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51.
Xingang Kong Jiarui Zhang Jianfeng Huang Jiayin Li Yi Qin Ting Zhao Qi Feng 《中国化学快报》2019,30(3):771-774
SnNb2O6 and Sn2Nb2O7 nanosheets were synthetized via microwave assisted hydrothermal method, and innovatively employed as anode materials for lithium-ion battery. Compared with Sn2Nb2O7 and the previously reported pure Sn-based anode materials, the SnNb2O6 electrode exhibited outstanding cycling performance. 相似文献
52.
Shanshan Wang Xianbo Kong Zhangjing Chen Guopin Wang Juan Zhang Jing Wang 《Molecules (Basel, Switzerland)》2022,27(13)
Alzheimer’s disease (AD) is a progressive neurological condition. The rising prevalence of AD necessitates the rapid development of efficient therapy options. Despite substantial study, only a few medications are capable of delaying the disease. Several substances with pharmacological activity, derived from plants, have been shown to have positive benefits for the treatment of AD by targeting various enzymes, such as acetylcholinesterase (AChE), butyrylcholinesterase (BuChE), β-secretase, γ-secretase, and monoamine oxidases (MAOs), which are discussed as potential targets. Medicinal plants have already contributed a number of lead molecules to medicine development, with many of them currently undergoing clinical trials. A variety of medicinal plants have been shown to diminish the degenerative symptoms associated with AD, either in their raw form or as isolated compounds. The aim of this review was to provide a brief summary of AD and its current therapies, followed by a discussion of the natural compounds examined as therapeutic agents and the processes underlying the positive effects, particularly the management of AD. 相似文献
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Mengya Kong Yuyang Gu Yingjie Chai Jiaming Ke Yulai Liu Xincheng Xu Zhanxian Li Wei Feng Fuyou Li 《中国科学:化学(英文版)》2021,(6):974-984
Luminescence nanothermometry makes non-invasive and real-time temperature readings possible in living animals. However,the spectral fluctuation in tissues and fluids, as well as the interaction between fluorophores and environment hinders accuracy of the thermometry. Here, we report a luminescence lifetime-based nanothermometry which specifically addresses this problem. A temporal based calibration(lifetime sensing) in the NIR range, an endogenous thermal response as well as a polymer encapsulation evading environmental factors, altogether help to pinpoint temperature in vivo. Thanks to the highly condensed NdYb ions in a well-protected tiny core-shell nanocrystal(overall 11 nm), a temperature sensitivity about 2.07% K~(-1)(with 5% Yb~(3+) doped nanoparticles) and an accuracy of 0.27 K(with 25% Yb~(3+) doped nanoparticles) in biological fluids are achieved.Hopefully, combining thermally activated energy transfer nanothermometer with anti-interference lifetime thermometry would provide a more accurate temperature measurement for biological and preclinical studies. 相似文献
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本文利用红外光解离光谱研究了第三族金属氧化物离子对二氧化碳分子的转化机制. 研究表明,对于[ScO(CO2)n]+体系,在n≤4时,形成了溶剂化结构;在n=5时,形成了碳酸盐结构,实现了二氧化碳的转化. 对于[YO(CO2)n]+体系,需要4个二氧化碳分子就可以实现二氧化碳的转化. 而在[YO(CO2)n]+体系中,只发现了溶剂化结构,没有观察到碳酸盐结构. 理论计算表明,[YO(CO2)n]+体系拥有最小的溶剂化结构向碳酸盐结构转化能垒,[LaO(CO2)n]+体系拥有最大的溶剂化结构向碳酸盐结构转化能垒. 本文从分子水平揭示了不同金属氧化物离子对二氧化碳分子转化的影响规律. 相似文献
56.
Electrical, dielectric and surface wetting properties of multi-walled carbon nanotubes/nylon-6 nanocomposites 下载免费PDF全文
This paper reports that the multi-walled carbon nanotubes(MWCNT)/nylon-6 (PA6) nanocomposites with different MWCNT loadingshave been prepared by a simple melt-compounding method. Theelectrical, dielectric, and surface wetting properties of theCNT/PA6 composites have been studied. The temperature dependence ofthe conductivity of the CNT/PA6 composite with 10.0 wt{\%} CNTloading ($\sigma _{\rm RT} \sim 10^{-4}$ S/cm) are measured, andafterwards a charge-energy-limited tunnelling model (ln $\sigma (T)\sim T^{-1/2})$ is found. With increasing CNT weight percentage from0.0 to 10.0 wt%, the dielectric constant of the CNT/PA6composites enhances and the dielectric loss tangent increases twoorders of magnitude. In addition, water contact angles of theCNT/PA6 composites increase and the composites with CNT loadinglarger than 2.0 wt%even become hydrophobic. The obtainedresults indicate that the electrical and surface properties of thecomposites have been significantly enhanced by the embedded carbonnanotubes. 相似文献
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Spiders in electro-dynamic loudspeakers are most commonly concentrically corrugated fabric disks, and their viscoelastic behaviors affect the loudspeaker reproductions. A noncontact dynamic measuring technology is presented by a subwoofer closed box to excite the tested spiders pneumatically with a Laser Doppler Vibrometer (LDV) to measure the velocity of the moving spiders. Correlation techniques were employed to get an accurate and reliable acoustical transfer function between the measured velocity and sound pressure. The Young’s moduli of the tested spider composite materials were derived from the measured vibration modes. The creep effect and the level dependent behaviors of tested spiders were investigated. The results indicate that, the Young’s moduli of the tested spiders are frequency dependent. The mechanical stiffness increases with a small slope in low frequency range while a large slope in high frequency range. The loss factor exhibits the maximum around the resonance frequency, and after that it decreases with increasing frequency. The effective stiffness has a monotonic decrease with input voltage levels and the harder the spider, the less stiffness changes with input levels. 相似文献
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Chun-Yan Li Chun-Xiang Zou Yong-Fei Li Xue-Fei Kong Yu Zhou Yin-Shuang Wu Wei-Guo Zhu 《Analytica chimica acta》2013
A rhodamine spirolactam derivative (1) was developed as a colormetric and fluorescent chemosensor for adenosine-5′-triphosphate (ATP) via hydrogen bonds interaction. As far as we know, this is the first case to explore ATP-induced ring-opening of spirolactam in rhodamine derivatives. It exhibited a highly sensitive “turn-on” fluorescent response toward ATP with a 47-fold fluorescence intensity enhancement under 20 equiv. of ATP added. The chemosensor can be applied to the quantification of ATP with a linear range covering from 1.0 × 10−7 to 2.0 × 10−4 M and a detection limit of 2.5 × 10−8 M. The experiment results show that the response behavior of 1 toward ATP is pH independent in medium condition (pH 6.0–8.0). Most importantly, the novel chemosensor has well solved the problem of serious interferences from other nucleoside polyphosphates such as ADP and AMP generally met by previously reported typical fluorescent chemosensors for ATP. Moreover, the response of the chemosensor toward ATP is fast (response time less than 3 min). In addition, the chemosensor can be used for the fluorescence assay for protein kinase activity with satisfactory results. The chemosensor for ATP based on hydrogen bonds interaction provided a novel strategy for the design of colormetric and ratiometric fluorescent probes for other target anions with high sensitivity and selectivity. 相似文献