The unsteadiness of shock waves propagating through gas-particle mixtures

A shock wave which is incident onto a gas-particle mixture or initiated within such a mixture needs a certain distance to reach a constant velocity. This effect is due to the inertia and the heat capacity of the particles. In general the shock wave is decelerated and the frozen pressure jump is decaying. A vertical shock tube was used in order to produce a plane shock wave incident onto a homogeneous gas-particle mixture. In addition to measurements of the shock velocity and the pressure history along the total low pressure section, the particle velocity was measured within the relaxation zone far downstream of the diaphragm using a laser-Doppler-velocimeter. Thus a drag law describing the particle acceleration within the relaxation zone was derived from the measurements. To compare the experiments with theoretical results, calculations were performed by the random-choice method.     

Experimental studies on particle behaviour and turbulence modification in horizontal channel flow with different wall roughness

Detailed measurements in a developed particle-laden horizontal channel flow (length 6 m, height 35 mm, the length is about 170 channel heights) are presented using phase-Doppler anemometry for simultaneous determination of air and particle velocity. The particles were spherical glass beads with mean diameters in the range of 60 µm-1 mm. The conveying velocity could be varied between about 10 m/s and 25 m/s, and the particle mass loading could reach values of about 2 (the mass loading is defined as the ratio of particle to gas phase mass flow rates), depending on particle size. For the first time, the degree of wall roughness could be modified by exchanging the wall plates. The influence of these parameters and the effect of inter-particle collisions on the profiles of particle mean and fluctuating velocities and the normalised concentration in the developed flow were examined. It was shown that wall roughness decreases the particle mean velocity and enhances fluctuating velocities due to irregular wall bouncing and an increase in wall collision frequency, i.e. reduction in mean free path. Thereby, the larger particles are mainly more uniformly distributed across the channel, and gravitational settling is reduced. Both components of the particle velocity fluctuation were reduced with increasing mass loading due to inter-particle collisions and the momentum loss involved. Moreover, the effect of the particles on the air flow and the turbulent fluctuations was studied on the basis of profiles in the developed flow and turbulence spectra determined for the streamwise velocity component. In addition to the effect of particle size and mass loading on turbulence modulation, the influence of wall roughness was analysed. It was clearly shown that increasing wall roughness also results in a stronger turbulence dissipation due to two-way coupling.     

Investigation of droplet collisions for solutions with different solids content

The collision behaviour of droplets and the collision outcome are investigated for high viscous polymer solutions. For that purpose, two droplet chains produced by piezoelectric droplet generators are directed towards each other at a certain angle so that individual droplet pairs collide. For recording the collision event, one double-image and one high-speed CCD camera were used. One camera is positioned perpendicular to the collision plane recording the outcome of the collision, and the second camera is aligned parallel to the collision plane to assure that the droplet chains are exactly in one plane. A new approach for tracking droplets in combination with an extended particle tracking velocimetry algorithm has been developed. Time-resolved series of pictures were used to analyse the dynamics of droplet collisions. The three different water soluble substances were saccharose and 1-Ethenyl-2-pyrrolidone (PVP) with different molecular weights (K17, K30). The solvent was demineralised water. The solids contents ranged from 20 to 60 %, 5 to 25 % and 5 to 35 %, yielding dynamic viscosities in the range of 2–60 mPa s. Results were collected for different pairs of impact angles and Weber numbers in order to establish common collision maps for characterising the outcomes. Here, relative velocities between 0.5 and 4 m/s and impact parameters in the interval from 0 to 1 for equal-sized droplets (Δ = 1) have been investigated. Additionally, satellite formation will be discussed exemplarily for K30. A comparison with common models of different authors (Ashgriz and Poo in J Fluid Mech 221:183–204, 1990; Estrade et al. in Int J Heat Fluid Flow 20:486–491, 1999) mainly derived for low viscous droplets revealed that the upper limit of their validity is given by an Ohnesorge number of Oh = 0.115 and a capillary number of Ca = 0.577. For higher values of these non-dimensional parameters and hence higher dynamic viscosities, these models are unable to predict correctly the boundaries between collision scenarios. The model proposed by Jiang et al. (J Fluid Mech 234:171–190, 1992), which includes viscous dissipation, is able to predict the boundary between coalescence and stretching separation for higher viscosities (i.e. Oh > 0.115 and Ca > 0.577). However, the model constants are not identical for different solution properties. As a conclusion, an alteration of the collision appearance takes place because of the relative importance between surface tension and viscosity.     

Dehydroalanine-Containing Peptides by AcOH-Elimination from O-Acetylserine Residuces with DBU/LiClO4 in Tetrahydrofuran

The elimination of H₂O from serine residues in peptides was found to be feasible by the following two steps: O-acylation with AcCl/pyrideine in CH₂Cl₂ and treatment with an imidine base (DBU or DBN) in THF in the presence of large amounts of LiClO₄ (10 examples). Other Li salts such as LiBr and LiCl can also be used. No epimerization of the amino acid residues in te peptide could be detected under these conditions. Thus, a simple method for the preparation of peptides with dehydroalanine residues in high yield, directly from serine-containing precursors, is available.     

Critical current measurement on Y-Ba-Cu-O

We report critical current measurements on sintered Y_0.35Ba_0.65CuO_y. The sample, in the perovskite phase, shows zero resistance at 87 K. The critical current transition is seen, in zero field and at 77 K, at a current densityJ _c of 50 A/cm².