全文获取类型
收费全文 | 77688篇 |
免费 | 518篇 |
国内免费 | 112篇 |
专业分类
化学 | 41262篇 |
晶体学 | 1260篇 |
力学 | 3277篇 |
综合类 | 1篇 |
数学 | 7827篇 |
物理学 | 24691篇 |
出版年
2022年 | 629篇 |
2021年 | 872篇 |
2020年 | 965篇 |
2019年 | 1103篇 |
2018年 | 1596篇 |
2017年 | 1686篇 |
2016年 | 2148篇 |
2015年 | 1022篇 |
2014年 | 1719篇 |
2013年 | 3268篇 |
2012年 | 2896篇 |
2011年 | 3274篇 |
2010年 | 2636篇 |
2009年 | 2634篇 |
2008年 | 2996篇 |
2007年 | 2872篇 |
2006年 | 2767篇 |
2005年 | 2432篇 |
2004年 | 2238篇 |
2003年 | 2071篇 |
2002年 | 2133篇 |
2001年 | 2233篇 |
2000年 | 1625篇 |
1999年 | 1252篇 |
1998年 | 1125篇 |
1997年 | 1036篇 |
1996年 | 892篇 |
1995年 | 831篇 |
1994年 | 811篇 |
1993年 | 811篇 |
1992年 | 864篇 |
1991年 | 933篇 |
1990年 | 877篇 |
1989年 | 905篇 |
1988年 | 816篇 |
1987年 | 767篇 |
1986年 | 739篇 |
1985年 | 864篇 |
1984年 | 961篇 |
1983年 | 818篇 |
1982年 | 834篇 |
1981年 | 746篇 |
1980年 | 701篇 |
1979年 | 768篇 |
1978年 | 890篇 |
1977年 | 913篇 |
1976年 | 808篇 |
1975年 | 774篇 |
1974年 | 790篇 |
1973年 | 760篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
961.
Molluscicidal triterpenoidal saponin from Lysimachia sikokiana 总被引:2,自引:0,他引:2
The main molluscicidal activity of the methanol extract of Lysimachia sikokiana is due to several triterpenic saponins called sakuraso-saponins. The most active component was isolated from the aerial parts and elucidated as 3-O-beta-xylopyranosyl-(1----2)-beta-glucopyranosyl-(1----4)- [beta-glucopyranosyl-(1----2)]-alpha-arabinopyranosyl protoprimulagenin A, named lysikoianoside 1, on the basis of 1H- and 13C-nuclear magnetic resonance spectral data and methylation analysis results. 相似文献
962.
The synthesis of the indoles 7 , 15 , 16 with a 3-methoxyphenyl group, attached via an α-side chain of 1,2,or 3 CH2 units, is reported. These compounds, after appropriate protection at C(3), were transformed into the N-[(dimethylamino)methyl]indoles 22 , 23 , and 24 , respectively. When treated with AcCl, these N-Mannich bases gave, in two cases, stable N-(chloromethyl)indoles 25 and 26 . In the presence of SnCl4, ring closure occurred via electrophilic attack of 1-methylideneindolium ions on the methoxyphenyl group. Formation of seven-membered rings (→ 27 , 28 ) and eight-membered rings (→ 29 ) was found to be a favorable process. Cyclization to six-membered rings did not occur within this series. 相似文献
963.
V. N. Charushin M. G. Ponizovskii O. N. Chupakhin A. I. Rezvukhin G. M. Petrova Yu. A. Efremov 《Chemistry of Heterocyclic Compounds》1981,17(11):1129-1134
The reactions of substituted quinoxalinium, benzo[g]- and benzo[f]quinoxalinium, and pyrido[2,3-b]pyrazinium salts with anions of -dicarbonyl compounds give furo[2,3-b]-annelated systems with strictly determined regio- and stereoorientations.See [1] for Communication 3.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1543–1548, November, 1981. 相似文献
964.
O. G. Koch 《Fresenius' Journal of Analytical Chemistry》1973,265(1):29-30
Zusammenfassung Zur Bestimmung von 2,5–100 ppm Sb in Eisen, unlegierten und niedrig legierten Stählen sowie in Automatenstählen wird das Antimon zuerst in 2 Stufen vorisoliert mit Hilfe der Spurenfällung mit Mangan(IV)-oxidhydrat als Spurenfänger und anschließender Jodidextraktion. Nach der Rückextraktion erfolgt die photometrische Bestimmung mit Methylfluoron in der wäßrigen Phase. Der relative Fehler beträgt ±5%, der Zeitbedarf für eine Einzelbestimmung 1,5 h.Herrn H. Sifirin danke ich für die sorgfältige Durchführung der Versuche. 相似文献
965.
O. N. Chechina S. V. Sokolov A. P. Tomilov 《Russian Journal of General Chemistry》2004,74(11):1714-1718
Carboxylic acids prepared from hexafluoropropene oxide CF3CF2CF2O[CF(CF3)CF2O]nCF (CF3)COOH [n = 0, 2,5-bis(trifluoromethyl)-3,6-dioxaperfluorononanoic acid; n = 1, 2,5,8- tris(trifluoromethyl)-3,6,9-trioxaperfluorododecanoic acid], according to voltammetric data, enter the Kolbe reaction both at the Pt anode and at anodes from carbon materials in H2O-CH3CN and CH3OH-CH3CN solutions. The critical potential appreciably depends both on the anode material and on the solvent composition. Favorable effect of pyridine additions in H2O-CH3CN solutions is due to replacement of water molecules from the electrical double layer. The sodium ions exert a negative effect on the Kolbe synthesis.Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 11, 2004, pp. 1842–1846.Original Russian Text Copyright © 2004 by Chechina, Sokolov, Tomilov.This revised version was published online in April 2005 with a corrected cover date. 相似文献
966.
Dip-pen nanolithography in tapping mode 总被引:1,自引:0,他引:1
Dip-pen nanolithography (DPN) is becoming a popular nano-patterning technique for depositing materials onto a substrate using the probe of an atomic force microscope (AFM). Here, we demonstrate the deposition of a short synthetic peptide by DPN using the Tapping Mode of AFM rather than the commonly used contact mode. DPN in Tapping Mode requires drive amplitude modifications for deposition, yet allows for gentle imaging of the deposited material and enables deposition on soft surfaces. 相似文献
967.
Menezes PH Gonçalves SM Hallwass F Silva RO Bieber LW Simas AM 《Organic letters》2003,5(10):1601-1604
[reaction: see text] Several (77)Se NMR experiments were performed by titrating a sample of selenides with the chiral shift reagent methylbenzylamine (MBA), followed by acquisition of (77)Se NMR spectra. Eventually, we observed the appearance of two anisochronous resonances, with a relatively large separation, from 37 to 56 Hz, corresponding to the formation of the diastereomeric complexes. This methodology avoids derivatization processes, and the studied compound can be easily recovered from the NMR tube. 相似文献
968.
A new algorithm for location of the critical points in general scalar fields is described. The new method has been developed as part of an on-going process to exploit the topologic analysis of general 3D scalar fields. Part of this process involves the use of topologic information to seed the critical point search algorithm. The continuing move away from topologic studies of just the electron density requires more general algorithms and the ability to easily "plug in" new functions, for example, the Laplacian of the electron density ( triangle down (2)rho), the Electron Localisation Function (ELF), the Localised Orbital Locator (LOL), the Lennard-Jones function (LJF), as well as any new functions that may be proposed in the future. Another important aspect of the current algorithm is the retention of all possible intermediate information, for example, the paths describing the connectivity of critical points, as well as an ability to restart searches, something that becomes increasingly important when analysing larger systems. This new algorithm represents a core part of a new local version of the MORPHY code. We distinguish nine universal types of gradient paths. 相似文献
969.
An automated technique for the determination of analytes in an ultrasonically levitated sample of 2 to 5 microL volume has been developed. Contactless dosing of reagents or solvents into an ultrasonically levitated drop was realized via piezoelectric micropumps. Drop size was continually controlled with a programmed CCD camera. A diode array spectrometer designed for the use with optical fibers was used for absorption and fluorescence measurements. Determinations via direct absorption measurements following the method of standard addition and acid-base titrations with an absorption indicator and a fluorescent indicator were carried out. The mean consumption of sodium hydroxide added via a piezoelectric micropump in five successive titrations with 18 nmol of sulfuric acid inside a levitated drop (indicator bromothymol blue) had a relative standard deviation of 0.7% and differed only by 0.2% from the expected value. 相似文献
970.
O. V. Prokuda V. R. Belosludov I. K. Igumenov P. A. Stabnikov 《Journal of Structural Chemistry》2006,47(6):1032-1041
Experimental data have been analyzed and interpreted for four volatile acetylacetonates of trivalent metals Al, Cr, Fe, and Ir. The crystal lattice energies were calculated by the atom-atom potential method. The lattice energies obtained by using the Buckingham potential are in better agreement with the sublimation heats of these metal complexes than those calculated from the Lennard-Jones potential. The experimental dependences of vapor pressure for the complexes are in satisfactory agreement with the values obtained from the calculated lattice energies and entropies of crystal-gas transitions. 相似文献