深紫外激光光发射与热发射电子显微镜在热扩散阴极研究中的应用

对热扩散阴极表面微区发射状态进行原位观察和分析一直是热阴极研究的重要课题.本文着重介绍深紫外激光光发射电子/热发射电子显微镜的基本原理及其在热扩散阴极研究中的典型实例.系统配备了高温激活所用的加热装置,样品可被加热至1400℃.系统具有光发射电子、阴极热发射电子、光发射电子和阴极热发射电子联合三种电子成像模式.应用表明,对于热扩散阴极而言,深紫外激光光发射电子像适于呈现阴极表面的微观结构形貌;热发射电子像适于反映阴极表面的本征热电子发射及均匀性;光电子和热电子联合成像适于对阴极表面的有效发射点做出精确定位.     

基于MgO:QPLN的多光参量振荡器电场调谐特性理论与实验研究

报道了基于掺氧化镁准周期极化铌酸锂(MgO:QPLN)的多光参量振荡器电场调谐特性理论与实验研究. 通过对电场调谐能力与极化结构参数间关联性的理论分析, 确定了高正负晶畴比MgO:QPLN电场调谐的可行性, 并模拟得到跨周期参量光输出波长与加载电压的关系曲线. 实验中通过对MgO:QPLN有效的电场加载, 实现了3.84 μm波段参量光的电场调谐, 频谱调谐带宽约6 nm, 调谐速率接近1 nm/kV, 进一步结合温度调谐, 实现了参量光宽谱段高精度的连续调谐. 所获得实验结果与理论模拟结果基本符合, 电场调谐在精度控制、快速响应方面相比于传统温度调谐更具技术优势.     

基于MgO:APLN的1.57μm/3.84μm连续波内腔多光参量振荡器研究

报道了一种基于MgO:APLN实现1.57 μm和3.84 μm跨周期参量光连续输出的内腔抽运多光参量振荡器. 采用1064 nm谐振腔与多光参量振荡腔折叠型复合结构, 综合考虑高功率抽运下谐振腔的热稳定性及多光参量振荡过程的光斑模式匹配, 通过对两个子腔谐振结构的数值模拟分析, 确定了最佳腔型参数. 在此基础上, 进一步研究了谐振参量光透过率对振荡阈值、抽运光下转换效率、输出功率稳定性的影响, 最终实现了3.13 W的1.57 μm和0.85 W的3.84 μm参量光输出, 对应斜效率为6.8%和1.9%, 输出功率稳定性分别达到了1.8%和3%.     

NⅡ离子2p4f—2p3d辐射跃迁概率的理论研究

在全相对论理论框架下，利用多组态Dirac-Fock(MCDF)方法，系统计算了NⅡ离子2p4f—2p3d的辐射跃迁概率，得到的结果与已有实验值符合很好.具体计算中，详细分析了相对论效应、电子关联、弛豫效应、Breit相互作用和量子电动力学(QED)效应对能级精细结构及辐射跃迁概率的影响.结果表明：相对论效应、电子关联和弛豫效应对NⅡ 2p4f-2p3d辐射跃迁概率有很重要的影响,考虑了这些效应后计算值得到明显改善.     

氧气氛低温退火Pt/Ba0.8Sr0.2TiO3Pt引起的低频介电弛豫效应

研究了在不同温度区间氧气氛和氮气氛退火后处理对PtBa0.8Sr0.2TiO3Pt介电特性的影响.经过高温550℃氮气退火处理后,再放入350℃的氧气中退火,发现样品的介电特性出现了非常明显的低频弛豫现象,并且这种低频弛豫现象在350℃的氮气中退火后将会消失.通过在出现低频弛豫现象的样品的上下电极加一偏压,可以发现低频弛豫现象更加明显,并且在撤消偏压后这种增强将会逐渐减弱,直至最终恢复到偏压前的弛豫状态 关键词： 脉冲激光沉积 介电弛豫 动态随机存储器     

电子商务中人类活动的标度行为实证研究

应用去趋势波动分析法,对电子商务中人类网上购物行为进行研究,首次探讨了人类浏览及购买行为时间序列(数量波动)标度律.首先,研究发现人类网上购物行为呈现出明显的周期性,其时间序列的概率密度函数具有显著的双模态特征.其次,利用傅里叶变换方法分析浏览以及购买行为时间序列的功率谱,发现其演化过程不同于无关联的泊松过程.最后,基于功率谱过滤周期性趋势的影响,对去除周期趋势后的浏览和购买行为时间序列进行去趋势波动分析,发现其标度行为表明其具有较强的长程关联特性,且平均标度值近似为1,表明其具有自组织临界性.实证研究结果与其他领域如因特网交通流和金融市场价格波动的标度行为相似,有助于理解人类活动如何影响电子商务系统演化和提高在线商务活动效率,对分析电子商务中人类行为活动的机制和预测其波动趋势具有重要的启示作用.     

Why to synthesize vaterite polymorph of calcium carbonate on the cellulose matrix via sonochemistry process?

Vaterite is an important biomedical material due to its features such as high specific surface area, high solubility, high dispersion, and small specific gravity. The purposes of this article were to explore the growth mechanism of vaterite on the cellulose matrix via sonochmistry process. In the work reported herein, the influences of experimental parameters on the polymorph of calcium carbonate were investigated in detail. The calcium carbonate crystals on the cellulose matrix were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Experimental results revealed that all the reactants, solvent, and synthesis method played an important role in the polymorph of calcium carbonate. The pure phase of vaterite polymorph was obtained using Na₂CO₃ as reactant in ethylene glycol on the cellulose matrix via sonochmistry process. Based on the experimental results, one can conclude that the synthesis of vaterite polymorph is a system process.     

ZnO–SnO2 branch–stem nanowires based on a two-step process: Synthesis and sensing capability

ZnO–SnO₂ branch–stem nanostructures were realized on a basis of a two-step process. In step 1, SnO₂-stem nanowires were synthesized. In step 2, ZnO-branch nanowires were successfully grown on the SnO₂-stem nanowires through a simple evaporation technique. We have pre-deposited thin Au layers on the surface of SnO₂ nanowire stems and subsequently evaporated Zn powders on the nanowires. The ZnO branches, which sprouted from the SnO₂ stems, had diameters in a range of 30–35 nm. As-synthesized branches were of single crystalline hexagonal ZnO structures. Since the branch tips were comprised of Au-containing nanoparticles, the Au-catalyzed vapor–liquid–solid growth mechanism was more likely to control the growth process of the ZnO branches. To test a potential use of ZnO–SnO₂ branch–stem nanostructures in chemical gas sensors, their sensing performances with respect to NO₂ gas were investigated, showing the promising potential in chemical gas sensors.