Application of X-ray photoelectron spectroscopy to characterization of Au nanoparticles formed by ion implantation into SiO2

In X-ray photoelectron spectroscopy (XPS) of Au nanoparticles, the width of 5d valence band changes with Au particle size. This enables us to estimate the size of Au nanoparticles by using XPS. In this work, the 5d-band width has been measured for Au nanoparticles formed by ion implantation into SiO₂. The 5d-band width is found to be correlated strongly with the Au concentration. As the Au concentration increases, the 5d-band width becomes larger, indicating that the Au nanoparticles with the larger size tend to be formed in the vicinity of the projected range of Au ions. This correlation agrees very well with the results from transmission electron microscopy.     

A Network of Analog Metal Oxide Semiconductor Circuits for Motion Detection with Local Adaptation to a Background Image

Inspired by a mechanism of biological vision systems, a model and a network of analog metal oxide semiconductor (MOS) circuits are proposed which display an optical flow with local adaptation to the relative velocity of a background image. A function of displaying an optical flow successfully worked as a result of simulations using the simulation program with integrated circuit emphasis (SPICE). A function of varying an optical flow at a certain instant by local adaptation was also demonstrated. The proposed network is suitable for the realization of a large-scale integrated circuit (LSI), which displays an optical flow with local adaptation to the local velocity of a background.     

A new type oscillatory phenomenon in the magnetotransport of θ-(BEDT-TTF)2I3

A new type oscillatory magnetotransport phenomenon has been observed in θ-type crystals of (BEDT-TTF)₂I₃ at temperatures below 6 K and in the magnetic field above 3 T. The oscillation appears when the magnetic field of a fixed strength is rotated from the direction normal to the conductive two dimensional plane to a direction parallel to the plane. The period of the oscillation is described by an equation tan (θ_min)=sN (s=0.39, N=0, 1, 2, 3,…), where θ_min is the angle giving the position of the trough of the oscillation. The amplitude of the oscillation is primarily determined by the magnetic field component normal to the conductive plane. It is related to the temperature through the change in the resistivity ₀.     

Specific heat of 1T-Ta0.93Ti0.07S2 in the Anderson localized states

The specific heat of 1T-Ta_0.93Ti_0.07S₂ in the Anderson localized states has been measured from 0.2 to 5.0 K in magnetic fields up to 60 kOe. Below 3.5 K, a Schottky type excess specific heat was observed, depending on the magnetic field. This excess specific heat is explained on the basis of both the Coulomb interactions between different Anderson localized states as well as in the same state.     

Novel polymer incarcerated palladium with phosphinated polymers: active catalyst for Suzuki-Miyaura coupling without external phosphines

[reaction: see text] Immobilization of a palladium catalyst with use of new phosphinated polymers was carried out utilizing the polymer incarcerated (PI) method. This phosphinated PI Pd catalyst showed excellent activity in Suzuki-Miyaura couplings without addition of external phosphine ligands. No leaching of Pd was observed in this reaction, and the catalyst was recovered quantitatively by simple filtration and reused several times without loss of activity.     

Preparation of 3-hydroxyisoindolin-1-ones and o-acylbenzamides. A study of ring-chain tautomerism

3-Hydroxyisoindolinones (ring form) as well as their chain tautomers, o-acylbenzamides, were prepared from the reactions of 3-benzalphthalide 1 , 3-halophthalides 3 , and o-acylbenzoic acids 6 or their esters 7 with amines 2 , and those of phthalimides 4 with Grignard reagents 5 . The characteristic spectroscopic properties of ring and chain forms are observed in the ir and ¹³C-nmr spectra. The significance of the spectroscopic results is discussed, as is the relationship between the structure of the products and the position of the ring-chain equilibrium.     

Spatial confinement effect on the atomic structure of solid argon

Molecules confined in nanopores show unusual behavior not seen in bulk systems. The present paper reports on molecular dynamics simulations of unusual freezing behavior in confined Ar. Similar to bulk Ar, liquid Ar confined in pores with a diameter D>15sigma (5.1 nm), where sigma is the diameter of the Ar atom, crystallizes when the cooling rate is lower than a critical value (Qc). We also find that the spatial confinement does not have significant influence on Qc when D>15sigma (5.1 nm). In the pore of 10sigma (3.4 nm) in diameter, on the other hand, the behavior is dramatically changed. Crystalline Ar does not appear inside the pore even when the system is cooled at a rate lower than the Qc in the bulk system by over two orders of magnitude. Instead, amorphous Ar characterized by local icosahedral configurations is formed in the pore. We further find that, even when crystalline Ar is formed outside the pore, it does not grow deeply into the pore. This supports that the amorphous Ar is actually the most stable phase in the pore. It is well known that Ar is a poor glass former. Our finding that even such an amorphous Ar is the most stable in the pore suggests that, in any system, it is possible to prepare amorphous structure selectively by using nano-molds.     

Reactions of β-sulfenyl α,β-unsaturated ketones with guanidine,Amidines, and diamines

β-Sulfenyl α, β-unsaturated ketones 1a-c reacted with guanidine or amidines to give pyrimidine derivatives 3 in 14-76% yields. Treatment of ketones 1 with diamines such as ethylenediamine and o -phenylenediamine afforded the seven-membered heterocycles, 2,3-dihydro-1,4-diazepine 5 and 2,3-benzo-1,4-diazepines 8a-c .     

The photochemistry of α,β-acetylenic ketones. II. Formation of furan derivatives

The photochemical reactions of α,β-acetylenic ketones have been examined. Irradiation of 1-p-substituted phenyl-2-propyn-1-ones 2–4 in primary alcohols gave 2,5-disubstituted furans 2a–4c. The formation of furans can be explained in terms of cyclization, followed by dehydration of the 1:1-adduct of acetylenic ketone and alcohol, which was formed initially by hydrogen atom abstraction from alcohol by the excited acetylenic ketone. Irradiation of 1-p-tolyl-2-propyn-1-one ( 2 ) in ethanol-d₁ yielded 2-methyl-5-p-tolylfuran ( 2b ) containing no deuterium. This result was consistent with a mechanism that involves hydrogen atom abstraction from alcohol by the carbon of triple bond rather than abstraction by carbonyl oxygen.