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991.
实验研究了大模面积光子晶体光纤飞秒激光器在近零色散点展宽脉冲锁模的束缚态运转.获得了双脉冲束缚态锁模,以及脉冲间隔不相等的多脉冲束缚态锁模,实验发现束缚态的子脉冲间距具有随机性.通过建立光纤锁模激光器的数值模型,分析了激光器束缚态锁模建立的动力学过程,在一定抽运强度下,激光器存在多个稳态,或者单脉冲运转,或者子脉冲间隔不相等的束缚态运转,这取决于锁模建立阶段半导体可饱和吸收镜(SESAM)对噪声信号的随机提取.并提出了抑制束缚态的方法,模拟得出此项技术可直接获得的最大单脉冲能量为19.6 nJ,考虑到40%左右的压缩损耗,可得到压缩至76 fs的最短脉冲,单脉冲能量为11.8 nJ.数值模拟结果能很好的与实验相符合. 相似文献
992.
K. I. Mikhailopulo T. S. Serchenya E. P. Kiseleva Yu. G. Chernov T. M. Tsvetkova N. V. Kovganko O. V. Sviridov 《Journal of Applied Spectroscopy》2008,75(6):857-863
We have used fluorescence spectroscopy methods to show that imidacloprid and its structural analogs form complexes with human
serum albumin (HSA). The nature of the spectral changes in the ligand×protein systems and the calculated complexation parameters
suggest that these low molecular weight compounds mainly bind to a specific section of the protein molecule, near the tryptophan
residue in the 214 position of the polypeptide chain. We have found that the association constants are on the order of 104 M−1, and the affinity of the ligands for HSA varies in the series 6-chloronicotinic acid > 6-methoxynicotinic acid = imidacloprid
> the keto analog of imidacloprid. The major contribution to the complexation energy probably comes from hydrophobic interaction
forces with participation of the aromatic pyridine ring of the ligands, while additional enhancement of ligand-protein affinity
can be provided by the nitroimine group of imidacloprid.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 6, pp. 859–866, November–December, 2008. 相似文献
993.
Shengkai Li Zhaotian Zhu Xinqi Cai Minghui Song Shen Wang Qing Hao Long Chen Zhuo Chen 《中国化学》2021,(6):1491-1497
Main observation and conclusion
Surface-enhanced Raman spectroscopy(SERS)-based bioanalytical technique involves the interaction of SERS-active substrate with c... 相似文献
994.
O. Daillant D. Boilley M. Josset B. Hettwig H. W. Fischer 《Journal of Radioanalytical and Nuclear Chemistry》2013,297(3):437-441
In literature quite a lot of data is available on uptake of radioactive caesium in mushrooms. There is less available on the evolution of concentration in fruitbodies after several years and on “outbound” transfer of radiocaesium from fruitbodies to their direct environment, i.e. dilution according to cooking techniques. The recent event at Fukushima has put the question of radionuclides in food, and the following exposure of consumers, high on the agenda. The purpose of this paper is twofold: (1) in order to investigate the variation in time of caesium uptake by fungi, analyses of the same species having grown on the same spot at different intervals during the last 25 years have been performed and (2) in terms of radiation protection the most important thing is the activity taken in by the consumer and not the contamination of raw products. Preparation can have a great impact on activity concentration. Various species of mushrooms frequently eaten have been sampled in Europe and contaminated areas in Japan. Different preparation techniques that can break the walls of the hyphae (drying, deepfreezing etc.) have been applied as well as different treatments: boiling or macerating in water with salt, in acid and basic media. The pH of different media was adjusted and measured. The samples and the medium were analysed separately in gamma spectrometry. 相似文献
995.
S. Friedrich C. R. Bates M. T. Burks O. B. Drury D. P. DiPrete 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(2):927-930
The difficulty to directly detect plutonium in spent nuclear fuel due to the high Compton background of the fission products motivates the design of a gamma detector with improved sensitivity at low energies. We have built such a detector by operating a thin high-purity Ge detector with a large scintillator Compton veto directly behind it. The Ge detector is thin to absorb just the low-energy Pu radiation of interest while minimizing Compton scattering of high-energy radiation from the fission products. The subsequent scintillator is large so that forward-scattered photons from the Ge detector interact in it at least once to provide an anti-coincidence veto for the Ge detector. For highest sensitivity, additional material in the line of sight is minimized, the radioactive sample is kept thin, and its radiation is collimated. We will discuss the instrument design, and demonstrate the feasibility of the approach with a prototype that employs two large CsI scintillator vetoes. Initial spectra of a thin Cs-137 calibration source show a background suppression of a factor of ~2.5 at ~100 keV, limited by an unexpectedly thick 4 mm dead layer in the Ge detector. 相似文献
996.
O. Merwitz H. M. Nitzsche E. Hochhäuser 《Isotopes in environmental and health studies》2013,49(4):319-322
Abstract The dose-dependent isotope fractionation during decarboxylation (13C/12C) amplifies the radiation effect in the relatively low dose range. The fractionation of the nitrogen isotopes during deamination (15N/14N) at the dose of 17 Gy was found to be smaller than that of decarboxylation. 相似文献
997.
A. I. Ryabchikov D. O. Sivin A. I. Bumagina V. K. Struts 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2013,7(6):1148-1155
It is experimentally revealed that the pulse-periodic bias potential provides a multifold decrease in the surface content of microparticles (MPs). It is ascertained that a decrease in the MP concentration at the target can be explained by several physical mechanisms. From experiments with a fine-structure grid, it is found that less than 10% of MPs negatively charged in the plasma can be reflected in the electric field of the charge-separation layer near the sample. A substantial decrease in the MP density occurs after direct interaction between a MP and the sample under the action of a negative HF short-pulse bias potential. Almost half the MP surface density is caused by ion sputtering. A twelvefold reduction in the MP surface density is attained when the target is irradiated for 2 min. 相似文献
998.
L. V. Sokolov A. A. Zhukov N. M. Parfenov S. O. Igoshin 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2013,7(1):178-180
The results of studying the formation of the three-dimensional micromechanical structure of an integral tensoconverter are presented. The technological restrictions on contact photolithography over the relief structure formed on the device layer of the silicon-on-insulator wafer are analyzed. The effect of the design parameters (the frame height and the width of the frame slit) are described. 相似文献
999.
1000.
G. K. Zahariou E. Gavrielatos I. M. Kalogeras G. Athanasellis A. Vassilikou-Dova O. Igglessi-Markopoulou 《辐射效应与固体损伤》2013,168(6-12):1057-1062
The 3-acyl tetramic acids constitute a growing class of natural products displaying a range of biological activities. The g , g ' tricarbonyl moiety present in the 3-acyl tetramic acid provides a suitable site for bidentate complexation to a metal, which increases the biological activity. For the dielectric study of N-acetyl-3-butanoyl tetramic acid and a series of its complexes with Cu(II) and Co(II) in symmetric and asymmetric forms, we used the Thermally Stimulated Depolarization Currents (TSDC) technique. The drastic decrease of the intensity of the TSDC peaks of the symmetric and asymmetric complexes, compared to the above mentioned ligand, suggested that the polarizability of the side groups is considerably reduced. This result enhances the proposed complexation mode of the ligand through oxygen next to carbons 3 and 4 of the 5-member ring. 相似文献