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21.
An acoustic field effectively affects chromatographic retention in some separation modes and, thus, can be a novel factor controlling retention. After being transmitted into the column, ultrasound energy is mostly converted into heat as a result of absorption by stationary and mobile phases. Thus, ultrasound brings about temperature increases. However, actual temperature increases measured by thermosensors are smaller than those calculated from chromatographic retention changes. In addition, larger ultrasound effects are observed in chromatographic modes involving ionic interactions. These results possibly imply that ultrasound directly influences ionic interactions involved in retention mechanisms. 相似文献
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Stanisaw Kozdrowski Pawe Cichosz Piotr Paziewski Sawomir Sujecki 《Entropy (Basel, Switzerland)》2021,23(1)
Increasing demand in the backbone Dense Wavelength Division (DWDM) Multiplexing network traffic prompts an introduction of new solutions that allow increasing the transmission speed without significant increase of the service cost. In order to achieve this objective simpler and faster, DWDM network reconfiguration procedures are needed. A key problem that is intrinsically related to network reconfiguration is that of the quality of transmission assessment. Thus, in this contribution a Machine Learning (ML) based method for an assessment of the quality of transmission is proposed. The proposed ML methods use a database, which was created only on the basis of information that is available to a DWDM network operator via the DWDM network control plane. Several types of ML classifiers are proposed and their performance is tested and compared for two real DWDM network topologies. The results obtained are promising and motivate further research. 相似文献
25.
Microstructure of nickel nanoparticles embedded in carbon films: case study on annealing effect by micromorphology analysis
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Ştefan Ţălu Miroslaw Bramowicz Slawomir Kulesza Azizollah Shafiekhani Maryam Rahmati Atefeh Ghaderi Mohammad Ahmadirad Shahram Solaymani 《Surface and interface analysis : SIA》2017,49(3):153-160
The presented study is aimed at analyzing the surface texture of amorphous hydrogenated carbon layers containing nickel nanoparticles (Ni‐NPs@a‐C:H) within their structure, which were deposited by Radio Frequency (RF) sputtering and RF‐Plasma Enhanced Chemical Vapor Deposition (RF‐PECVD) methods on glass substrates. Prepared films were then used as research material following their annealing at two different temperatures of 250 °C and 350 °C in an inert argon atmosphere. Series of height samples were taken with the help of atomic force microscopy (AFM) operating in a non‐contact mode and examined in order to determine their fractal characteristics. Raw AFM data were first plane‐fitted to remove the surface bow exhibiting the so‐called residual surface, and then numerically processed to calculate the Areal Autocorrelation Function (AACF), which was later used to compute the Structure Function (SF). The log–log plots of the latter served for calculation of fractal properties of surfaces under investigation, including fractal dimension D, and pseudo‐topothesy K. The analysis of 3‐D surface texture helps to understand their essential characteristics and their implications as well as graphical models and their implementation in computer simulation. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
26.
Slawomir Borysiak 《Journal of Thermal Analysis and Calorimetry》2010,101(2):439-445
The interest in lignocellulosic composites has been growing in recent years because of their specific properties. In this
study, a new technique of wood treatment using γ-irradiation was used. This research focuses on the influence of the gamma
irradiation on the chemical composition of wood and on the nucleation ability of polypropylene matrice. The inner morphology
of the transcrystalline layer was investigated using hot stage optical microscopy. Differential scanning calorimetry was used
to investigate the kinetic parameters of polypropylene crystallization in the presence of wood surface. The results showed
that the gamma irradiation can decrease the content of the cellulose in the wood, but it has a slightly negative effect on
the transcrystallization process of polypropylene. This treatment also affects the crystal conversion and the half-time of
PP crystallization. These results suggested that the gamma irradiation of wood may play a useful role in changing the microstructure
of the matrice near the wood. It was observed that the nucleation of the wood surface was selective, indicating that the chemical
characteristics of the lignocellulosics might have influence on the polypropylene crystallization. A possible mechanism for
the appearance of transcrystallinity involving chemical composition of lignocellulosic is also proposed. 相似文献
27.
Slawomir Cynk 《代数通讯》2013,41(8):4097-4102
Let B be a surface of even degree d in P3 with nodes as the only singular points. In [1] Clemens proved that the topology of the small resolution of the double covering of P3 branched along B depends not only on the number of nodes but also on the so-called defect, a non-negative integer describing their configuration. The aim of this note is to give an elementary proof of the Clemens. result and to present some geometric interpretation of defect. 相似文献
28.
In this paper, the numerical modelling of the flow through the low‐pressure steam turbine last stage was presented. On the basis of predicted wet steam flow‐field, the aerodynamic as well as thermodynamic losses were estimated. For calculations of the wet steam steady flow‐field three numerical methods were employed. The first method was a streamline curvature method (SCM). The commercial CFD code (CFX‐TACflow) and an in‐house code, both solving the 3‐D RANS equations, were the next two methods. In the wet steam region, by means of all three methods, the equilibrium flow was modelled. Additionally, the in‐house CFD code was used for modelling of the non‐equilibrium steam condensing flow. In this work, the comparison of the cascade loss coefficient for stator and rotor and selected flow parameters for the stage were presented, compared and discussed. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
29.
Slawomir Kwasik 《Commentarii Mathematici Helvetici》1986,61(1):415-428
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The ground‐state electronic structure of peroxynitrous acid (HOONO) and its singlet biradicaloid form (HO ··· ONO) have been studied using topological analysis of the electron localization function (ELF), together with the electron localizability indicator (ELI‐D), at the DFT (B3LYP, M05, M052X, and M06), CCSD, and CASSCF levels. Three isomers of HOONO (cis‐cis, cis‐perp, and trans‐perp) have been considered. The results show that from all functionals applied, only B3LYP yields the correct geometrical structure. The ELF and ELI‐D‐topology of the O? O and central N? O bonds strongly depends on the wave function used for analysis. Calculations carried out at CAS (14,12)/aug‐cc‐pVTZ//CCSD(T)/aug‐cc‐pVTZ level reveal two bonds of the charge‐shift type: a protocovalent N? O bond with a basin population of 0.82–1.08e, and a more electron depleted O? O bond with a population of 0.66–0.71e. The most favorable dissociation channel (HOONO → HO + ONO) corresponds to breaking of the most electron‐deficient bond (O? O). In the case of cis‐ and trans‐HO ··· ONO, the ELF, ELI‐D, and electron density fields results demonstrate a closed‐shell O ··· O interaction. The α‐spin electrons are found mainly (0.64e) in the lone pairs of oxygen Vi = 1,2 (O) from the OH group. The β‐spin electrons are delocalized over the ONO group, with the largest concentration (0.34e) on the lone pair of nitrogen V(N). © 2011 Wiley Periodicals, Inc. J Comput Chem, 2011 相似文献