Synthesis and Properties of Carbocyclic Schiff Bases

New Schiff bases containing both adamantyl and phenyl fragments in a single molecule were synthesized by condensation of appropriate diamines with aromatic aldehydes. The condensation products were brought into reduction and nucleophilic addition reactions.     

Use of interphase catalysis in the synthesis of 2-acyl-4-oxopyrazino[2,1-α]isoquinolines and 4-acyl-2-piperazinones

2-Acetyl-4-oxopyrazino[2,1-a]isoquinolines and 4-acyl-2-piperazinones have been synthesized, with interphase catalysis, by the intramolecular N-alkylation of the corresponding diamides.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1107–1109, August, 1991.     

Optical constants of lead telluride films in the range 5–11 μm

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 1, pp. 103–107, January, 1991.     

Algebraic Bethe Ansatz for SO(N)-invariant transfer matrices

A matrix version of an algebraic Bethe Ansatz is proposed for R-matrices of a special structure. It is shown that SO(N)-invariant R-matrices in spinor representation possess this special structure. Eigenvalues of transfer matrices corresponding to these R-matrices are computed.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im. V. A. Steklova AN SSSR, Vol. 169, pp. 122–140, 1988.     

In situ transmission electron microscopy study of the nucleation and grain growth of Ge2Sb2Te5 thin films

The nucleation and grain growth of the Ge₂Sb₂Te₅ (GST) thin films were studied using high voltage electron microscope operated at 1250 kV. As a result, we have found that 2 nm-sized nucleus forms as a cluster which atoms are arranged regularly at the stage of nucleation prior to the formation of grains having crystal structure. The high-resolution transmission electron microscopy study and fast-Fourier transformations revealed that coexistence of face-centered-cubic (FCC) and hexagonal structure occurs, and formation of twin defect is found in the hexagonal structure during the grain growth as the annealing temperature is increased. GST grain having the hexagonal structure grow from the surface, and the growth proceeded perpendicular to the [0 0 0 1], namely the path parallel to the (0 0 0 1) plane. Consequently, grain growth to a large-scale result in a lengthened shape.     

Retrieval of the vertical distribution of chemical components in the mesosphere from simultaneous measurements of ozone and hydroxyl distributions

We propose a method for retrieval of directly unmeasurable concentrations of minor gas constituents of the mesosphere from available experimental data using simplified models of atmospheric photochemical systems. The method is used for processing of the results of simultaneous measurements of ozone and hydroxyl concentrations within the framework of the CRISTA-MAHRSI satellite experiments. As a result, vertical distributions of concentrations of three more key chemical components of the mesosphere, namely, atomic oxygen, atomic hydrogen, and hydroperoxide, were retrieved. It is shown that a limiting altitude-dependent ratio between OH and O₃ concentrations is valid in the mesosphere and lower thermosphere. It is found that CRISTA-MAHRSI data satisfy this ratio up to an altitude of 87 km, but a strong discrepancy between theory and experiment arises in the upper region. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 49, No. 9, pp. 760–769, September 2006.