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991.
992.
Terminal phosphino groups of [Re2(CO)9(η1-P-P)] (P-P = diphosphines) are activated towards oxidation by Me3NO. The respective reactions of Me3NO with [Re2(CO)9{η1-P(o-anisyl)2(CH2)3PPh2}], [Re2(CO)9{η1-PPh2(CH2)3P(o-anisyl)2}] and [Re2(CO)9(η1-trans-PPh2CHCHPPh2)] were studied to investigate the mechanism of this oxidation. The results are consistent with an intramolecular pathway involving a cyclic intermediate, without exchange of the coordinated and terminal phosphino groups. A mechanism which involves an interaction of the terminal phosphino group with a carbonyl ligand is proposed. In sharp contrast to eq-[Re2(CO)9(η1-P-P)] (P-P = Ph2P(CH2)nPPh2, n = 1-6), eq-[Re2(CO)9(η1-trans-PPh2CHCHPPh2)] appears to be indefinitely stable towards equatorial → axial isomerization at room temperature, thus, allowing its crystal structure to be determined. 相似文献
993.
A new complex of copper(II) picrate (pic) with 1, 3‐bis(1‐allaylbenzimidazol‐2‐yl)‐2‐oxopropane (aobb), with the composition [Cu(aobb)2](pic)2, was synthesized and characterized. The crystal structure of the copper(II) complex revealed that the coordination environment around the central copper(II) atom is a distorted octahedral arrangement. Electronic absorption spectroscopy, ethidium bromide displacement experiments and viscosity measurements indicate that the ligand and the CuII complex can strongly bind to calf thymus DNA, presumably by an intercalation mechanism. Furthermore, the antioxidant activity of the CuII complex was determined by superoxide and hydroxyl radical scavenging method in vitro, which indicate that the CuII complex has the activity to suppress OH · and O2 · –. 相似文献
994.
Two aggregation-induced emission (AIE) macrocycles (DMP[5]-TPE and PCP[5]-TPE) were prepared by embedding Tetraphenylethene (TPE) unit into the skeletons of Dimethoxypillar[5]arene (DMP[5]) and [15]Paracyclophane ([15]PCP) at meso position, respectively. In crystal, the PCP[5]-TPE showed a distorted cavity, and the incubation of hexane inside the DMP[5]-TPE cavity caused a distinct change in the molecular conformation compared to PCP[5]-TPE. There was no complexation between PCP[5]-TPE and 1,4-dicyanobutane (DCB). UV absorption experiments showed the distorted cavity of DMP[5]-TPE hindered association with DCB. 相似文献
995.
FAN Feng-Ying ZHENG Tao YE Yan-Lin JIANG Dong-Xing HUA Hui LI Zhi-Huan GE Yu-Cheng LI Xiang-Qing SHI Fan NEI Peng-Xuan LU Fei 《中国物理C(英文版)》2009,33(Z1)
In order to look for a proposed cluster structure of 16C, simulation work was made. The simulation of the reaction dynamics give the resolution of the excitation energy on 16C which was reconstructed prior to breakup. The excitation energy resolution is typically ~200 keV at 2 MeV above the two body decay threshold for 16C→12Be+4He. Moreover,some performances of detectors tested using 241 Am α source are also reported. 相似文献
996.
We study statistical properties of the Hamiltonian generating phase state. Using the generalized Hellmann-Feynman theorem for ensemble average, we derive its mean energy and find the ratio of the mean energies contributed from the term a†a to that from . The relation on the entropy-variation with respect to the dynamic parameters ω and κ is also examined. 相似文献
997.
In this paper,we report a novel approach to the heteroaryl-condensed nuclei of natural furo[3,2-a]carbazole alkaloids.Our synthetic studies use N-phthaloyl tryptophan methyl ester as starting material and zinc ion mediated transamination reaction as the key step.This work also implicated a novel strategy to assemble other [a]-fused carbazoles. 相似文献
998.
C.K. Fan 《Journal of Algebraic Combinatorics》1996,5(3):175-189
Let (W, S) be a Coxeter group associated to a Coxeter graph which has no multiple bonds. Let H be the corresponding Hecke Algebra. We define a certain quotient \-H of H and show that it has a basis parametrized by a certain subset W
cof the Coxeter group W. Specifically, W
cconsists of those elements of W all of whose reduced expressions avoid substrings of the form sts where s and t are noncommuting generators in S. We determine which Coxeter groups have finite W
cand compute the cardinality of W
cwhen W is a Weyl group. Finally, we give a combinatorial application (which is related to the number of reduced expressions for w W
cof an exponential formula of Lusztig which utilizes a specialization of a subalgebra of \-H. 相似文献
999.
热效应仍是限制激光放大器向高功率、高光束质量进一步发展的瓶颈问题, 高效的热管理是抑制热效应的重要技术途径. 研究了基于激光二极管抽运氦气冷却的钕玻璃叠片激光放大器的热效应. 利用有限元数值模拟的方法, 分析了钕玻璃的温度、应力应变和应力双折射分布, 并计算了热致波前畸变和退偏损耗, 与实验结果符合得较好, 在热沉积为0.7 W/cm3的条件下, 6片钕玻璃总的热致波前畸变为6.77λ , 最大退偏量大于90%. 相似文献
1000.
叠层连续开口圆柱壳的精确解 总被引:2,自引:0,他引:2
抛弃任何有关位移和应力模式的假设,引入δ-函数,对正变异性连续开口圆柱壳建立状态方程.给出薄的、中厚的和强厚的叠层连续开口圆柱壳静力问题的统一的精确解.数值结果和SAPS解进行了对比. 相似文献