The role of free carbon in the transport and magnetic properties of boron carbide

Boron carbide is a ceramic which has a wide field of application because of its mechanical and nuclear properties. This material is difficult to characterise due to the presence of different levels of disorder and inhomogeneities which are found in the usual available samples. The transport and magnetic properties of several samples of boron carbide have been measured from liquid helium to room temperature as a function of temperature and composition. We have attempted to attribute the different features of these properties to the different levels of disorder. The role of free carbon, in form of thin layers of graphite within the disordered semi-conducting matrix, was investigated in particular details, because it was either ignored or neglected by others. Free carbon is found to dominate the D.C. transport when its concentration is larger than 5%; while the principal features of the electron spin resonance (E.S.R.) line show a dominance of free carbon when the concentration is larger than 3.5%. Below these concentrations conductivities as well as spin relaxation rates do not depend very much on free carbon; neither these have been found to be correlated in a simple way to the stoichiometry: the disorder in the boron sublattice is probably responsible for the electronic properties in this range of concentrations.     

A quasi random search technique for functional fitting of detector responses

The problem of nonlinear optimization is encountered while fitting the observed response of certain radiation detectors. In this paper the development of an optimizing technique based on quasi random search is described. The performance of this technique is compared with other existing methods of gradient search and linear Taylor differential correction technique in the case of fitting the photopeak responses of Nal(Tl) detectors. Our results are favourable especially when the observed data are associated with poor statistics.     

Analysis of a model scheme incorporating reactant inhibition: Instability of homogeneous solution and formation of spatio–temporal structures

A model scheme incorporating reactant inhibition in the rate process has been analyzed with a view to study the instability of homogeneous solution due to diffusion. Conditions for the occurrence of Turing as well as phase instability are derived and show the existence of multiplicity in the parameter space. The Ginzburg-Landau equation for the system is developed and solved numerically in various regions of the parameter space. The simple model system shows the existence of very rich behavior including normal and inverted bifurcations in the super and subcritical regimes. The various results are analyzed and discussed. © 1993 John Wiley & Sons, Inc.     

Global tuning of local molecular phenomena: an alternative approach to bionanoelectronics

We have applied simultaneous horizontal and vertical bias to a single molecule (2 nm(2)) in an ordered and disordered matrix to virtually isolate and tune its property without taking it out physically from its environment. Using a dedicated electrode system, we have locally tuned nanoscale properties vertically by STM, while stabilizing its environment by applying a global electric field horizontally. Using this technique, we report tuning of molecular conformations in room temperature, whose evolution of states has been statistically investigated. We have also shown control on switching of a few selected conformations by applying dual bias simultaneously. As we avoid any direct injection of charge into the system via electrode contact, this technique could be used as a generalized method to tune phenomena evolved in an environment of weak interaction from a large distance without destroying the property.     

Effect of regulation on efficiency: evidence from Indian cement industry

The main objective of the paper is to analyze the impact of environmental regulation on technical efficiencies of Indian cement producing firms. It derives the technical efficiency (TE) scores of firms in the presence and absence of regulation and brings out the differences in their magnitudes in two scenarios: one in which the firms take initiatives to comply with the set standards by investing additional resources for pollution abatement and the other in which the firms do not take the necessary initiatives. The paper uses establishment level data from Annual Survey of Industries on cement for two years, the most recent data published for 2003–2004 and a previous year for 1999–2000 when the environmental regulations in India were in the initial phases of implementation. A non-parametric deterministic method of data envelopment analysis (DEA) is used to derive the TE scores of firms. The traditional DEA framework is modified by introducing weak disposability of bad outputs to characterize ‘effective environmental regulation’, which ensures that reducing pollution is not costless. For both years it has been found that the TE scores of firms under ‘effective regulation’ scenario are either higher than or equal to those derived under ‘ineffective regulation’ scenario resulting in a higher average TE at the industry level in the ‘effective regulation’ scenario.     

Ultrahigh-temperature regenerated gratings in boron-codoped germanosilicate optical fiber using 193 nm

Regenerated gratings seeded by type I gratings in boron-codoped germanosilicate optical fiber written with 193 nm are shown to withstand temperatures beyond 1000 degrees C.