A new synthesis of alkynyl tellurides promoted by CsOH and 4(A°) MS

The mixture of cesium hydroxide and terminal alkynes in dry DMF in the presence of 4(A°), molecular sieves was stirred for 3.0 h at room temperature under N2, then aryltellurenyl bromide in THF was added, and the reaction mixture was stirred for 2.0 h. Alkynyl tellurides were obtained in about 90% yields by flash chromatography.     

基于多维名义模型的加权似然估计方法(英文)

The Monte Carlo study evaluates the relative accuracy of Warm's (1989) weighted likelihood estimate (WLE) compared to the maximum likelihood estimate (MLE) using the nominal response model. And the results indicate that WLE was more accurate than MLE.     

分散化供应链的自组织演化机制建模与仿真

供应链是一个复杂适应系统.提出了分散化供应链演化的自组织机制.在开放结构下,多企业主体为了适应外部环境,在非线性互动中涌现出供应链协作结构和协调模式.借鉴生物系统环境适应能力思想,建立了分散化供应链自组织演化模型,并采用Multi-agent技术进行仿真,证明了分散化供应链的自组织演化机制.外部环境和企业内部机制因素控制着分散化供应链的演化,其演化对初始条件高度敏感,存在着锁定、路径依赖和混沌等自组织系统特性.     

Synthesis and characterization of fluorene‐based rod–coil liquid crystal polymers

A series of fluorene‐based rod–coil liquid crystal polymers with different lengths of the coil segments on backbones were designed and synthesized by a palladium‐catalyzed Suzuki coupling‐reaction. The thermal stability, the UV–Vis absorption and fluorescence spectra in chloroform solution and thin film, the electrochemical properties, thermal behavior, and morphology of these rod–coil polymers were investigated. The thermal stability of these polymers steadily decreased on increasing the length of the coil segments on the backbone; their optical and electrochemical properties did not exhibit noticeable dependence on the weight fraction of the coil segments. However, the shoulder emission and the full width at the half‐maximum (FWHM) in PL spectra of the films increased, whereas the oxidation onset potentials and the corresponding HOMO energy levels decreased with the increase in the weight fraction of the coil segments, which was assigned to microphase separation and formation of folded chain conformation as the weight fraction of the coil segments increased. These polymers displayed a characteristic liquid crystalline texture. The variation of the weight fraction of the coil segments obviously affected the thermal behavior and morphology of these rod–coil polymers. Copyright © 2008 John Wiley & Sons, Ltd.     

Dye-sensitized solid-state solar cells fabricated by screen-printed TiO_2 thin film with addition of polystyrene balls

The screen-printed nanoporous TiO2 thin film was employed to fabricate dye-sensitized solid-state solar cells using CuI as hole-transport materials. The solar cell based on nanoporous TiO2 thin film with large pores formed by the addition of polystyrene balls with diameter of 200 nm to the TiO2 paste exhibits photovoltaic performance enhancement, which is attributed to the good contact of CuI with surface of dye-sensitized thin film due to easy penetration of CuI in the film with large pores.     

2维Zakharov方程组爆破解的L2集中率

讨论了2维Zakharov方程组的Caucgy问题的爆破解.对径向对称爆破解,证明了原点0是爆破点,并建立了当t→T(爆破时间)时,集中率的下界.     

A superlinearly convergent norm-relaxed SQP method of strongly sub-feasible directions for constrained optimization without strict complementarity

In this paper, a kind of optimization problems with nonlinear inequality constraints is discussed. Combined the ideas of norm-relaxed SQP method and strongly sub-feasible direction method as well as a pivoting operation, a new fast algorithm with arbitrary initial point for the discussed problem is presented. At each iteration of the algorithm, an improved direction is obtained by solving only one direction finding subproblem which possesses small scale and always has an optimal solution, and to avoid the Maratos effect, another correction direction is yielded by a simple explicit formula. Since the line search technique can automatically combine the initialization and optimization processes, after finite iterations, the iteration points always get into the feasible set. The proposed algorithm is proved to be globally convergent and superlinearly convergent under mild conditions without the strict complementarity. Finally, some numerical tests are reported.     

Generalized Strang–Fix condition for scattered data quasi-interpolation

Quasi-interpolation is very useful in the study of the approximation theory and its applications, since the method can yield solutions directly and does not require solving any linear system of equations. However, quasi-interpolation is usually discussed only for gridded data in the literature. In this paper we shall introduce a generalized Strang–Fix condition, which is related to nonstationary quasi-interpolation. Based on the discussion of the generalized Strang–Fix condition we shall generalize our quasi-interpolation scheme for multivariate scattered data, too. AMS subject classification 41A63, 41A25, 65D10Zong Min Wu: Supported by NSFC No. 19971017 and NOYG No. 10125102.     

倍增型有机光电探测器的研究进展

介绍了倍增型有机光电探测器的发展、工作机理、性能调控及相关的应用探索. 2015年张福俊课题组以单载流子传输通道的给受体混合(质量比约为100:1)薄膜为有源层，率先报道了界面附近受陷电子诱导空穴隧穿注入的倍增型有机光电探测器，并抑制了器件的暗电流密度.通过优化有源层厚度调控了界面附近受陷电荷的体分布，制备出超窄响应的倍增型有机光电探测器，并提出载流子注入窄化的新概念.利用三元策略及双层策略，制备出了宽响应倍增型有机光电探测器.利用光子俘获层调控器件的响应范围，以及利用倍增层获得了较大的外量子效率，将二极管型与倍增型器件的优势集中在一个器件中.引入光学调控层或将宽带隙材料引入有源层中，调控界面附近受陷电子分布，优化了器件的光谱形状，进而制备出响应光谱宽且平的倍增型有机光电探测器.将制备的倍增型有机光电探测器应用到心率监测、单像素成像及光开关等领域，取得较好的应用成果.