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991.
Subhash C. Mishra Rohan Ranganath Vernekar 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(16):2088-2099
Application of the lattice Boltzmann method (LBM) recently proposed by Asinari et al. [Asinari P, Mishra SC, Borchiellini R. A lattice Boltzmann formulation to the analysis of radiative heat transfer problems in a participating medium. Numer Heat Transfer B 2010; 57:126–146] is extended to the analysis of transport of collimated radiation in a planar participating medium. To deal with azimuthally symmetric radiation in planar medium, a new lattice structure for the LBM is used. The transport of the collimated component in the medium is analysed by two different, viz., flux splitting and direct approaches. For different angles of incidence of the collimated radiation, the LBM formulation is tested for the effects of the extinction coefficient, the anisotropy factor, and the boundary emissivities on heat flux and emissive power distributions. Results are compared with the benchmark results obtained using the finite volume method. Both the approaches in LBM provide accurate results. 相似文献
992.
Prateek Jain Pradyumn Kumar Sahoo Bivudutta Mishra 《International Journal of Theoretical Physics》2012,51(8):2546-2551
The purpose of this paper is to investigate the role of wet dark fluid in axially symmetric cosmological model within the frame work of bimetric theory of gravitation proposed by Rosen (Gen. Relativ. Gravit. 4:435, 1973). In this theory, it is observed that there is no contribution from wet dark fluid. 相似文献
993.
Rasmita Sahoo Rashmi Ranjan Mishra 《Journal of Experimental and Theoretical Physics》2012,114(5):805-809
The phonon dispersion of graphene is derived by using a simple mass spring model and considering up to the first, second, third, and fourth nearest-neighbor interactions. The results obtained from different nearest-neighbor interactions are compared and it is shown that the k 2 dependence for the out-of-plane transverse acoustic mode obtained in other sophisticated methods as well as experiment occurs only after including the fourth nearest-neighbor interaction. 相似文献
994.
The kinetics of chiral transitions in quark matter is studied in a two-flavor Nambu-Jona-Lasinio model. We focus on the phase-ordering dynamics subsequent to a temperature quench from the massless quark phase to the massive quark phase. We study the dynamics by considering a phenomenological model (Ginzburg-Landau free-energy functional). The morphology of the ordering system is characterized by the scaling of the order-parameter correlation function. 相似文献
995.
Wireless sensor networks (WSNs) have received extensive attention due to their great potential in civil and military applications. The sensor nodes have limited power and radio communication capabilities. As sensor nodes are resource constrained, they generally have weak defense capabilities and are attractive targets for software attacks. Cyber attack by worm presents one of the most dangerous threats to the security and integrity of the computer and WSN. In this paper, we study the attacking behavior of possible worms in WSN. Using compartmental epidemic model, we propose susceptible – exposed – infectious – recovered – susceptible with a vaccination compartment (SEIRS-V) to describe the dynamics of worm propagation with respect to time in WSN. The proposed model captures both the spatial and temporal dynamics of worms spread process. Reproduction number, equilibria, and their stability are also found. If reproduction number is less than one, the infected fraction of the sensor nodes disappears and if the reproduction number is greater than one, the infected fraction persists and the feasible region is asymptotically stable region for the endemic equilibrium state. Numerical methods are employed to solve and simulate the systems of equations developed and also to validate our model. A critical analysis of vaccination class with respect to susceptible class and infectious class has been made for a positive impact of increasing security measures on worm propagation in WSN. 相似文献
996.
Mphilisi M. Mahlambi Ajay K. Mishra Shivani B. Mishra Rui W. Krause Bhekie B. Mamba Ashok M. Raichur 《Journal of Thermal Analysis and Calorimetry》2012,110(2):847-855
Titania (TiO2) nano-photocatalysts, with different phases, prepared using a modified sol?Cgel process were employed in the degradation of rhodamine at 10?mg?L?1 concentration. The degradation efficiency of these nano-photocatalysts was compared to that of commercial Degussa P25 titania. It was found that the nanocatalysts calcined at 450?°C and the Degussa P25 titania had similar photoreactivity profiles. The commercial Degussa P25 nanocatalysts had an overall high apparent rate constant of (K app) of 0.023?min?1. The other nanocatalyst had the following rate constants: 0.017, 0.0089, 0.003 and 0.0024?min?1 for 450, 500, 550 and 600?°C calcined catalysts, respectively. This could be attributed to the phase of the titania as the anatase phase is highly photoactive than the other phases. Furthermore, characterisation by differential scanning calorimetry showed the transformation of titania from amorphous to anatase and finally to rutile phase. SEM and TEM characterisations were used to study the surface morphology and internal structure of the nanoparticles. BET results show that as the temperature of calcinations was raised, the surface area reduced marginally. X-ray diffraction was used to confirm the different phases of titania. This study has led to a conclusion that the anatase phase of the titania is the most photoactive nanocatalyst. It also had the highest apparent rate constant of 0.017?min?1, which is similar to that of the commercial titania. 相似文献
997.
This article is written from an organic chemist's point of view and provides an up-to-date review about organic solar cells based on small molecules or oligomers as absorbers and in detail deals with devices that incorporate planar-heterojunctions (PHJ) and bulk heterojunctions (BHJ) between a donor (p-type semiconductor) and an acceptor (n-type semiconductor) material. The article pays particular attention to the design and development of molecular materials and their performance in corresponding devices. In recent years, a substantial amount of both, academic and industrial research, has been directed towards organic solar cells, in an effort to develop new materials and to improve their tunability, processability, power conversion efficiency, and stability. On the eve of commercialization of organic solar cells, this review provides an overview over efficiencies attained with small molecules/oligomers in OSCs and reflects materials and device concepts developed over the last decade. Approaches to enhancing the efficiency of organic solar cells are analyzed. 相似文献
998.
Samanta S Mishra BK Pace TC Sathyamurthy N Bohne C Moorthy JN 《The Journal of organic chemistry》2006,71(12):4453-4459
The phenomenon of beta-phenyl quenching has been examined by laser-flash photolysis in a series of alpha- and/or beta-substituted ketones 4-8 with similar excited-state characteristics. It is found that alpha-substitution markedly increases the triplet lifetimes in contrast to beta-substitution. The force field calculations for the various staggered conformers of ketones 4-6 and 8-syn show that the lowest-energy conformation in all these ketones has the carbonyl group and the beta-phenyl ring gauche to each other. Despite this geometrical requirement, the longer lifetimes observed are interpreted as being due to the influence of the alpha-substituent on the rotational freedom of the planar benzoyl moiety as a whole. The experimental results are suggestive of the attainment of what appears to be a critical geometry for quenching. This scenario may be likened to Norrish type II reactions, where the alpha-substituent has long been known to suppress the elimination pathway and promote Yang cyclization. In addition, we have shown that the diastereomers of alpha,beta-disubstituted ketones exhibit distinct lifetimes. 相似文献
999.
This paper describes the evaluation of synchronous fluorescence spectroscopy (SFS) and excitation emission matrix fluorescence (EEMF) spectroscopy as means of monitoring transformer oil degradation. When accelerated thermal ageing method is used, the onset of degradation of transformer oil on 17th day and transformer oil with polypropylene and cellulosic paper on 23rd and 27th days is sensitively reflected in the SFS and EEMF fluorescence spectral characteristics. 相似文献
1000.
The regioselective aminoethylation of 1,4-benzodiazepin-2-one 1 can be carried out using classical heating or microwave irradiation as the source of energy to furnish either N-1 or N-4 aminoethylated products 2a-d and 3a-d, respectively. The regioselectivity observed has been rationalized using computational studies and has been traced to the disparity of the rate-determining steps along the N-1 product (N-1 PR) and N-4 product (N-4 PR) formation pathways. 相似文献