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排序方式: 共有143条查询结果,搜索用时 31 毫秒
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Aurlien Pitois Laura Aldave de Las Heras Maria Betti 《International journal of mass spectrometry》2008,270(3):118-126
Determination of fission products and of their isotopic composition is of high importance for the characterisation and complete inventory of nuclear fuels. Radiometric and mass spectrometric methods, which are currently used, enable only an incomplete determination of the fission products. Radiometric methods cannot be applied to all fission products and mass spectrometric methods are hindered by the existence of isobaric interferences, therefore a previous chemical separation is required before mass spectrometric analysis. Capillary electrophoresis (CE) has been coupled with inductively coupled plasma mass spectrometry (both ICP-QMS and ICP-SFMS). Typical detection limits of 6 ng/mL and 4 pg/mL for caesium as well as 8 ng/mL and 7 pg/mL for lanthanides have been obtained by CE-ICP-QMS and CE-ICP-SFMS, respectively. In addition to these very low detection limits, the procedures present the advantages to be fast (6 min for caesium and 13 min for lanthanides, respectively), to require a low microliter range sample volume and a nanoliter range injection volume. The radiation dose for the personnel as well as the volume of nuclear liquid wastes generated during the measurements are consequently reduced.The procedures have been applied to nuclear samples from PUREX process and leachates from MOX fuels. 相似文献
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Stefano Cicchi Giacomo Ghini Alberto Brandi Francesca Betti 《Tetrahedron letters》2008,49(10):1701-1705
The synthesis of new organogelators based on a triazine nucleus is described together with the analysis of the properties of the main compound 15. This compound revealed an efficient organogelator in both polar and apolar solvents and represents a promising precursor of other functionalized organogelators. 相似文献
34.
The electronic properties of a single layer (SL) of pentacene molecules are investigated by high-resolution UV photoemission and near-edge X-ray absorption spectroscopy in different configurations of the SL, either standing up on an aromatic self-assembled monolayer or planar on a bare Cu(001) substrate. The weakly interacting pentacene molecules in the standing-up SL present a semiconducting character, and the empty states distribution reflects that of gas-phase pentacene, while the planar pentacene-Cu system shows a metallic interface with redistribution of the empty molecular states. The highest-occupied molecular orbital lineshape in the weakly interacting SL shows a double structure, attributed to two nonequivalent molecules in the ordered configuration. 相似文献
35.
Zampolli S Betti P Elmi I Dalcanale E 《Chemical communications (Cambridge, England)》2007,(27):2790-2792
Micromachining technology is coupled to a selective pre-concentration material for the development of a portable sub-ppb level monitoring system for aromatic volatile organic compounds (VOC); the high sensitivity of Metal Oxide (MOX) gas sensors is combined with a supramolecular concentration unit to increase selectivity and reduce the detection limits. 相似文献
36.
Tudisco C Betti P Motta A Pinalli R Bombaci L Dalcanale E Condorelli GG 《Langmuir : the ACS journal of surfaces and colloids》2012,28(3):1782-1789
This paper reports on the preparation of a porous silicon-based material covalently functionalized with cavitand receptors suited for the detection of organophosphorus vapors. Two different isomeric cavitands, both containing one acid group at the upper rim, specifically designed for covalent anchoring on silicon, were grafted on H-terminated porous silicon (PSi) by thermal hydrosilylation. The covalently functionalized surfaces and their complexation properties were characterized by combining different analytical techniques, namely X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), and mass spectroscopy analysis coupled with thermal desorption experiments. Complexation experiments were performed by exposing both active surfaces and a control surface consisting of PSi functionalized with a structurally similar but inactive methylene-bridged cavitand (MeCav) to dimethyl methylphosphonate (DMMP) vapors. Comparison between active and inactive surfaces demonstrated the recognition properties of the new surfaces. Finally, the nature of the involved interactions, the energetic differences between active and inactive surfaces toward DMMP complexation, and the comparison with a true nerve gas agent (sarin) were studied by DFT modeling. The results revealed the successful grafting reaction, the specific host-guest interactions of the PSi-bonded receptors, and the reversibility of the guest complexation. 相似文献
37.
Renato Betti 《Applied Categorical Structures》2000,8(1-2):307-316
Weak equivalence is defined as equivalence in the bicategory of modules between internal categories. It is known that two categories are weakly equivalent if and only if their Cauchy completions are equivalent. We prove that this condition can be generalized to a suitable notion of intermediate category, stable under composition with weak equivalences. Applications to categorical Morita theory are given. 相似文献
38.
Mario Betti 《Fresenius' Journal of Analytical Chemistry》1913,52(12):778-779
Ohne Zusammenfassung 相似文献
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