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21.
A highly diastereo- and enantioselective Pd(II)-catalyzed hydrophosphination of dienones with Ph(2)PH involving formation of double C*-P bonds has been developed, providing a series of chiral tertiary diphosphines (chiral PCP pincer ligands) in high yields. A catalytic cycle for the reaction was proposed. 相似文献
22.
23.
In a world with exact SUN symmetry Veneziano has proposed a topological expansion in terms of the small dimensionless parameter . We relate this convergence factor to the density of hadronic states. The weakness of higher-order corrections (i.e., ) is interpreted as reflecting the small proportion of states that can flow through a “cylinder.” States that communicate with the cylinder may be strongly affected thereby, but the number of such states is relatively small. 相似文献
24.
We formulate a discrete quantum-mechanical precursor to spacetime geometry. The objective is to provide the foundation for a quantum mechanics that is rooted exclusively in quantum-mechanical concepts, with all classical features, including the three-dimensional spatial continuum, emerging dynamically. 相似文献
25.
Leong M. Gan Chwee H. Chew Stig E. Friberg 《Journal of polymer science. Part A, Polymer chemistry》1983,21(2):513-523
The solubility of styrene, its oligomers, and different molecular weight polymers was determined in W/O microemulsions stabilized by sodium dodecyl sulfate and pentanol. The results showed a complex pattern due to the interactions with pentanol, surfactant, and associated structures. 相似文献
26.
H.H. Bingham D.M. Chew W.B. Fretter W.R. Graves L. Stutte G.P. Yost G.S. Abrams B.Y. Daugéras C.E. Friedberg G. Goldhaber A.D. Johnson J.A. Kadyk G.H. Trilling F.C. Winkelmann D. Bogert R. Hanft F.R. Huson D. Ljung W.M. Smart 《Physics letters. [Part B]》1974,51(4):397-401
In a 48 000-picture exposure of the Fermilab 30-inch hydrogen bubble chamber to a 205 GeV/cπ?beam, we have measured 169 events of the reaction, π?p→π?π+π?p, with a cross section of 635 ± 61 μb. This reaction proceeds almost entirely via low mass π? → 3π and p → pππ dissociation. Factorization is satisfied for p → pππ dissociation in πp and pp interactions. 相似文献
27.
Vladimir Chaloupka Claude Bricman Angela Barbaro-Galtieri Denyse M. Chew Robert L. Kelly Thomas A. Lasinski Alan Rittenberg Arthur H. Rosenfeld Thomas G. Trippe Fumiyo Uchiyama Naomi Barash-Schmidt Paul Söding Matts Roos 《Physics letters. [Part B]》1974,50(1):i
This review of the properties of leptons, mesons, and baryons is an updating of Review of Particle Properties, Particle Data Group [Rev. Mod. Phys. 45, No. 2, Part II, Supplement (1973)]. Data are evaluated, listed, averaged, and summarized in tables. 相似文献
28.
Influence of an interface layer on the effective coupling at a ferromagnet/antiferromagnet interface
We examine the exchange anisotropy induced at a ferromagnetic/antiferromagnetic interface when an antiferromagnetic interface layer exists. We show that competition between exchange couplings in the interface layer can result in a ferrimagnetic-like compensation point. This leads to a reversal of the effective field acting on the ferromagnet, and a consequent sign change of the exchange bias for temperatures near the Néel temperature of the antiferromagnet. A surprising result is the sensitive dependence of the compensation point on exchange interactions. Even minute modifications of the exchange interactions near the interface can result in a reversal of the effective field, provided certain conditions are met. 相似文献
29.
In this paper, we consider how to address the issues of having designs with close performance in the multi-objective ranking and selection (MORS) problem. To resolve this issue we propose integrating the indifference-zone (IZ) concept into the multi-objective computing budget allocation (MOCBA) framework. In particular, when IZ is introduced into the MOCBA framework, we address how to determine the probability of non-dominance, how to define the Pareto set, and how to derive allocation rules for the simulation replications. Empirical results show that the MOCBA framework with IZ can significantly save simulation budget when designs to be compared have close performance. 相似文献
30.
The multilevel fast multipole algorithm (MLFMA) is extended to solve for acoustic wave scattering by very large objects with three-dimensional arbitrary shapes. Although the fast multipole method as the prototype of MLFMA was introduced to acoustics early, it has not been used to study acoustic problems with millions of unknowns. In this work, the MLFMA is applied to analyze the acoustic behavior for very large truncated ground with many trenches in order to investigate the approach for mitigating gun blast noise at proving grounds. The implementation of the MLFMA is based on the Nystrom method to create matrix equations for the acoustic boundary integral equation. As the Nystrom method has a simpler mechanism in the generation of far-interaction terms, which MLFMA acts on, the resulting scheme is more efficient than those based on the method of moments and the boundary element method (BEM). For near-interaction terms, the singular or near-singular integrals are evaluated using a robust technique, which differs from that in BEM. Due to the enhanced efficiency, the MLFMA can rapidly solve acoustic wave scattering problems with more than two million unknowns on workstations without involving parallel algorithms. Numerical examples are used to demonstrate the performance of the MLFMA with report of consumed CPU time and memory usage. 相似文献