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991.
Dan Jin Zhao‐Fu Dai De‐Chun Zhang 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(2):o50-o52
In the title compound, C15H16NO+·C24H20B−, the pyridinium ring of the cation makes a dihedral angle of 4.3 (2)° with the benzene ring. Each is rotated in the same direction with respect to the central C—CH=CH—C linkage, by 10.0 (2) and 7.8 (2)°, respectively. The anions have a slightly distorted tetrahedral geometry. The most interesting feature of the structure is that the anions form a honeycomb‐like hexagonal structure down the b axis through C—H...π interactions. The hexagon is constructed from six BPh4− anions. The cations interact in a head‐to‐tail fashion along [010], forming chains, and pack antiparallel inside the above honeycomb‐like structure through C—H...π interactions. 相似文献
992.
993.
994.
High temperature thermoelectric properties of highly c-axis oriented Bi<sub>2</sub>Sr<sub>2</sub>Co<sub>2</sub>O<sub>y</sub> thin films fabricated by pulsed laser deposition 下载免费PDF全文
High-temperature thermoelectric transport property measurements have been performed on the highly c-axis oriented Bi2Sr2Co2Oy thin films prepared by pulsed laser deposition on LaAlO3(001).Both the electric resistivity ρ and the seebeck coefficient S of the film exhibit an increasing trend with the temperature from 300 K-1000 K and reach up to 4.8 m·Ω· cm and 202 μV/K at 980 K,resulting in a power factor of 0.85 mW/mK which are comparable to those of the single crystalline samples.A small polaron hopping conduction can be responsible for the conduction mechanism of the film at high temperature.The results demonstrate that the Bi2Sr2Co2Oy thin film has potential application in high temperature thin film thermoelectric devices. 相似文献
995.
The microphase adsorption ‐ spectral correction (MPASC) technique has been described and applied to the aggregation of trypan blue (TB) in proteins. The formation of the microelectrostatic field in protein causes the Langmuir monolayer aggregation of TB. The adsorption ratio of TB to bovine serum albumin (BSA), ovalbumin (OVA), hemoglobin (Hb) and human γ‐globulin (γ‐G) was determined to be 14.8, 8.4, 2.8 and 27.6, respectively, and the adsorption constant of the aggregates to be 7.17 × 105, 4.88 × 106, 4.85 × 106 and 2.99 × 106. The adsorption ratio of TB to proteins interestingly indicates almost no relation to the array sequence of amino acid residues. The interaction of TB with proteins is sensitive at pH 3.29, and the reaction was applied to the determination of protein trace with satisfactory results. 相似文献
996.
Jianwu Tian Bowen Li Fu Zhang Zhuo Yao Wentao Song Yufu Tang Yuan Ping Bin Liu 《Angewandte Chemie (International ed. in English)》2023,62(46):e202307288
The phototoxicity of photosensitizers (PSs) pre and post photodynamic therapy (PDT), and the hypoxic tumor microenvironment are two major problems limiting the application of PDT. While activatable PSs can successfully address the PS phototoxicity pre PDT, and type I PS can generate reactive oxygen species (ROS) effectively in hypoxic environment, very limited approaches are available for addressing the phototoxicity post PDT. There is virtually no solution available to address all these issues using a single design. Herein, we propose a proof-of-concept on-demand switchable photosensitizer with quenched photosensitization pre and post PDT, which could be activated only in tumor hypoxic environment. Particularly, a hypoxia-normoxia cycling responsive type I PS TPFN-AzoCF3 was designed to demonstrate the concept, which was further formulated into TPFN-AzoCF3 nanoparticles (NPs) using DSPE-PEG-2000 as the encapsulation matrix. The NPs could be activated only in hypoxic tumors to generate type I ROS during PDT treatment, but remain non-toxic in normal tissues, pre or after PDT, thus minimizing side effects and improving the therapeutic effect. With promising results in in vitro and in vivo tumor treatment, this presented strategy will pave the way for the design of more on-demand switchable photosensitizers with minimized side effects in the future. 相似文献
997.
998.
Dr. Joel E. Schmidt Donglong Fu Dr. Michael W. Deem Prof. Dr. Bert M. Weckhuysen 《Angewandte Chemie (International ed. in English)》2016,55(52):16044-16048
Zeolites, having widespread applications in chemical industries, are often synthesized using organic templates. These can be cost‐prohibitive, motivating investigations into their role in promoting crystallization. Herein, the relationship between framework structure, chemical composition, synthesis conditions and the conformation of the occluded, economical template tetraethylammonium (TEA+) has been systematically examined by experimental and computational means. The results show two distinct regimes of occluded conformer tendencies: 1) In frameworks with a large stabilization energy difference, only a single conformer was found (BEA, LTA and MFI). 2) In the frameworks with small stabilization energy differences (AEI, AFI, CHA and MOR), less than the interconversion of TEA+ in solution, a heteroatom‐dependent (Al, B, Co, Mn, Ti, Zn) distribution of conformers was observed. These findings demonstrate that host–guest chemistry principles, including electrostatic interactions and coordination chemistry, are as important as ideal pore‐filling. 相似文献
999.
We report a continuous-wave (CW) coherent green radiation at 532 nm by intracavity frequency doubling generation of 1064 nm
Nd:Gd0.18Y0.82VO4 laser. With incident pump power of 18.2 W, output power of 1.08 W at 532 nm has been obtained using a 5 mm-long KTP crystal.
The optical conversion efficiency was up to 5.9%. At the output power level of 1.08 W, the output stability is better than
5%. The beam quality M2 values were equal to 1.26 and 1.12 in X and Y directions, respectively. 相似文献
1000.