Deuterium isotope effect in (+)-glutamic acid hydrochloride

A study of the effects of deuterium substitution in (+)-glutamic acid hydrochloride is described. Solid state vibrational spectra depicting band shifts resulting from deuterium indicate that interatomic bond distances remain virtually unchanged. The cell volume expands only 0.05% upon deuteration, while the macroscopic linear and nonlinear polarizabilities are unaffected. The optical nonlinearity is therefore ascribed to the electronic nature of the hydrogen bonds.     

Improved separation method for determining actinides in soil samples

Radionuclides have been identified as a significant source of contamination at many United States Department of Energy (DOE) sites. As a result, reliable and accurate methods to determine actinide content in environmental samples have become increasingly important. Therefore, an improved analytical scheme using a series of actinide-selective extraction chromatography (Tru-Spec, Teva-Spec) and ion-exchange (Diphonix) resins was designed to satisfy the requirements of both alpha spectrometry and inductively coupled plasma mass spectrometry (ICP-MS). Alpha spectrometry required the sequential isolation of the actinides, whereas ICP-MS required only a group separation of the actinides. The separation schemes were designed to allow analysis of the actinides in soil, whether the soils were acid leached or totally dissolved through fusion. For those analytes present as contaminants (^239/240Pu,²⁴¹Am), the laboratory results agreed favorably with the accepted values for several reference soils. However, for the acid digestion procedure, the results for matrix constitutents (²³⁸U,²³⁴U,²³²Th) were quite low because the silicate matrix was not decomposed. The sodium hydroxide fusion technique described allowed accurate analysis of both matrix constituents and contaminants because a total dissolution was achieved.     

Particle flow in a jet

The angular distribution of hadrons in a jet is evaluated in perturbative QCD. The predictions are restrictive in the sense they do no depend on the details of the non-perturbative process. The distribution depends on only one phenomenologically adjustable parameter, a cutoff massQ ₀ (in addition to the universal QCD mass-scale ). The fit of the leading order prediction to the TASSO data is obtained withQ ₀270 MeV.The low value ofQ ₀ supports the hypothesis of local partonhadron duality. The particle flow in a gluon jet is also analysed.     

Structure of 2,2′-bis(3-allyl-4-cyanatophenyl)isopropylidene

The structure of the title compound (I) was determined by direct methods using MoK diffractometer data, and refined by full-matrix least squares toR=0.066 for 1536 reflections (I3 (I)). The structure shows a central tetrahedral carbon atom surrounded by two methyl and two 3-allyl-4-cyanatophenyl groups. The geometry of the cyanato group in this molecule compares well with those in 2,2-bis(4-cyanatophenyl)isopropylideneII) and 4-chloro-3,5-dimethyl-phenylcyanate (III), the only other examples of organic compounds bearing the cyanato moiety in the Cambridge Crystallographic Database (V.3).