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71.
Pei Li Qichao Zhao Jared L. Anderson Sasidhar Varanasi Maria R. Coleman 《Journal of polymer science. Part A, Polymer chemistry》2010,48(18):4036-4046
Block copolyimides based on aromatic dianhydrides and diamines copolymerized with diamino room temperature ionic liquid (RTIL) monomers were synthesized over a range of compositions. Specifically, two diamino RTILs, 1,3‐di(3‐aminopropyl) imidazolium bis[(trifluoromethyl)sulfonyl] imide ([DAPIM] [NTf2]) and 1,12‐di[3‐(3‐aminopropyl) imidazolium] dodecane bis[(trifluoromethyl) sulfonyl] imide ([C12 (DAPIM)2] [NTf2]2) were synthesized using a Boc protection method. The two RTILs were reacted with 2,2‐bis(3,4‐carboxylphenyl) hexafluoropropane dianhydride (6FDA) to produce 6FDA‐RTILs oligomers that formed the RTIL component for the block copolyimides. The oligomers were reacted with 6FDA and m‐phenylenediamine (MDA) at oligomer concentration from 6.5 to 25.8 mol % to form block copolyimides. Increasing the concentration of the 6FDA‐RTIL oligomer in the block copolyimides resulted in a decrease in the thermal degradation temperature, glass transition temperature and an increase in the density. The gas permeability of the RTIL based block copolyimide decreased but the ideal permeability selectivity for CO2/CH4 gas pair increased relative to the pure 6FDA‐MDA. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 4036–4046, 2010 相似文献
72.
Several analogues of the 9-phenylthioxanthyl (S-pixyl) photocleavable protecting group have been synthesized, containing substituents on the 9-aryl ring and on the thioxanthyl backbone. Each analogue protected the 5'-hydroxy moiety of thymidine in good to excellent yield. The protected substrates were deprotected in 1:1 water:acetonitrile with irradiation at 300 nm, resulting in recovered thymidine in excellent yield, except for the nitro-substituted analogues which gave substantially lower yields. Substrates with 2,7-dibromo or 3-methoxy substitution on the thioxanthyl backbone were also deprotected efficiently with irradiation at 350 nm. Shorter irradiation times were observed in the less nucleophilic solvent mixture of 1:9 trifluoroethanol:acetonitrile, with no formation of secondary photooxidation products. Photodeprotection with high yields was also achieved in the absence of solvent, with no secondary photoproducts. 相似文献
73.
Zou Y Fahmi NE Vialas C Miller GM Hecht SM 《Journal of the American Chemical Society》2002,124(32):9476-9488
Metabolic inactivation of the antitumor antibiotic bleomycin is believed to be mediated exclusively via the action of bleomycin hydrolase, a cysteine proteinase that is widely distributed in nature. While the spectrum of antitumor activity exhibited by the bleomycins is believed to reflect the anatomical distribution of bleomycin hydrolase within the host, little has been done to characterize the product of the putative inactivation at a chemical or biochemical level. The present report describes the synthesis of deamidobleomycin demethyl A(2) (3) and deamido bleomycin A(2) (4), as well as the respective aglycones. These compounds were all accessible via the key intermediate N(alpha)-Boc-N(beta)-[1-amino-3(S)-(4-amino-6-carboxy-5-methylpyrimidin-2-yl)propion-3-yl]-(S)-beta-aminoalanine tert-butyl ester (16). Synthetic deamido bleomycin A(2) was shown to be identical to the product formed by treatment of bleomycin A(2) with human bleomycin hydrolase, as judged by reversed-phase HPLC analysis and (1)H NMR spectroscopy. Deamido bleomycin A(2) was found to retain significant DNA cleavage activity in DNA plasmid relaxation assays and had the same sequence selectivity of DNA cleavage as bleomycin A(2). The most significant alteration of function noted in this study was a reduction in the ability of deamido bleomycin A(2) to mediate double-strand DNA cleavage, relative to that produced by BLM A(2). 相似文献
74.
De Vita R Anghinolfi M Burkert VD Dodge GE Minehart R Taiuti M Weller H Adams G Amaryan MJ Anciant E Armstrong DS Asavapibhop B Asryan G Audit G Auger T Avakian H Bagdasaryan H Ball JP Barrow S Battaglieri M Beard K Bektasoglu M Bianchi N Biselli AS Boiarinov S Bonner BE Bosted P Bouchigny S Branford D Brooks WK Bueltmann S Calarco JR Capitani GP Carman DS Carnahan B Cazes A Ciciani L Cole PL Coleman A Connelly J Cords D Corvisiero P Crabb D Crannell H Cummings JP De Sanctis E Degtyarenko PV 《Physical review letters》2002,88(8):082001
The double spin asymmetry in the (-->)e(-->)p --> e(prime)pi(+)n reaction has been measured for the first time in the resonance region for four-momentum transfer Q2 = 0.35-1.5 GeV(2). Data were taken at Jefferson Lab with the CLAS detector using a 2.6 GeV polarized electron beam incident on a polarized solid NH3 target. Comparison with predictions of phenomenological models shows strong sensitivity to resonance contributions. Helicity-1/2 transitions are found to be dominant in the second and third resonance regions. The measured asymmetry is consistent with a faster rise with Q(2) of the helicity asymmetry A1 for the F(15)(1680) resonance than expected from the analysis of the unpolarized data. 相似文献
75.
We conduct numerical simulations of random packings of frictionless particles at T = 0. The packing fraction where the pressure becomes nonzero is the same as the jamming threshold, where the static shear modulus becomes nonzero. The distribution of threshold packing fractions narrows, and its peak approaches random close packing as the system size increases. For packing fractions within the peak, there is no self-averaging, leading to exponential decay of the interparticle force distribution. 相似文献
76.
Joo K Smith LC Burkert VD Minehart R Aznauryan IG Elouadrhiri L Stepanyan S Adams GS Amaryan MJ Anciant E Anghinolfi M Armstrong DS Asavapibhop B Audit G Auger T Avakian H Barrow S Bagdasaryan H Battaglieri M Beard K Bektasoglu M Bertozzi W Bianchi N Biselli AS Boiarinov S Bonner BE Brooks WK Calarco JR Capitani GP Carman DS Carnahan B Cole PL Coleman A Cords D Corvisiero P Crabb D Crannell H Cummings J De Sanctis E De Vita R Degtyarenko PV Demirchyan RA Denizli H Dennis LC Deppman A 《Physical review letters》2002,88(12):122001
Models of baryon structure predict a small quadrupole deformation of the nucleon due to residual tensor forces between quarks or distortions from the pion cloud. Sensitivity to quark versus pion degrees of freedom occurs through the Q2 dependence of the magnetic (M1+), electric (E1+), and scalar (S1+) multipoles in the gamma*p-->Delta(+)-->p pi(0) transition. We report new experimental values for the ratios E(1+)/M(1+) and S(1+)/M(1+) over the range Q2 = 0.4-1.8 GeV2, extracted from precision p(e,e(')p)pi(0) data using a truncated multipole expansion. Results are best described by recent unitary models in which the pion cloud plays a dominant role. 相似文献
77.
[formula: see text] Both in vivo and in vitro techniques have been developed to test putative intermediates in the biosynthetic pathway to the pseudopterosins, antiinflammatory compounds isolated from Pseudopterogorgia elisabethae. Furthermore, specific activity data we have obtained indicate that pseudopterosin A is a precursor to pseudopterosins B, C, and D. We conclude that in the biosynthesis xylose is attached to the diterpene skeleton to produce pseudopterosin A and is then aceylated to form pseudopterosins B-D. 相似文献
78.
In a review paper [H. M. Jaeger, S. R. Nagel, and R. P. Behringer, "Granular solids, liquids and gases," Rev. Mod. Phys. 68, 1259-1273 (1996)] a few years ago, we wrote about granular material as a distinctive form of matter that exhibits behavior rather different from that of ordinary solids, liquids, or gases. We traced this distinction to three characteristic properties. First, the individual particles making up a granular material are typically large so that thermal energy is irrelevant compared to gravitational energy. Consequently, concepts from equilibrium statistical mechanics are often not applicable. Second, the interactions between particles are frictional and can be mobilized to different degrees depending on the preparation history, giving rise to memory effects, i.e., a static pile will remember how it was formed. Third, when particles collide they do so inelastically so that a "gas" of particles will slow down and come to rest in clumps. In the intervening years, the research on granular matter has progressed rapidly and this may be a good time to ask what we have learned since that article was written. In this spirit, the present special issue of the journal Chaos assembles a spectrum of papers discussing recent developments in the field. (c) 1999 American Institute of Physics. 相似文献
79.
It is shown in this paper that if A is a closed normal subgroup of kω-topological groups G and H, then the free product of G and H with A amalgamated, G1AH, exists, is Hausdorff and indeed a kω-group. 相似文献
80.
Sidney C. Scull 《Reports on Mathematical Physics》1976,10(1):1-7
The spectrum of self-adjoint operators arising from unitary representations of semi-simple Lie groups is investigated. A series of irreducible unitary representations in which certain generators of non-compact one-parameter subgroups are realized by positive operators is described. These representations occur only for groups of automorphisms of bounded symmetric domains. 相似文献