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31.
The synthesis of 2-(3-(4-(dimethylamino)phenyl)-2-oxoindolin-3-yl)-1H-indene-1,3(2H)-diones as new unsymmetrical oxindoles via a Friedel-Crafts type three-component reaction of 1,3-indandion, N,N-dimethylaniline and isatins in ethanol in the presence of LiClO4 is reported. 相似文献
32.
Magnesium oxide nanopartticels in average size between 35–120 nm were prepared by sonochemistry method. Synthesis of polyhydroquinoline derivatives using MgO nanoparticles from the reaction of dimedone, benzaldehyde, ethyl acetoacetate and ammonium acetate under solvent‐free conditions is reported. Easy handling, reusability, thermal stability and non‐toxicity of the catalyst make the present protocol as an eco‐friendly and economically acceptable method for synthesis of these heterocycles. 相似文献
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In this study, a soft method is proposed to calculate concentration and spectral profiles for the two‐way spectral data from dissociation equilibria of polyprotic acids (HnA). This method has four main distinct steps: (i) a fixed size moving window evolving factor analysis (FSMWEFA) was used to identify the local rank map, (ii) WFA was applied to calculate the concentration profiles of HnA and An− (selection of the window for application of WFA was performed using EFA), (iii) PVA was used to calculate Hn − 1A to HA spectral profiles, and (iv) a symmetry constraint, in addition to the non‐negativity constraint, was utilized to obtain the unique concentration and spectral profiles from different acceptable sets of profiles. In the absence of any selective region in the spectral data, the proposed soft method resulted in unique solution without rotational ambiguity. This study is the first application of symmetry constraint on concentration profiles. The rotational ambiguity drastically decreased on considering the constraint of symmetry of the Hn − 1A and HA concentration profiles, in addition to non‐negativity of profiles. Simulated examples were used to confirm these approaches. Effect of closeness of dissociation constants on the estimated values of constants was investigated. The results showed that when the difference between pKa values is more than 1.2, the obtained errors in the estimation of pKa values are less than about 6.5%. The considered real data were from pH‐metric titration of fluorescein. The obtained spectral and concentration profiles and the estimated pKa values for fluorescein were in good agreement with the previously reported data. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
34.
A partial second-order subdifferential is defined here for extended real valued functions of two variables corresponding to its variables through coderivatives of first-order partial subdifferential mappings. In addition, some rules are presented to calculate these second-order structures along with defining some conditions to insure the equality \(\partial ^2_{yx}\) and \(\partial ^2_{xy}\). Moreover, as an application, some conditions are stated which show the relation between local minimum of a function and positiveness of principal minors of its hessian matrix. 相似文献
35.
A La3+ doped Co3O4 nanocube modified graphite screen-printed electrode (La3+-doped Co3O4 nanocube/SPE) was prepared and utilized for the sensitive voltammetric determination of bisphenol A. In comparison with an unmodified electrode, the presence of the La3+ doped Co3O4 nanocubes caused a significant enhancement in the peak current. Differential pulse voltammetry (DPV), cyclic voltammetry (CV), and chronoamperometry approaches were utilized as diagnostic methods. The modified SPE was used to determine bisphenol A concentrations in the range from 0.5 to 900.0?μM with a limit of detection equal to 6.1?×?10?8 M. Real samples were effectively analyzed with the modified electrode. 相似文献
36.
Somayeh Fotoohi Mohammad Kazem Moravvej-Farshi Rahim Faez 《Applied Physics A: Materials Science & Processing》2014,116(4):2057-2063
Using density functional theory combined with non-equilibrium Green’s function method, we have investigated the electronic and transport properties of graphenes defected by one and two carbon ad-dimers (CADs), placed parallel to the graphene lattice. Addition of these CADs to graphenes creates 3D paired pentagon–heptagon defects (3D-PPHDs). The band structure, density of states (DOS), quantum conductance, projected DOS, as well as the current–voltage characteristic per graphene super-cells containing each type of 3D-PPHD are calculated. The local strain introduced to graphene by 3D-PPHDs forces the C-bonds in the dimers to hybridize in sp 3-like rather than sp 2-like orbitals, creating localized states at the center of the corresponding defect below the Fermi energy. Simulations show that the zero-bias conductances per super-cells containing defects created by one and two CADs exhibit dip about ~0.579 and ~0.253 eV below their corresponding Fermi levels, respectively. These can be attributed to the localized states around the same energy levels. Simulations also show that the enhanced carriers scatterings within the graphenes defected by the 3D-PPHDs have increased their overall resistances, as compared with the pristine graphene. Moreover, the current–voltage characteristic calculated per super-cell for each case shows that the current for those containing one and two CADs, at an applied voltage of 0.5 V, is ~5 and 13 % less than the current calculated for the pristine super-cell of the same size. 相似文献
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38.
Teimuri-Mofrad Reza Ahadzadeh Iraj Gholamhosseini-Nazari Mahdi Esmati Somayeh Shahrisa Aziz 《Research on Chemical Intermediates》2018,44(4):2913-2927
Research on Chemical Intermediates - In this research, for the first time, aminonaphthol derivatives were introduced as efficient corrosion inhibitors. A linear polarization method was employed to... 相似文献
39.
Somayeh Hashemi-Uderji Mohammad Abdollahi-Alibeik 《Journal of the Iranian Chemical Society》2018,15(8):1709-1719
A three-component process for the one-pot synthesis of 6-amino-4-aryl-5-cyano-3-methyl-1-phenyl-1,4-dihydropyrano[2,3-c]pyrazoles by the reaction of aldehydes, 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one, and malononitrile in the presence of FSM-16-SO3H as an efficient mesoporous catalyst. The FSM-16-SO3H was prepared and characterized by SEM, XRD, BET, and FT-IR techniques. The advantages of the presented method are high yields, short reaction times, easy purification of products, easy work-up, and reusability of the catalyst. 相似文献
40.
Sima Ahmadi Mohammad Taghi Hamed Mosavian Somayeh Heydari 《Journal of the Iranian Chemical Society》2018,15(11):2605-2614
A rapid and simple approach for the preconcentration and determination of catechin from pistachio green hull samples has been proposed by surfactant-assisted dispersive liquid–liquid microextraction followed by UV–Vis spectrophotometry (SADLLME/UV–Vis). This method involved the formation of a catechin complex with cetylpyridinium chloride (CPC) as cationic surfactant, and subsequently, DLLME was applied to extract the catechin–CPC complex into chloroform. Different parameters affected the extraction efficiency were optimized by central composite design (CCD) and response surface methodology (RSM). In optimum condition, the calibration curve was linear in the range of 0.4–5 µg mL??1 of catechin with correlation coefficient of 0.9982. The relative standard deviation based on five replicated analyses of 1 µg mL??1 catechin was 1.85%. The proposed method was successfully applied for preconcentration and determination of trace amounts of catechin in pistachio hull samples. 相似文献