Synthesis of cryptands with one carbon and one nitrogen bridgehead atom

Two novel cryptands which each contains one carbon and one nitrogen atom at the bridgehead positions are synthesized and found to form strong complexes with lithium cations.     

A study of hadronic decays of the ϒ′

We present a detailed study of the decays ?′ → π⁺π^?? and ?′ → π⁰π⁰?, where the ? decays subsequently to e⁺e^? or μ⁺μ^?. The results are obtained from a sample of 146 000 ?′ decays observed with the CUSB detector at the Cornell Electron Storage Ring. We derive branching fractions of (18.9 ± 2.6)% for ?′ → π′π^?? and (10.3 ± 2.3)% for ?′ → π⁰π⁰?, and determined partial widths for these decays. Invariant mass and angular distributions of both the π⁺π^? and π⁰π⁰ systems are presented. We also set a limit on the branching fraction for ?′ → η? of less than 0.2% at the 90% confidence level.     

Biflavone glucosides from Ginkgo biloba yellow leaves

Phytochemical investigation of Ginkgo biloba (Ginkgoaceae) has resulted in the isolation of two new biflavone glucosides, ginkgetin 7'-O-beta-D-glucopyranoside (1) and isoginkgetin 7-O-beta-D-glucopyranoside (2). The structures were determined on the basis of chemical and spectroscopic evidences.     

Synthesis of monodisperse chromium nanoparticles from the thermolysis of a Fischer carbene complex

We successfully synthesized monodisperse chromium nanoparticles from the thermolysis of a Fischer carbene complex.     

Pi-bonded quinonoid transition-metal complexes

Coordination of the carbocyclic ring of hydroquinones to electrophilic transition-metal fragments such as Mn(CO)3+ and Rh(COD)+ produces stable pi-bonded eta6-complexes that are activated to facile reversible deprotonation of the -OH groups. The deprotonations are accompanied by electron transfer to the transition metal, which acts as an internal oxidizing agent or electron sink. With manganese as the metal, the resulting eta5-semiquinone and eta4-quinone complexes have been used to synthesize one- two- and three-dimensional polymeric metal-organometallic coordination networks. With rhodium as the metal, the pi-quinonoid complexes have been demonstrated to play a unique role in multifunctional C-C coupling catalysis and in the synthesis of new organolithium reagents. Both classes of pi-quinonoid complexes appear to have significant applications in nanochemistry by providing an excellent vehicle for templating the directed self-assembly of nanoparticles into functional materials.