全文获取类型
收费全文 | 1527篇 |
免费 | 66篇 |
国内免费 | 2篇 |
专业分类
化学 | 1038篇 |
晶体学 | 6篇 |
力学 | 19篇 |
数学 | 213篇 |
物理学 | 319篇 |
出版年
2024年 | 2篇 |
2023年 | 12篇 |
2022年 | 40篇 |
2021年 | 49篇 |
2020年 | 40篇 |
2019年 | 43篇 |
2018年 | 29篇 |
2017年 | 28篇 |
2016年 | 77篇 |
2015年 | 50篇 |
2014年 | 62篇 |
2013年 | 64篇 |
2012年 | 125篇 |
2011年 | 145篇 |
2010年 | 109篇 |
2009年 | 64篇 |
2008年 | 99篇 |
2007年 | 133篇 |
2006年 | 76篇 |
2005年 | 64篇 |
2004年 | 53篇 |
2003年 | 37篇 |
2002年 | 27篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 14篇 |
1998年 | 9篇 |
1997年 | 5篇 |
1996年 | 12篇 |
1995年 | 18篇 |
1994年 | 16篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1935年 | 1篇 |
1905年 | 3篇 |
1904年 | 2篇 |
排序方式: 共有1595条查询结果,搜索用时 15 毫秒
131.
132.
Lai C. Chan Brian G. Cox Ian C. Jones Simone Tomasi 《Journal of Physical Organic Chemistry》2011,24(9):751-763
A detailed kinetic analysis and computational study of an SNAr reaction between 2,5,6‐trifluoronicotinonitrile, 2 , and the ambident 3‐isopropoxy‐1H‐pyrazol‐5‐amine, 3 , is presented. The selectivity with respect to the reaction at the primary amino group of 2 , to give the desired product, 2,5‐difluoro‐6‐[(3‐isopropoxy‐1H‐pyrazol‐5‐yl)amino]nicotinonitrile, 1 , is strongly dependent upon reaction conditions. Reaction is found to proceed via both uncatalysed and base catalysed routes, and selectivity towards 1 is strongly enhanced in the presence of the base diazabicyclo[2,2,2]octane (DABCO). Computational studies in tetrahydrofuran solution at the B3LYP/6‐31G* level of theory have provided valuable insight into alternative kinetically indistinguishable reaction pathways. The results suggest that for reaction at the primary amino group, proton removal by DABCO accompanying amine addition allows avoidance of a high‐energy, zwitterionic Meisenheimer intermediate. Reactions at the alternative pyrazole nitrogen atoms are less sensitive to the presence of base because of stabilisation of the Meisenheimer zwitterions by intramolecular hydrogen bonding. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
133.
We report on improved and controlled light outcoupling of transparent organic light-emitting diodes (TOLEDs) by inserting thin silver layers between the indium tin oxide anode and the hole transporting layer. The introduction of Ag layers influences both the bottom and top emission of the TOLEDs, and it results in dramatic changes in the electroluminescence spectra and angular distribution. We find that the overall external quantum efficiency can be increased up to 18.8%, and the ratio of bottom and top emission can be almost identical. 相似文献
134.
We investigate a set of transparent organic LEDs (TOLEDs) with different organic capping layer (OC) thicknesses to understand the capping layer effect. We find that thickness variation of the OC strongly influences the emission properties of TOLEDs and exhibits different trends for top or bottom emission. The external quantum efficiency for the top side can be enhanced by a factor of 63%, but that of the bottom side only by 4% compared to a reference device without an OC. Additionally, we demonstrate that the introduction of the OC is an effective method to control the bottom-to-top emission ratio within a measured range from 2.87 to 6.05. 相似文献
135.
Simone Göttlich Simon Hoher Patrick Schindler Veronika Schleper Alexander Verl 《Applied Mathematical Modelling》2014
In this paper a model comparison approach based on material flow systems is investigated that is divided into a microscopic and a macroscopic model scale. On the microscopic model scale particles are simulated using a model based on Newton dynamics borrowed from the engineering literature. Phenomenological observations lead to a hyperbolic partial differential equation on the macroscopic model scale. Suitable numerical algorithms are presented and both models are compared numerically and validated against real-data test settings. 相似文献
136.
In view of Andreotti and Grauert (Bull Soc Math France 90:193–259, 1962) vanishing theorem for \(q\) -complete domains in \(\mathbb C ^{n}\) , we reprove a vanishing result by Sha (Invent Math 83(3):437–447, 1986), and Wu (Indiana Univ Math J 36(3):525–548, 1987), for the de Rham cohomology of strictly \(p\) -convex domains in \(\mathbb R ^n\) in the sense of Harvey and Lawson (The foundations of \(p\) -convexity and \(p\) -plurisubharmonicity in riemannian geometry. arXiv:1111.3895v1 [math.DG]). Our proof uses the \({L}^2\) -techniques developed by Hörmander (An introduction to complex analysis in several variables, 3rd edn. North-Holland Publishing Co, Amsterdam 1990), and Andreotti and Vesentini (Inst Hautes Études Sci Publ Math 25:81–130, 1965). 相似文献
137.
Alexandre Plastino Hugo Barbalho Luis Filipe M. Santos Richard Fuchshuber Simone L. Martins 《Journal of Heuristics》2014,20(1):39-74
Metaheuristics represent an important class of techniques to solve, approximately, hard combinatorial optimization problems for which the use of exact methods is impractical. Some researches have been combining machine learning techniques with metaheuristics to adaptively guide and improve the search for near optimal solutions. An example of such development is the DM-GRASP, a hybrid version of the Greedy Randomized Adaptative Search Procedures (GRASP) metaheuristic which incorporates a data mining process. In this hybrid proposal, after executing half of the total number of iterations, the data mining process extracts patterns from an elite set of sub-optimal solutions for the optimization problem. These patterns present characteristics of near optimal solutions and can be used to guide the following half GRASP iterations in the search through the solution space. In this work, we explore new versions of the DM-GRASP metaheuristic to experiment, not a single activation, but multiple and adaptive executions of the data mining process during the metaheuristic execution. We also applied the data mining technique into a reactive GRASP to show that a more sophisticated and not memoryless GRASP approach can also benefit from the use of this technique. In order to evaluate these new proposals, we adopted the server replication for reliable multicast problem since the best known results for this problem were obtained by GRASP and DM-GRASP implementations. The computational experiments, comparing traditional GRASP, DM-GRASP, and the new proposals, showed that multiple and adaptive executions of the data mining process can improve the results obtained by the DM-GRASP hybrid metaheuristic—the new proposals were able to find better results in less computational time for the reliable multicast problem. 相似文献
138.
Matilde Dalla Rosa Laura M. Sangalli Simone Vantini 《Advances in Data Analysis and Classification》2014,8(3):287-302
We explore the use of principal differential analysis as a tool for performing dimensional reduction of functional data sets. In particular, we compare the results provided by principal differential analysis and by functional principal component analysis in the dimensional reduction of three synthetic data sets, and of a real data set concerning 65 three-dimensional cerebral geometries, the AneuRisk65 data set. The analyses show that principal differential analysis can provide an alternative and effective representation of functional data, easily interpretable in terms of exponential, sinusoidal, or damped-sinusoidal functions and providing a different insight to the functional data set under investigation. Moreover, in the analysis of the AneuRisk65 data set, principal differential analysis is able to detect interesting features of the data, such as the rippling effect of the vessel surface, that functional principal component analysis is not able to detect. 相似文献
139.
140.
Simone Manéglier-Lacordaire Pierre Besançon Jacques Rivet Jean Flahaut 《Journal of Non》1975,18(3):439-454
The glasses of the germanium-tellurium-sulphur ternary system were investigated in order to determine the formation and crystallization processes. Vitreous samples were prepared by quenching. The vitreous transition and crystallization temperatures, together with microhardnesses, were measured throughout the vitreous region. The latter was sub-divided into several zones, and the behaviour of the glasses in each of these zones was analyzed separately. 相似文献