Microwave Assisted Synthesis of a New Triplet Iridium(III) Pyrazine Complex

采用微波辅助加热方法,2,3-二苯基吡嗪(DPP)与水合三氯化铱(IrCl₃·3H₂O)反应制备了[Ir(DPP)₃],通过¹H NMR、元素分析和质谱方法对配合物结构进行了表征,并研究了配合物的吸收光谱和光致发光光谱. 结果表明,配合物Ir(DPP)₃在382和504 nm处存在单重态¹MLCT(金属到配体的电荷跃迁)和三重态³MLCT的吸收;在573 nm 处有较强的金属配合物三重态的磷光发射.     

Bounds for the blowup time of the solutions to quasi-linear parabolic problems

In this paper, we obtain the lower and the upper bounds of the blowup time of the solutions to quasi-linear parabolic problems subject to Dirichlet(or Neumann) boundary condition. Our results are suitable for the problems with any smooth bounded domain ${\Omega \subset \mathbb{R}^n}$ and ${n \geq 3}$ . In some special cases, we can even get the exact values of blowup time.     

ISG-FHEV等效燃油消耗最小控制策略

针对室内复杂环境下火灾识别准确率会降低的问题,提出了一种改进的粒子群算法优化支持向量机参数进行火灾火焰识别的方法。首先在 颜色空间进行火焰图像分割,对获得的火焰图像进行预处理并提取相关特征量;其次采用PSO算法搜索SVM的最优核参数和惩罚因子,并在PSO算法中加入变异操作和非线性动态调整惯性权值的方法,加快了搜索SVM最优参数的精度和速度;然后将提取的火焰各个特征量作为训练样本输入SVM模型进行训练,并建立参数优化后的SVM分类器模型;最后将待测试样本输入SVM模型进行分类识别。算法的火灾识别准确率达到94.09%,分类效果明显优于其他分类算法。仿真结果表明,改进的PSO优化SVM算法提高了火焰识别的准确率和实时性,算法的自适应性更强,误判率更低。     

Quasi-maximum likelihood estimators in generalized linear models with autoregressive processes

The paper studies a generalized linear model(GLM)y_t = h(x_t~T β) + ε_t,t = l,2,...,n,where ε_1 = η_1,ε_1 =ρε_t +η_t,t = 2,3,...;n,h is a continuous differentiable function,η_t's are independent and identically distributed random errors with zero mean and finite variance σ~2.Firstly,the quasi-maximum likelihood(QML) estimators of β,p and σ~2 are given.Secondly,under mild conditions,the asymptotic properties(including the existence,weak consistency and asymptotic distribution) of the QML estimators are investigated.Lastly,the validity of method is illuminated by a simulation example.     

Constrained consensuses in disconnected topologies

This paper is concerned with the constrained consensuses problem for a group of agents in disconnected topologies. By dividing the communication topology into a combination of directed trees, some necessary and sufficient conditions are derived for all the agents to asymptotically reach a single consensus and multiple consensuses, respectively. The obtained results indicate that arbitrary anticipant consensuses can be achieved, if additional constrained controllers are added to those agents with specific indexes. Some illustrative examples are provided to demonstrate the effectiveness of the proposed theoretical results.     

四方晶系应变Si空穴散射机制

基于Fermi黄金法则及Boltzmann方程碰撞项近似理论, 推导建立了(001)弛豫Si_1-xGe_x衬底外延四方晶系应变Si空穴散射几率与应力及能量的理论关系模型, 包括离化杂质、声学声子、非极性光学声子及总散射概率(能量40 meV时)模型. 结果表明: 当Ge组分(x)低于0.2时, 应变Si/(001)Si_1-xGe_x材料空穴总散射概率随应力显著减小. 之后, 其随应力的变化趋于平缓. 与立方晶系未应变Si材料相比, 四方晶系应变Si材料空穴总散射概率最多可减小66%. 应变Si材料空穴迁移率增强与其散射概率的减小密切相关, 本文所得量化模型可为应变Si空穴迁移率及PMOS器件的研究与设计提供理论参考.     

量子势阱粒子群优化算法的改进研究

为提高量子势阱粒子群优化算法的优化能力, 通过分析目前量子势阱粒子群优化算法的设计过程, 提出了改进的量子势阱粒子群优化算法. 首先, 分别基于Delta势阱、谐振子和方势阱 提出了改进的量子势阱粒子群优化算法, 并提出了基于统计量均值的控制参数设计方法. 然后, 在势阱中心的设计方面, 为强调全局最优粒子的指导作用, 提出了基于自身最优粒子加权平均和动态随机变量的两种设计策略. 实验结果表明, 三种势阱粒子群优化算法性能比较接近, 都优于原算法, 且Delta势阱模型略优于其他两种.     

A Secret Sharing Scheme for Quantum Gray and Color Images Based on Encryption

This paper is concerned with the better security of quantum image secret sharing (QISS) algorithm. The improved QISS (IQISS) scheme is implemented on both quantum gray image (FRQI) and quantum color image (MCQI). The new IQISS scheme comprises efficient sharing process and recovering process. The core idea of the sharing process is to combine encryption and measurement for two types of quantum secret images to acquire the quantum shadow images. In the recovering process, strip operation is firstly utilized on the shadow images. Afterwards, the decryption algorithm is used to recover the original quantum secret image. Experiments demonstrate that significant improvements in the security are in favor of the proposed approach.

     

Structural, elastic, and electronic properties of orthorhombic NH3BH3: An ab initio study

At the generalized gradient approximation (GGA), the elastic constants of the orthorhombic phase of NH₃BH₃ were calculated with plane-wave pseudo-potential method. Our calculation showed that the orthorhombic phase NH₃BH₃ is a loose and brittle material, as well as hard to be deformed, also we calculated the elastic anisotropies and the Debye temperatures from the elastic constants. And from the band structure and density of state (DOS), we concluded that NH₃BH₃ is a wide-gap semiconductor and the band gap is almost 6.0 eV. The bonds between N atoms and H atoms show a strong covalent characteristic, B atoms and H atoms form ironic bonds, and so as to the B-N bonds. Electrons from the B atoms are absorbed by the H atoms around the B atoms, and the H atoms display electronegativity.     

Conceptualizing and organizing content for teaching and learning in selected Chinese, Japanese and US mathematics textbooks: the case of fraction division

In this study, selected Chinese, Japanese and US mathematics textbooks were examined in terms of their ways of conceptualizing and organizing content for the teaching and learning of fraction division. Three Chinese mathematics textbook series, three Japanese textbook series, and four US textbook series were selected and examined to locate the content instruction of fraction division. Textbook organization of fraction division and other content topics were described. Further analyses were then conducted to specify how the content topic of fraction division was conceptualized and introduced. Specific attention was also given to the textbooks’ uses of content constructs including examples, representations, and exercise problems in order to show their approaches for the teaching and learning of fraction division. The results provide a glimpse of the metaphors of mathematics teaching and learning that have been employed in Chinese, Japanese, and US textbooks. In particular, the results from the textbook analyses demonstrate how conceptual underpinnings were developed while targeting procedures and operations. Implications of the study are then discussed.