit and consists of three water molecules coordinated to a central Ba(II) and two unique
2-nitrobenzoate (2-nba) anions, one of which (μ
2-2-nba-O,O,O-NO2) functions as a tridentate ligand and is linked to a Ba(II) through the oxygen atom of the-NO2 group and forms a monoatomic μ
2-carboxylate bridge between two symmetry related Ba(II) ions with a Ba···Ba distance of 4·5726(14) ?. The second unique 2-nba
anion (μ
2-2-nba-O,O,O′) also functions as a tridentate ligand with the carboxylate oxygen atoms linked to a Ba(II) ion in a bidentate
fashion and one of the carboxylate oxygen atoms forming a monoatomic bridge between two symmetry related Ba(II) ions resulting
in a Ba···Ba separation of 4·5406(15) ?. These differing tridentate 2-nba ligands link {Ba(H2O)3} units into a one-dimensional polymeric chain extending along b axis. In the infinite chain each nine coordinated Ba(II) is bonded to three water molecules and further linked to six oxygen
atoms of four different 2-nitrobenzoate anions with alternating pairs of Ba(II) ions in the chain bridged by a pair of (μ
2-2-nba-O,O,O-NO2) and (μ
2-2-nba-O,O,O′) ligands resulting in alternating Ba···Ba distances of 4·5406(15) and 4·5726(14) ? across the chain.
Dedicated to Prof. S. K. Paknikar on the occasion of his 73rd birthday. 相似文献
956.
957.
G. Madhurambal P. Ramasamy P. A. Srinivasan S. C. Mojumdar 《Journal of Thermal Analysis and Calorimetry》2006,86(3):601-604
Anthracene is one of the organic molecular crystals, which exhibits
peculiar optical and electronic properties. Since the 9, 10 positions are
very reactive in anthracene, it undergoes the Diel’s–Alder reaction
with maleic anhydride in 99% yield. The synthesis of Diel’s–Alder
adduct has been carried out by adopting standard procedure. The product was
subjected to various characterization studies such as FTIR, UV and 1H
NMR spectroscopy, and thermal studies to check its purity and determine the
applicability of adduct in various applications. The second harmonic generation
(SHG) efficiency of the adduct has been observed using Nd:YAG laser. 相似文献
958.
Ramakrishnan Chidambaram 《Tetrahedron letters》2004,45(7):1441-1444
Conditions that ensure a more reproducible Pd(0)-mediated procedure to convert aryl bromides to aryl cyanides have been developed that entail the use of zinc dust to keep the Pd in the zero oxidation state and zinc acetate to ensure high catalytic activity. This procedure is applicable to a wide range of substrates and obviates the need for stringent removal of oxygen from the reaction medium. 相似文献
959.
Two new compounds, [(C4N2H12)3][P2Mo5O23]·H2O,I, and [(C3N2H12)3][P2Mo5O23]4H2O,II, have been prepared employing hydrothermal methods in the presence of aliphatic organic amine molecules. Both the compounds
possess the same polyoxoanion, pentamolybdatobisphosphate, (P2Mo5O23)6-. The anions consist of a ring of five MoO6 distorted octahedra with four edge connections and one corner connection. The phosphate groups cap the pentamolybdate ring
anion on either side. The anion is stabilized by strong hydrogen bonds involving the hydrogen atoms of the amine molecules
and the oxygen atoms of the polyoxoanion and water molecules. Crystal data:I, monoclinic, space group = P21/n (no. 14), mol. wt. = 1192.1,a = 9.4180(1),b = 18.1972(3),c = 19.4509(1) ?, Β = 103.722(1)‡,V = 3238.37(7) ?3, Z = 4;II, triclinic, space group = P1 (no. 2), mol. wt. = 1210.1,a 9.5617(9),b = 13.3393(12),c = 13.7637(12) ?, α = 88.735(1), Β = 75.68(1), γ = 87.484(2)‡,V = 1699.2(3) ?3. 相似文献
960.
Srinivasan Natarajan 《无机化学与普通化学杂志》2004,630(2):291-295
A hydrothermal reaction of a mixture of ZnO, HCl, ethylenediphosphonic acid, ethylenediamine, acetic acid in a water, THF mixture gave rise to a new three‐dimensional zinc ethylenediphosphonate, [NH3(CH2)2NH3][Zn3{O3P(CH2)2}4], I . The structure, determined by single crystal X‐ray diffraction, (monoclinic, space group = C2/c, a = 16.9948(14), b = 6.7383(6), c = 16.8886(14)Å, β = 1113.568(1)°, V = 1772.7(3)Å3, Z = 4, R1 = 0.0227, wR2 = 0.0601), consists of a network of strictly alternating ZnO4 and PO3C tetrahedral units linked through their vertices forming the three‐dimensional structure. The amine molecules occupy the middle of the 8‐membered channels and interact with the framework through the hydrogen bonds. Unlike other zinc diphosphonates, I appear to have close similarity to zinc phosphate structures reported in the literature. To our knowledge, this is the first three‐dimensional zinc diphosphonate prepared in the presence of an organic amine molecule. 相似文献