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排序方式: 共有372条查询结果,搜索用时 15 毫秒
21.
Shotaro Hayashi Fumitaka Ishiwari Takanori Fukushima Shohei Mikage Yutaka Imamura Motomichi Tashiro Michio Katouda 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16329-16335
Elastic organic crystals have attracted considerable attention as next-generation flexible smart materials. However, the detailed information on both molecular packing change and macroscopic mechanical crystal deformations upon applied stress is still insufficient. Herein, we report that fluorescent single crystals of 9,10-dibromoanthracene are elastically bendable and stretchable, which allows a detailed investigation of the deformation behavior. We clearly observed a Poisson effect for the crystal, where the short axes (b and c-axes) of the crystal are contracted upon elongation along the long axis (a-axis). Moreover, we found that the Poisson's ratios along the b-axis and c-axis are largely different. Theoretical molecular simulation suggests that the tilting motion of the anthracene may be responsible for the large deformation along the c-axis. Spatially resolved photoluminescence (PL) measurement of the bent elastic crystals reveals that the PL spectra at the outer (elongated), central (neutral), and inner (contracted) sides are different from each other. 相似文献
22.
Shotaro Hayashi Fumitaka Ishiwari Takanori Fukushima Shohei Mikage Yutaka Imamura Motomichi Tashiro Michio Katouda 《Angewandte Chemie (International ed. in English)》2020,59(37):16195-16201
Elastic organic crystals have attracted considerable attention as next‐generation flexible smart materials. However, the detailed information on both molecular packing change and macroscopic mechanical crystal deformations upon applied stress is still insufficient. Herein, we report that fluorescent single crystals of 9,10‐dibromoanthracene are elastically bendable and stretchable, which allows a detailed investigation of the deformation behavior. We clearly observed a Poisson effect for the crystal, where the short axes (b and c‐axes) of the crystal are contracted upon elongation along the long axis (a‐axis). Moreover, we found that the Poisson's ratios along the b‐axis and c‐axis are largely different. Theoretical molecular simulation suggests that the tilting motion of the anthracene may be responsible for the large deformation along the c‐axis. Spatially resolved photoluminescence (PL) measurement of the bent elastic crystals reveals that the PL spectra at the outer (elongated), central (neutral), and inner (contracted) sides are different from each other. 相似文献
23.
24.
Spectroscopic and crystallographic studies on the stability of self-assembled coordination nanotubes
Aoyagi M Tashiro S Tominaga M Biradha K Fujita M 《Chemical communications (Cambridge, England)》2002,(18):2036-2037
On complexation with (en)Pd(NO3)2, tetrakis(3,5-pyridine) ligand gives two isomeric coordination nanotubes, which are in slow equilibrium despite the presence of sixteen Pd-N bonds in the tube framework. 相似文献
25.
Kawase K Mizuno M Sohma S Takahashi H Taniuchi T Urata Y Wada S Tashiro H Ito H 《Optics letters》1999,24(15):1065-1067
Among nonlinear materials, the organic ionic salt crystal 4-dimethylamino- N -methyl-4-stilbazolium-tosylate (DAST) is known for its large nonlinearity. We generated a coherent terahertz (THz) wave, using DAST, from the difference frequency between two oscillating wavelengths of an electronically tuned Ti:sapphire laser. In LiNbO(3), LiTaO(3), KTiOPO(4), and GaP crystals, THz-wave generation was not observed under the same experimental conditions. This result proves the high efficiency of DAST crystals for generation of difference-frequency THz waves. 相似文献
26.
We investigate the hadron productions in hyperon proton collisions in terms of the quark-diquark cascade model with diffractive component. We compare our predicted spectra Ξ?→Ξ? X and Ξ?→Ω? X with the experimental data. The distribution functions of constituents in incident hadrons and the momentum sharing functions of cascade processes are characterized by the intercepts of Regge trajectories, revealing the difference betweens quark and non-strange quark. 相似文献
27.
A simple Raman probe was realized using a single flexible hollow waveguide (HW). A HW coated with a silver film, which had reasonable transmission and little optical background noise, was used as a bidirectional transmission fiber for both the excitation and collection of Raman scattered light. The HW itself generated no Raman scattering or fluorescence noise during transmission. A complex filtering system at the end of the waveguide was thus unnecessary. In addition, the measured Raman spectra showed better signal-to-noise ratios than a conventional Raman fiber probe. The HW's suitability as a Raman fiber probe was also demonstrated. 相似文献
28.
The Huggins band of ozone is investigated by means of exact dynamics calculations using a new (diabatic) potential energy surface for the (1)B(2) state. The remarkable agreement with the measured spectrum strongly suggests that the Huggins band is due to the two C(s) potential wells of the (1)B(2) state. The vibrational assignment, based on the nodal structure of wave functions, supports the most recent experimental assignment. 相似文献
29.
30.
High-pressure elastic properties of solid argon to 70 GPa 总被引:3,自引:0,他引:3
The acoustic velocities, adiabatic elastic constants, bulk modulus, elastic anisotropy, Cauchy violation, and density in an ideal solid argon (Ar) have been determined at high pressures up to 70 GPa in a diamond anvil cell by making new approaches of Brillouin spectroscopy. These results place the first complete study for elastic properties of dense Ar and provide an improved basis for making the theoretical calculations of rare-gas solids over a wide range of compression. 相似文献