Synthesis and Stereochemistry of Novel Dibrominated 1,5-Dioxaspiro[5.5]undecane Derivatives

 The synthesis and stereochemistry of new dibrominated spiro-1,3-dioxane derivatives are reported. Investigations by means of NMR methods and single crystal X-ray diffraction for two compounds revealed the high regio- and diastereoselectivity of the bromination reaction of some new spiro-1,3-dioxanes and the asymmetric induction of the chiral carbon atom located in the spiro skeleton.     

Integrable structure of the field theory of open superstrings

We find asymptotic expansions in the “string mass” μ for μ-deformed Γ-functions and Neumann coefficients characterizing the three-string vertex in the light-cone gauge of the field theory of open superstrings on a maximally supersymmetric pp-wave background. Dedicated to the 80th birthday of Academician Anatolii Alekseevich Logunov __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 149, No. 3, pp. 381–385, December, 2006.     

Thermal properties of quantum electrodynamics in 2 + 1 dimensions and confinement

Conclusions Thus, we have shown that in QED₃ systematic allowance for screening makes it possible to eliminate infrared divergences and in this respect advance further than in QCD₄, in which the question of the mechanism of their elimination remains open. The comparative simplicity of the model also makes it possible to study systematically the more important question of the general structure of the series of skeleton perturbation theory and the excitation spectrum. We are currently working on this question.All-Union Scientific-Research Center for the Study of Surface and Vacuum Properties. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 69, No. 1, pp. 25–39, October, 1986.     

Gravitational Field Equations on Fefferman Space–Times

The total space \({\mathfrak M} \approx {\mathbb H}_1 \times S^1\) of the canonical circle bundle over the 3-dimensional Heisenberg group \({\mathbb H}_1\) is a space–time with the Lorentzian metric \(F_{\theta _0}\) (Fefferman’s metric) associated to the canonical Tanaka–Webster flat contact form \(\theta _0\) on \({\mathbb H}_1\). The matter and energy content of \(\mathfrak M\) is described by the energy-momentum tensor \({T}_{\mu \nu }\) (the trace-less Ricci tensor of \(F_{\theta _0}\)) as an effect of the non flat nature of Feferman’s metric \(F_{\theta _0}\). We study the gravitational field equations \(R_{\mu \nu } - (1/2) \, R \, g_{\mu \nu } = {T}_{\mu \nu }\) on \({\mathfrak M}\). We consider the first order perturbation \(g = F_{\theta _0} + \epsilon \, h\), \(\epsilon<< 1\), and linearize the field equations about \(F_{\theta _0}\). We determine a Lorentzian metric g on \({\mathfrak M}\) which solves the linearized field equations corresponding to a diagonal perturbation h.     

Recovery of Immersions from Their Metric Tensors and Nonlinear Korn Inequalities: A Brief Survey

The authors discuss the existence and uniqueness up to isometries of Enof immersions φ : Ω  R~n→ E~n with prescribed metric tensor field(g ij) : Ω→ S~n, and discuss the continuity of the mapping(gij) →φ defined in this fashion with respect to various topologies. In particular, the case where the function spaces have little regularity is considered. How, in some cases, the continuity of the mapping(gij) →φ can be obtained by means of nonlinear Korn inequalities is shown.     

Green light radiation effects on free radicals inhibition in cellular and chemical systems

Free radicals generation is inhibited through green light (GL) irradiation in cellular systems and in chemical reactions. Standard melanocyte cultures were UV-irradiated and the induced cellular reactive oxygen species (ROS) were quantified by the fluorescence technique. The same cell cultures, previously protected by a 24h GL exposure, displayed a significantly lower ROS production. A simple chemical reaction is subsequently chosen, in which the production of free radicals is well defined. Paraffin wax and mineral oil were GL irradiated during thermal degradation and the oxidation products checked by chemiluminescence [CL] and Fourier transform infrared spectra [FT-IR]. The same clear inhibition of the radical oxidation of alkanes is recorded. A quantum chemistry modeling of these results is performed and a mechanism involving a new type of Rydberg macromolecular systems with implications for biology and medicine is suggested.     

Quantitative estimates for a new complex Durrmeyer operator in compact disks

In the recent years the extension of linear positive operators from real to complex domain is one of the interesting area of research. In this context, we present the exact order of simultaneous approximation and Voronovskaja kind results with quantitative estimate for a new type of complex Durrmeyer operator (different from those previously studied), attached to analytic functions in compact disks. In this way, we put in evidence the overconvergence phenomenon for this kind of Durrmeyer operator, namely the extensions of approximation properties with exact quantitative estimates, from the real interval [1/3, 2/3] to compact disks in the complex plane.     

Synergic extraction of metals with α-acyl-d-camphor and optically active lewis bases

Solvent extraction of europium (III), zinc (II) cobalt (II) with α-acyl-d-camphor and optically active isomers of quinine and quinidine was studied in order to obtain information on chirality recognition based on adduct formation between a chiral metal chelate and optically active isomers. It was possible to differentiate clearly between the adduct formation of quinine and that of quinidine in the synergic extraction of cobalt and europium with 3-heptafluorobutyryl- d-camphor and cobalt with 3-trifluoroacetyl-d-camphor.