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71.
High pressure can effectively control the phase transition of MoTe2 in experiment, but the mechanism is still unclear. In this work, we show by first-principles calculations that the phase transition is suppressed and phase becomes more stable under high pressure, which originates from the pressure-induced change of the interlayer band occupancies near the Fermi energy. Specifically, the interlayer states of phase tend to be fully occupied under high pressure, while they keep partially occupied for the phase. The increase of the band occupancies makes the phase more favorable in energy and prevents the structure changing from to phase. Moreover, we also analyze the superconductivity under high pressure based on BCS theory by calculating the density of states and phonon spectra. Our results may shed some light on understanding the relationship between the interlayer band occupancy and crystal stability of MoTe2 under high pressures. 相似文献
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A back propagation artificial neural network (BPANN) prediction model for warpage of injection-molded polypropylene was developed based on an orthogonal design method. The BPANN model was trained by the input and output data obtained from the moldflow software platform simulations. It is proved that the BPANN model can predict the warpage with reasonable accuracy. Utilizing the BPANN model, the effects of the process parameters, packing pressure (Pp), melt temperature (Tme), mold temperature (Tmo), packing time (tp), cooling time (tc), and fill pressure (pf), on the warpage were investigated. The most important process parameter affecting the warpage was Pp, and the second most important was Tme. The rest of the process parameters, Tmo, tp, tc, and pf, were found to be relatively less influential. Warpage increased with elevating Tmo. In contrast, an increase in Pp and Tme caused the warpage to decrease. 相似文献
74.
Z. B. Pan J. J. Liu R. Wang X. Y. Liu J. Wang N. K. Sun P. Z. Si 《Applied Physics A: Materials Science & Processing》2014,115(4):1121-1125
Structural, magnetic and magnetostrictive properties of Tb0.4Nd0.6(Fe0.8Co0.2) x (1.50 ≤ x ≤ 1.90) alloys have been investigated by means of X-ray diffraction (XRD), a vibrating sample magnetometer and a standard strain technique. XRD analysis shows the presence of single Laves phase with a cubic MgCu2-type structure for the high Nd content alloy around the composition of x = 1.80, which tends to be formed by curing at relatively low annealing temperature. The easy direction of magnetization at room temperature is observed toward <111> axis, accompanied by a rhombohedral distortion with a large spontaneous magnetostriction λ111. An optimized effect on the linear anisotropic magnetostriction, 360 ppm at 3 kOe, was observed for the high Nd content Tb0.4Nd0.6(Fe0.8Co0.2)1.80 alloy, which can be attributed to its single Laves phase, the large λ111 (~1,520 ppm) of the MgCu2-type (Tb,Nd)(Fe,Co)2 phase and the good soft magnetic behaviors. 相似文献
75.
Muhammad Waqas Ali Siyuan Cheng Jianhao Si Muhammad Siddiq Xiaodong Ye 《Journal of polymer science. Part A, Polymer chemistry》2019,57(19):2030-2037
Hyperbranched poly(2‐ethyl‐2‐oxazoline) was synthesized by a combination of cationic ring‐opening polymerization and the oxidation of thiol to disulfide groups. A three‐arm star poly(2‐ethyl‐2‐oxazoline) (PEtOx) was first synthesized using 1,3,5‐tris(bromomethyl) benzene as an initiator. The star PEtOx was end‐capped with potassium ethyl xanthate. Similarly, a linear PEtOx was synthesized and end‐capped with potassium ethyl xanthate using benzyl bromide as an initiator. Hyperbranched PEtOx was then obtained by in situ cleaving and subsequent oxidation of the star PEtOx and linear PEtOx mixture with n‐butylamine as both a cleaving agent and a base in tetrahydrofuran. The linear PEtOx was used to prevent the formation of gel. The hyperbranched PEtOx can be cleaved with dithiothreitol to trithiol and monothiol polymer. The hyperbranched PEtOx shows no remaining thiols using Ellman's assay. The resulting hyperbranched PEtOx was hydrolyzed to a novel hyperbranched polyethyleneimine with degradable disulfide linkages. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 2030–2037 相似文献
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Samira Benmouloud Rachid Echarghaoui Si. Mohammed Sbaï 《Journal of Mathematical Analysis and Applications》2012,396(1):375-385
In this paper, by using the Lusternik–Schnirelmann category, we obtain a multiplicity result for a quasilinear elliptic system with both concave and convex nonlinearities and critical growth terms in bounded domains. 相似文献
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79.
Inside Back Cover: Stepwise Assembly of MII7 Clusters Revealed by Mass Spectrometry,EXAFS, and Crystallography (Chem. Eur. J. 51/2016) 下载免费PDF全文
80.
This study aims to reveal the laws of the relationship between fractional-order system and integer-order system. Meanwhile, delayed feedback control is introduced to control the fractional-order PMSG (permanent magnet synchronous generator) model of a wind turbine. First, the fractional-order mathematical model of PMSG is established. Next, numerical simulations under different system orders are given and the system dynamic behaviors are analyzed in detail. Then, the delayed feedback control method is introduced to control the fractional-order PMSG and the control results when different parameters vary are analyzed. Complex dynamics are presented and some interesting phenomena are discovered. It is found that the system order influences the dynamics of the system in many aspects such as chaos pattern, bifurcation behavior, period window, shape and size of strange attractor. The delayed time, feedback gain, feedback limitation, system order can obviously influence the control result except the initial state of the system. Moreover, the feedback limitation has a minimum to successfully control the system to stable states and the system order also has a maximum to do so. 相似文献