Magnetic and Structural Characterizations of Co-based Heusler Nanoparticles Fabricated via Simple Co-precipitation Method

Nanoparticles of Co₂FeAl magnetic alloy was successfully fabricated in the presence of a well-known capping agent, polyvinyl alcohol, as a polymer template. The magnetic properties were studied using hysteresis curve and first-order reversal curve (FORC) measurements at room temperature. FORC diagrams demonstrated a wide distribution of the coercive field owing to the presence of different particle sizes in products. TEM image also showed that the synthesized samples are composed of some large clusters containing a few smaller particles. The maximum value of magnetization (~76 emu/g) and coercivity (573 Oe) were obtained in the annealed sample with 5 °C/min. A wider distribution of grain size with a smaller average of 20.5 nm as well as lower-degree of crystallinity was observed in the sample annealed with higher rate of 10 °C/min.     

Comparative performance of INAA and other spectroscopy techniques in the elemental analysis of stainless steel materials

Samples of high alloy Stainless Steel SS 1 were analyzed by instrumental neutron activation analysis (INAA) at 5 research institutes in 4 European countries within the frame of an Inter-Laboratory Comparison (ILC) exercise aiming at checking if the results were independent of the standardization methods, and if INAA was accurate enough to contribute to certification. The mean element concentration values yielded by INAA were also compared with mean values obtained by atomic emission spectroscopy techniques at other laboratories that took part in the International Proficiency Testing organized by KIMAB Institute of Sweden, producer of the SS 1. The performances of the nuclear and atomic techniques were compared in terms of the z-score values calculated for 11 element concentrations evaluated by the two analytical ways. Finally, consideration is given to the ways in which highest accuracy and precision can be ensured for certifying stainless steels as CRMs.     

Two Different Structural Motifs Observed for Dimeric Dialkylaluminum and Dialkylgallium Alkynides [R2E‐C≡C‐C6H5]2

The dialkylaluminum and dialkylgallium alkynides [R₂E‐C≡C‐R′]₂ (R = Me, CMe₃; E = Al, Ga; R′ = Ph) containing C≡C triple bonds attached to their central aluminum or gallium atoms are easily obtained by the reactions of dialkylelement chlorides with lithium alkynides or by treatment of the corresponding alkyne R‐C≡C‐H with dialkylaluminum or dialkylgallium hydrides. The first reaction is favored by the precipitation of LiCl, the second one by the formation of elemental hydrogen. All products form dimers in which the carbanionic carbon atoms of the alkynido groups adopt bridging positions, but, interestingly, different types of molecular structures were observed depending on the steric demand of the substituents terminally attached to the aluminum or gallium atoms. The small methyl substituents gave structures in which the aluminum or gallium atoms seemed to be side‐on coordinated by the C≡C triple bonds of almost linear E‐C≡C groups. In contrast, the more bulky tert‐butyl groups forced an arrangement in which the C≡C triple bonds were perpendicular to the E‐E axis of the molecules. Different bonding modes result, which were analyzed by quantum‐chemical calculations.     

Comparative Study of the Electromagnetic Wave Absorption Properties in (FeNi,CoNi, and FeCo)/ZnS Nanocomposites

Journal of Cluster Science - Three EM wave absorbing (FeNi, CoNi, and FeCo)/ZnS nanocomposites were synthesized by simple and successful process. By comparison, it was demonstrated that the maximum...     

Mathematical modeling of flow and kinetics in a reactor for dilute-acid hydrolysis of cellulose particles

Amathematical model to simulate the dilute-acid hydrolysis process of cellulose particles is presented. In this model, the mass is treated as a mixture of different components. A test case is considered for which transport equations for components are developed and solved together with the momentum equation for the fluid flow. To solve the model equations, a commercially available flow solver was used. All input data were taken from previously published works. For the small static mixer considered as test geometry, the result, in terms of the conversion of the cellulose particles, was reasonable. With input parameters that are relevant to a plant-size reactor, the model can be used to predict the conversion of both cellulose and hemicellulose particles.     

Multi-spectroscopic and HPLC Studies of the Interaction Between Estradiol and Cyclophosphamide With Human Serum Albumin: Binary and Ternary Systems

Drug resistance is a phenomenon that frequently impairs a proper treatment of infections and cancer with chemotherapy. Multidrug efflux transporters extrude structurally dissimilar organic compounds often providing resistance to multiple toxic chemotherapeutic agents. The quantitative analysis of drug efflux requires measuring the affinity of ligands. In this work, the interaction between cyclophosphamide (Cyc) and estradiol (ES) with human serum albumin (HSA) was studied by fluorescence polarization, circular dichroism and high-performance liquid chromatography (HPLC) under physiological conditions (pH = 7.4). Gradual addition of HSA led to a marked increase in fluorescence polarization. Our assays indicated that the protein was bound to these drugs with different K _d. Also, the Hill coefficient showed a simple drug binding process with no cooperativity. Circular dichroism results revealed the occurrence of conformational changes in HSA molecules by the binding of Cyc and ES. The protein binding of the drug was studied by HPLC. Our results indicated that the drug was bound to the protein and that the presence of a second drug affected the interaction and resistance between the first drug and the protein.     

Use of TLC and UV–Visible Spectrometry for Fingerprinting of Dietary Supplements

We have studied dietary supplements containing sea-buckthorn (Hippophae rhamnoides), bilberry (Vaccinium myrtillus), and cranberry (Vaccinium vitis-idaea) by use of thin-layer chromatography (TLC), image analysis, and UV–visible spectroscopy. The results were subjected to multivariate techniques, for example cluster analysis (CA), principal-components analysis (PCA), and linear discriminant analysis (LDA). Evaluation of the discriminating power of TLC coupled with digital image analysis for characterization of the supplements was performed by use of chemometrics. Zero-order, first-order, and normalized zero-order UV–visible spectra of extracts of fruit and dietary supplements were digitized and used in the chemometric analysis. To increase the relevance of the study, the dietary supplement extracts were compared with extracts of the natural fruit. Results obtained by application of CA, PCA, and PCA–LDA to the chromatograms suggest the possibility of discrimination among dietary supplements on the basis of the raw material used for their preparation.

     

A convenient synthesis of 2-aminocyclohex-1-ene-1-carboxylic esters by FeCl3/SiO2 nanoparticles as robust and efficient catalyst

A simple and green method has been developed for the synthesis of 2-aminocyclohex-1-ene-1-carboxylic esters through a one-pot three-component condensation reaction of primary amines, ethyl acetoacetate and chalcones using FeCl3/SiO2 nanoparticles in ethanol. This method has several advantages such as high to excellent product yields in short time, using an inexpensive and reusable catalyst and available starting material.     

Penetration and Displacement Behavior of N2 in Porous Interlayer Structures Containing Water/Salt Component by Molecular Dynamics Simulation

The penetration and displacement behavior of N₂ molecules in porous interlayer structures containing a water/salt component with porosities of 4.29%, 4.73%, 5.17%, 7.22%, and 11.38% were explored using molecular dynamics simulations. The results demonstrated that the large porosity of the interlayer structures effectively enhanced the permeation and diffusion characteristics of N₂. The water and salt in the interlayer structures were displaced during the injection of N₂ in the porosity sequence of 4.29% < 4.73% < 5.17% < 7.22% < 11.38%. The high permeance of 7.12 × 10⁻⁶ indicated that the interlayer structures with a porosity of 11.38% have better movability. The strong interaction of approximately 15 kcal/mol between N₂ and H₂O had a positive effect on the diffusion of N₂ and the displacement of H₂O before it reached a stable equilibrium state. The distribution of N₂ in porous interlayer structures and the relationship between the logarithm of permeability and breakthrough pressure were presented. This work highlighted the effects of porosity on the permeability and diffusion of N₂/H₂O in the interlayer, thus providing theoretical guidance for the development of petroleum resources.     

Rational Chebyshev collocation method for the similarity solution of two dimensional stagnation point flow

In this study, we propose an efficient and accurate numerical technique that is called the rational Chebyshev collocation (RCC) method to solve the two dimensional flow of a viscous fluid in the vicinity of a stagnation point named Hiemenz flow. The Navier-Stokes equations governing the flow, are reduced to a third-order ordinary differential equation of a boundary value problem with a semi-infinite domain by using similarity transformation. The rational Chebyshev method reduces this nonlinear ordinary differential equation to a system of algebraic equations. This technique is a powerful type of the collocation methods for solving the boundary value problems over a semi-infinite interval without truncating it to a finite domain. We also present the comparison of this work with others and show that the present method is more accurate and efficient.