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381.
Abstract The current review covers explosive development of various synthetic approaches for piperidine scaffold and its analogues in the last few decades. The piperidine ring system is a key motif in many natural alkaloids and synthetic organic compounds. Further, piperidine moiety has gained significant consideration in drug discovery due to its wide range of therapeutic applications. 相似文献
382.
Polycrystalline LaFe1?xNixO3 (x = 0.0, 0.1, 0.3 and 0.5) have been prepared by the standard solid state reactions method. The phase formation has been confirmed by the powerful synchrotron X-ray diffraction experiment. In order to investigate the effects of Ni doping on the oxidation state, spin state and the magnetic ordering of the iron cations, 57Fe Mössbauer Spectroscopy has been carried out at room temperature. Iron is present as Fe3+ in high spin state in LaFeO3. Ni doping has no effect on the spin state of the Fe3+ cations. However, a progressive increase in the concentration of Fe4+ cations has been inferred. Relatively stronger covalent character of the Fe4+–O?2 bond causes a progressive collapse in the magnetic ordering and delocalization of the hole states. 相似文献
383.
Rehana Saeed Syed Muhammad Saqib Nadeem 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(6):1143-1150
The kinetics of the electron transfer reaction of methylene green and titanium trichloride was investigated in different solvents by spectrophotometry at different temperatures. The the reaction rate was determined by monitoring the absorbance as a function of time at λmax 655 nm. The reaction is pseudo-first order, dependent only on the concentration of titanium trichloride at a fixed concentration of methylene green. 相似文献
384.
Nadeem Raza Waseem Raza Zafar Iqbal Zafar R. V. Kumar 《Russian Journal of Applied Chemistry》2016,89(5):836-845
Zinc bearing wastes such as electric arc furnace dust (EAFD) obtained from steel making constitute an important resource for zinc extraction. Inclusion of heavy metals such as Pb, Cd, Cu, Cr, Ni, etc., in these wastes makes them hazardous to use and/or dispose. In the present research work, leaching kinetics of EAFD with sulfuric acid has been investigated and various experimental parameters such as concentration of lixiviant, stirring rate, sample particle size, liquid/solid proportion, and temperature of the reaction have been optimized. It has been found that the dissolution rate of EAFD increases with rise in temperature, acidic strength, rate of stirring, liquid to solid proportion and with reduction in EAFD particle size. From the analysis of leaching kinetic data by means of graphical and statistical methods, it has been evaluated that the leaching kinetics of EAFD is dictated by surface diffusion reaction. Apparent energy of activation for the leaching reaction of EAFD with sulfuric acid is found to be 13.1 kJ mol–1 within the temperature range of 308 to 358 K. 相似文献
385.
Synthesis and Characterization of Melamine Formaldehyde Resins for Decorative Paper Applications
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S. Ullah M. A. Bustam F. Ahmad M. Nadeem M. Y. Naz M. Sagir A. M. Shariff 《中国化学会会志》2015,62(2):182-190
Melamine‐formaldehyde (MF) resins of improved environmental compatibility were synthesized at different molar ratios, temperature and pH. Five molar ratios of melamine and formaldehyde: 35:65, 36.5:63.5, 38.3:61.7, 41.1:58.9 and 42.4:58.6 were used to synthesize the corresponding resins. The prepared samples were characterized by using molecular weight determination viscometery, field emission scanning electron microscopy and thermogravimetric analysis. It was noticed that the solid content in the resin increases with an increase in pH. The maximum percentage of the solid content (51 %) was obtained for pH of 8.5 and temperature range of 95–98 oC. The refractive index of the final product was found increasing with an increase of melamine concentration in the resin. A similar trend was noticed in molecular weight of the resins with an increase in monomer yield. The maximum molecular weight of 114218 was obtained from the sample synthesized with MF molar ratio of 42.4:58.6. 相似文献
386.
Particle Tracking Velocimetry (PTV) is one of the evolving techniques which can cover the increasing need for measurements in a Lagrangian frame. Here some recent developments and the validation of the tracking scheme on the Kinematic Simulation Inertial Model (KSIM) test flow field is presented. 相似文献
387.
This review updates the explosive development of gold catalysis for organic transformation focusing on the current literature over last 3 years. Recent investigations have shown that gold catalysis provides catalytically active systems, whereas selectivity and reusability are advantages over noncatalyzed organic transformations. The collected literature is focusing for new organic reactions and synthetic methodologies. Gold can also be suggested for green processes dedicated to fine chemicals, pharmaceuticals, and the food industry due to its recognized biocompatibility. The current review is focused on new methods in the organic synthesis that could be of interest in the wide area of organic chemistry for developing new catalytic pathways. 相似文献
388.
Unstable mode of ion-acoustic waves with two temperature q-nonextensive distributed electrons
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The linear characteristics of the unstable mode of ion-acoustic waves are examined in an electrostatic electron-ion plasma composed of streaming hot electrons, non-streaming cold electrons and dynamical positive ions. The plasma under consideration is modeled by using a non-gyrotropic nonextensive q-distribution function in which the free energy source for wave excitation is provided by the relative directed motion of streaming hot electrons with respect to the other plasma species. In the frame work of kinetic model, a linearized set of Vlasov–Poisson's equations are solved to obtain the analytical expressions for dispersion relation and Landau damping rate. The threshold condition for the unstable ionacoustic wave is derived to assess the stability of the wave in the presence of nonextensive effects. Growth in the wave spectrum and nontrivial effects of q-nonextensive parameter on the ion-acoustic waves can be of interest for the readers in the regions of Saturns' s magnetosphere. 相似文献
389.
Muhammad Nadeem Md. Shakilur Rahman Muhammad Shahid Guinyun Kim Haladhara Naik Nguyen Thi Hien 《中国物理C(英文版)》2021,45(12):124002-124002-14
The flux-weighted average cross sections of natCd(γ, xn)115g,m,111m,109,107,105,104Cd and natCd(γ, x)113g,112,111g,110mAg reactions were measured at the bremsstrahlung end-point energies of 50 and 60 MeV. The activation and off-line γ-ray spectrometric technique was carried out using the 100 MeV electron linear accelerator at the Pohang Accelerator Laboratory, Korea. The natCd(γ, xn) reaction cross sections as a function of photon energy were theoretically calculated using the TALYS-1.95 and the EMPIRE-3.2 Malta codes. Then, the flux-weighted average cross sections were obtained from the theoretical values of mono-energetic photons. These values were compared with the flux-weighted values from the present study and were found to be in general agreement. The measured experimental reaction cross-sections and integral yields were described for cadmium and silver isotopes in the natCd(γ, xn)115g,m,111m,109,107,105,104Cd and natCd(γ, x)113g,112,111g,110mAg reactions. The isomeric yield ratio (IR) of 115g,mCd in the natCd(γ, xn) reaction was determined for the two bremsstrahlung end-point energies. The measured isomeric yield ratios of 115g,mCd in the natCd(γ, xn) reaction were also compared with the theoretical values of the nuclear model codes and previously published literature data of the 116Cd(γ, n) and 116Cd(n, 2n) reactions. It was found that the IR value increases with increasing projectile energy, which demonstrates the characteristic of excitation energy. However, the higher IR value of 115g,mCd in the 116Cd(n, 2n) reaction compared to that in the 116Cd(γ, n) reaction indicates the role of compound nuclear spin alongside excitation energy. 相似文献
390.
We report oscillator strengths distribution in the bound region of cadmium corresponding to the 5s5p 3P1 → 5snd 3D2 (21 ≤ n ≤ 52) Rydberg transitions. The experiment was performed using two frequency doubled dye lasers simultaneously pumped by a common Nd:YAG laser in conjunction with an atomic beam set-up. The absolute photoionization cross section of the 5s5p 3P1 intermediate state at the 5s 2S1/2 ionization threshold has been measured as 20 (4) Mb using the saturation technique. The measured value of the photoionization cross section at threshold is used to extract the f-values of the above mentioned Rydberg transitions. 相似文献