全文获取类型
收费全文 | 448篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 289篇 |
晶体学 | 8篇 |
力学 | 11篇 |
数学 | 62篇 |
物理学 | 87篇 |
出版年
2023年 | 3篇 |
2022年 | 5篇 |
2021年 | 7篇 |
2020年 | 8篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 4篇 |
2014年 | 20篇 |
2013年 | 33篇 |
2012年 | 22篇 |
2011年 | 38篇 |
2010年 | 13篇 |
2009年 | 9篇 |
2008年 | 18篇 |
2007年 | 17篇 |
2006年 | 18篇 |
2005年 | 18篇 |
2004年 | 10篇 |
2003年 | 8篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 10篇 |
1993年 | 6篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1982年 | 3篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1979年 | 10篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1969年 | 3篇 |
1943年 | 5篇 |
1942年 | 4篇 |
1941年 | 2篇 |
1940年 | 9篇 |
1939年 | 6篇 |
排序方式: 共有457条查询结果,搜索用时 31 毫秒
21.
A highly sensitive spectrophotometric method for the determination of nitrite in water and soil has been developed. The reaction of nitrite with acidified potassium iodide to liberate iodine which oxidizes leuco‐crystal violet (LCV) to form crystal violet having absorption maxima at 590 nm forms the bases of this method. In aqueous medium the system obeys Beer's law in the range of 0.1 to 1.0 μg per 25 mL (0.004–0.04 ppm), while in an extractive system the range is 0.025–0.25 μg in 100 mL (0.00025–0.0025 ppm). The molar absorptivity and Sandell's sensitivity were found to be 1.54 × 106 1 mol?1 cm?1 and 44 pg cm?2, respectively. 相似文献
22.
A chelating ion-exchange resin with hydroxamic acid functional groups was synthesized from styrene-maleic acid co-polymer cross-linked with divinylbenzene. A resin prepared from equimolar amounts of styrene and maleic anhydride with 0.75 mole% divinylbenzene gives the best sorption characteristics. The selectivity of the resin for metal ions is copper(II) > cobalt(II) > zinc(II) > nickel(II) > manganese(II) > chromium(III) > iron(III) > vanadium(V). Copper(II), chromium(III) and iron(III) in chromium plating baths can be separated by use of the resin and determined spectrophotometrically. 相似文献
23.
The effect of impurities on the growth of manganese carbonate crystals has been studied. Stereophotogrammetric analysis showed
that all crystal faces have the same Miller indices
and the peanut-shaped forms are twins with twin axis 0001. 相似文献
24.
Hong Zhang Zuoquan Wang Ion Ghiviriga Girinath G. Pillai Farukh Jabeen Justin A. Arami Wenfeng Zhou Peter J. Steel C. Dennis Hall Alan R. Katritzky 《Tetrahedron letters》2017,58(12):1079-1085
Synthesis, characterization and energetic properties of novel, nitrogen-rich 1-methyl-1,2,4-triazolium N-aryl/N-pyridinyl ylids 3a–m are reported. 相似文献
25.
Beena Mathew P. M. Madhusudanan V. N. Rajasekharan Pillai 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):1781-1800
Abstract Amino groups were incorporated into polyacrylamides with 2?20 mol% of crosslinking agents by transamidation with ethylenediamine. Divinylbenzene, N,Nv′-methylene-bis-acrylamide, and tetraethyleneglycol diacrylate were used as the crosslinking agents. The complexation of these resins, which contain ligand functions in different macromolecular structural environments, was investigated with Cu(II) ions. The Cu(II) uptake of these different resins was correlated with the molecular character and degree of crosslinking in the polymer matrix. The time course and kinetics of complexation depend on the nature of the crosslinking agent in the polymer matrix. The swelling behavior of the uncomplexed and complexed resins, structural characteristics, and thermal decomposition behavior were followed by IR, EPR, and thermal analysis. The swelling characteristics of the complexed resins are lower than those of the uncomplexed resins. Complexation resulted in shifting of the IR absorptions. The EPR parameters depend on the nature of crosslinking and are in agreement with the distorted tetragonal geometry of the Cu(II) complexes. The thermal decomposition behavior also depends on the nature and the degree of crosslinking in the polymer matrix. 相似文献
26.
The cure kinetics of epoxy based on the diglycidyl ether of bisphenol A (DGEBA) modified with different amounts of poly(acrylonitrile-butadiene-styrene) (ABS) and cured with 4,4′-diaminodiphenylsulfone (DDS) was investigated by employing differential scanning calorimetry (DSC). The curing reaction was followed by using an isothermal approach over the temperature range 150–180°C. The amount of ABS in the blends was 3.6, 6.9, 10 and 12.9 wt%. Blending of ABS in the epoxy monomer did not change the reaction mechanism of the epoxy network formation, but the reaction rate seems to be decreased with the addition of the thermoplastic. A phenomenological kinetic model was used for kinetic analysis. Activation energies and kinetic parameters were determined by fitting the kinetic model with experimental data. Diffusion control was incorporated to describe the cure in the latter stages, predicting the cure kinetics over the whole range of conversion. The reaction rates for the epoxy blends were found to be lower than that of the neat epoxy. The reaction rates decreased when the ABS contents was increased, due to the dilution effect caused by the ABS on the epoxy/amine reaction mixture. 相似文献
27.
Paulson Mathew Satheesh K. Nair K. M. Sreedhar V. N. Rajasekharan Pillai 《合成通讯》2013,43(16):2157-2161
When α‐oxoketene dithioacetals 1a–n were treated with the bromine complex of a copolymer of 1‐vinyl‐2‐pyrrolidone and 4‐vinylpyridine, the corresponding thiolcarboxylates 2a–n were formed in excellent yields. The reaction also works with other 1‐vinyl‐2‐pyrrolidone‐derived polymers as well as commercially available polyvinylpyrrolidone–bromine complexes. The method is suitable for preparing aliphatic, aromatic, and γ,δ‐unsaturated β‐oxothiolcarboxylates. 相似文献
28.
A simple and sensitive spectrophotometric method for the determination of hydrogen peroxide, based on the increase in color intensity of dye on addition of surfactant, is described. Hydrogen peroxide is first reacted with potassium iodide in acidic medium, in presence of ammonium molybdate to liberate iodine. The liberated iodine oxidizes leucocrystal violet to crystal violet having maximum absorbance at 593 nm. The color of the dye intensifies with the addition of the surfactant, cetyl pyridinium chloride though the absorption maximum remains the same. Beer's law is obeyed in the range 0.05–0.45 µg of hydrogen peroxide per 25 mL of final solution (0.002–0.018 µg mL?1) with an excellent correlation coefficient (r = 0.9977). The proposed method has been successfully applied for the analysis of hydrogen peroxide in various food products and rainwater. 相似文献
29.
K. Jeevarenuka G. Sankaran Pillai P. Shahul Hameed R. Mathiyarasu 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(1):245-252
The activity concentrations and absorbed gamma dose of primordial radionuclides 238U, 232Th and 40K were determined employing γ-ray spectrometry in 31 soil samples from the land area earmarked for house construction in Perambalur district and 14 rock samples from quarries that supply stones for the entire district. The soil samples registered relatively a higher mean value of 13.2 Bq kg?1 for 238U, 66 Bq kg?1 for 232Th and 340.3 Bq kg?1 for 40K as compared to mean values for rock samples (238U—8.0 Bq kg?1; 232Th—65.1 Bq kg?1; 40K—199.1 Bq kg?1). The mean absorbed gamma dose rate for soil (61.4 nGy h?1) marginally exceeded the prescribed limit of 55 nGy h?1 while, rocks registered the mean absorbed gamma dose rate of 10.4 nGy h?1. The mean radium equivalent activity was distinctly higher in soil (130.6 Bq kg?1) than in rock (20.0 Bq kg?1). However, these values were lower than the limit (370 Bq kg?1) set by OECD for building materials. It is evident from the data that the soil and rocks do not pose any radiological risk for house constructions in Perambalur district. 相似文献
30.
An electrochemical pathway to prepare circular planar 90Sr/90Y sources for the calibration of surface contamination monitors 总被引:1,自引:0,他引:1
Manoj Kumar Shyamala S. Gandhi J. Nuwad J. Udhayakumar Ashutosh Dash 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(1):709-719
In this communication, we describe a novel method to prepare circular planar 90Sr/90Y sources (? = 16 mm) exploiting the intrinsic properties of the anodized titanium to electro-deposit predicted quantity of 90Sr activity from an aqueous solution. The influences of various experimental parameters such as pH of the electrolyte, applied current density, electrodeposition time and carrier strontium concentration were thoroughly investigated to arrive at a condition resulting optimal deposition of the 90Sr/90Y activity on the substrate. An optimized electrochemical procedure to prepare ~3.7 MBq (~0.1 mCi) of circular planar 90Sr/90Y sources commensurate with regulatory safety requirement has been the positive outcome. 相似文献