Stability of monomolecular films of archaebacterial tetraether lipids on silicon wafers: a comparison of physisorbed and chemisorbed monolayers

The monomolecular organisation of symmetric, chemically modified tetraether lipids caldarchaeol-PO(4) was studied using Langmuir film balance, ellipsometry, and atomic force microscopy (AFM). Solid silicon wafer substrates were modified to hydrophobic, hydrophilic, and amino-silanised surfaces; and Langmuir-Blodgett (LB)-films were transferred onto each. LB-caldarchaeol-PO(4) films were subjected to further rinsing with organic solvent and additional physical treatments, to compare their resistance and stability on chemisorbed (amino-silanised) and physisorbed (hydrophobic and hydrophilic) surfaces. The resistance and stability of these monolayer films was characterized by ellipsometry and AFM, and film thickness was determined using ellipsometry. AFM was also employed to observe surface morphology. Monolayer films on hydrophobic surfaces were found to be more resistant to rinsing with organic solvent and additional physical treatments than monolayer films on either amino-silanised or hydrophilic surfaces. The hydrophobic effect with hydrophobic surfaces appears to support the formation of stronger caldarchaeol-PO(4) films on silicon wafer substrates, with increased resistance and stability.     

Zeros of a family of hypergeometric para‐orthogonal polynomials on the unit circle

Para‐orthogonal polynomials derived from orthogonal polynomials on the unit circle are known to have all their zeros on the unit circle. In this note we study the zeros of a family of hypergeometric para‐orthogonal polynomials. As tools to study these polynomials, we obtain new results which can be considered as extensions of certain classical results associated with three term recurrence relations and differential equations satisfied by orthogonal polynomials on the real line. One of these results which might be considered as an extension of the classical Sturm comparison theorem, enables us to obtain monotonicity with respect to the parameters for the zeros of these para‐orthogonal polynomials. Finally, a monotonicity of the zeros of Meixner‐Pollaczek polynomials is proved.     

Fluorescence Correlation Spectroscopy of Gold Nanoparticles

Diffusion dynamics of gold nanoparticles (GNPs) was studied by fluorescence correlation spectroscopy (FCS). The fluorescence was studied by exciting the particles by green laser (532 nm), which is far from longitudinal plasmon band of nanorods. Transmission electron microscope (TEM) and UV-Vis-NIR spectrometer were used to characterize the gold nanoparticles. Despite their low quantum yields, GNPs possess the native fluorescence. The excellent antiphotobleaching behavior of gold nanorods leads to prospects of using FCS for its detailed studies. Using FCS, dynamic information can be extracted from the fluorescence fluctuations in the system by autocorrelation function. Maximum entropy method (MEMFCS) was used to identify the number of distinct components present in the system. The particle sizes obtained from FCS were found to be higher (by few orders of magnitude) compared to TEM analysis. This might be due to the possible contributions from cetyltrimethyl ammonium bromide (CTAB) capping in the system.     

Experimental investigation to study flow and heat transfer characteristics over a NACA0018 aerofoil for different height ratios

Experiments are carried out to study flow and heat transfer characteristics over NACA0018 aerofoil when the body approaches the wall of a wind tunnel. Investigations have been done to study the effect of wall proximity due to flow separation around the body at Reynolds number 2.5 × 10⁵, different height ratios and various angles of attack. The static pressure distribution has been measured on upper and lower surfaces of the aerofoil. The results have been presented in the form of pressure coefficient, drag coefficient for different height ratios. Pressure coefficient values are decreased and then increased on the lower surface of the aerofoil and decreased on the upper surface of the aerofoil at all angles of attack. The negative pressure coefficient and drag coefficient decreases as the body approaches the upper wall of wind tunnel. The maximum value of drag coefficient has been observed at an angle of attack 30° for the aerofoil at all height ratios. The Heat transfer experiments have been carried out under constant heat flux condition. Heat transfer coefficients are determined from the measured wall temperature and ambient temperature and presented in the form of Nusselt number. The variation of local as well as average Nusselt number has been shown with non dimensional distance for different angles of attack and for various height ratios. The local as well as average Nusselt number decreases as the height ratio decreases for all non-dimensional distance and angles of attack respectively. Maximum value of average Nusselt number has been observed at an angle of attack 40°.     

Differential pulse anodic stripping voltammetric determination of Hg2+ at poly(Eriochrome Black T)-modified carbon paste electrode

The electrochemical behavior of Hg²⁺ was investigated in poly(Eriochrome Black T)-modified carbon paste electrode (CPE) using cyclic voltammetry (CV). Poly(Eriochrome Black T) was prepared in an alkaline medium on the surface of the CPE using a solution of Eriochrome Black T with the CV technique. The electrochemical impedance study revealed a better charge transfer kinetics at the modified electrode. The effects of variation of the experimental conditions, such as the concentration of electrolytes, pH, deposition time, and the deposition potential, which maximize current efficiency were studied. The optimum response of Hg²⁺ was observed in 1.0 M KCl solution. The differential pulse anodic stripping voltammetric technique was employed successfully to detect Hg²⁺, which gave a good linear response at low concentration levels of Hg²⁺. The detection limit was found to be 2.2?×?10^?10 M (S/N?=?3), which is comparable with that achieved in multiwall carbon nanotube-modified electrode. The remarkable electroanalytical performance of the modified electrode makes it amenable to employ it successfully as an electrochemical sensor for the determination of hazardous pollutant Hg²⁺ in environmental samples.     

A new approximate analytical solution for arbitrary Stokes flow past rigid bodies

A method of computing general Stokes flows in the presence of rigid boundaries of arbitrary shape is proposed. The solution satisfies the governing field equations exactly and the boundary conditions approximately. The method has been illustrated with three examples. The advantage of the method lies in the ease of implementation for rigid bodies of arbitrary shape, providing an approximate but analytical solution throughout the domain.     

Increased photocatalytic activity caused by B doping into BiVO4

Research on Chemical Intermediates - We have prepared B-doped BiVO4 (B-BiVO4) with oval-shaped morphology through a simple, one-step hydrothermal route employing sodium citrate as the chelating...     

Extended Relativistic Toda Lattice,L-Orthogonal Polynomials and Associated Lax Pair

When a measure \(\varPsi(x)\) on the real line is subjected to the modification \(d\varPsi^{(t)}(x) = e^{-tx} d \varPsi(x)\), then the coefficients of the recurrence relation of the orthogonal polynomials in \(x\) with respect to the measure \(\varPsi^{(t)}(x)\) are known to satisfy the so-called Toda lattice formulas as functions of \(t\). In this paper we consider a modification of the form \(e^{-t(\mathfrak{p}x+ \mathfrak{q}/x)}\) of measures or, more generally, of moment functionals, associated with orthogonal L-polynomials and show that the coefficients of the recurrence relation of these L-orthogonal polynomials satisfy what we call an extended relativistic Toda lattice. Most importantly, we also establish the so called Lax pair representation associated with this extended relativistic Toda lattice. These results also cover the (ordinary) relativistic Toda lattice formulations considered in the literature by assuming either \(\mathfrak{p}=0\) or \(\mathfrak{q}=0\). However, as far as Lax pair representation is concern, no complete Lax pair representations were established before for the respective relativistic Toda lattice formulations. Some explicit examples of extended relativistic Toda lattice and Langmuir lattice are also presented. As further results, the lattice formulas that follow from the three term recurrence relations associated with kernel polynomials on the unit circle are also established.

     

Synthesis,structural characterization and in vitro cytotoxicity of diorganotin complexes with Schiff base ligands derived from 3‐hydroxy‐2‐naphthoylhydrazide

A series of diorganotin complexes with Schiff base ligands, (E)‐N′‐(5‐bromo‐2‐hydroxybenzylidene)‐3‐hydroxy‐2‐naphthohydrazide, H₂L1, and (E)‐N′‐(5‐chloro‐2‐hydroxybenzylidene)‐3‐hydroxy‐2‐naphthohydrazide, H₂L2, were synthesized and characterized by elemental analysis, IR, ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopy. The molecular structures of the complexes, [(5‐bromo‐2‐oxidobenzylidene)‐3‐hydroxy‐2‐naphthohydrazidato]di(o‐chlorobenzyl)tin(IV) 6 and [(5‐chloro‐2‐oxidobenzylidene)‐3‐hydroxy‐2‐naphthohydrazidato]dibutyltin(IV) 9, were determined through single‐crystal X‐ray diffraction and revealed a distorted trigonal‐bipyramidal configuration. The in vitro cytotoxic activity of the Schiff bases and their diorganotin complexes was also evaluated against several human carcinoma cell lines, namely HT29 (human colon carcinoma cell line), SKOV‐3 (human ovarian cancer cell line), MCF7 (hormone‐dependent breast carcinoma cell line) and MRC5 (non‐cancer human fibroblast cell line). [(5‐Bromo‐2‐oxidobenzylidene)‐3‐hydroxy‐2‐naphthohydrazidato]dibutyltin(IV) 2 and [(5‐bromo‐2‐oxidobenzylidene)‐3‐hydroxy‐2‐naphthohydrazidato]dibenzyltin(IV) 5 were the most active diorganotin complexes of H₂L1 ligand. Among the diorganotin complexes of H₂L2 ligand, [(5‐chloro‐2‐oxidobenzylidene)‐3‐hydroxy‐2‐naphthohydrazidato]dicyclohexyltin(IV) 11 showed good cytotoxic activity against all the tested cell lines. As such, the above compounds can be considered agents with potential anticancer activities, and can therefore be investigated further in in vitro or in vivo anticancer studies. Copyright © 2012 John Wiley & Sons, Ltd.