全文获取类型
收费全文 | 624篇 |
免费 | 137篇 |
国内免费 | 126篇 |
专业分类
化学 | 453篇 |
力学 | 11篇 |
综合类 | 7篇 |
数学 | 161篇 |
物理学 | 255篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 9篇 |
2021年 | 6篇 |
2020年 | 19篇 |
2019年 | 23篇 |
2018年 | 12篇 |
2017年 | 8篇 |
2016年 | 26篇 |
2015年 | 25篇 |
2014年 | 20篇 |
2013年 | 50篇 |
2012年 | 37篇 |
2011年 | 52篇 |
2010年 | 39篇 |
2009年 | 57篇 |
2008年 | 46篇 |
2007年 | 40篇 |
2006年 | 43篇 |
2005年 | 39篇 |
2004年 | 35篇 |
2003年 | 38篇 |
2002年 | 60篇 |
2001年 | 52篇 |
2000年 | 27篇 |
1999年 | 32篇 |
1998年 | 15篇 |
1997年 | 8篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
排序方式: 共有887条查询结果,搜索用时 0 毫秒
81.
Yan‐Long Qian Xin‐Rong Qin Ji‐Ling Huang Albert Sun‐Chi Chan Shou‐Shan Chen Hong‐Gen Wang 《中国化学》2001,19(1):97-101
The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl4·2THF, ZrCl4 and (CpTiCl2)2O respectively, to give complexes 1–5. The complex [η5‐1‐methyl‐3‐(α, α‐dimethylbenzyl) cyclopentadienyl] titanium dichloride has been studied by X‐ray diffraction. The red crystal of this complex is monoclinic, space group P2t/C with unit cell parameters: a =6.973(6) × 10?1 nm, b =36.91(2) × 10?1 nm, c = 10.063(4) × 10?1 nm, α=β= γ = 93.35(5)°, V = 2584(5) × 10?3 nm3 and Z = 4. Refinement for 1004 observed reflections gives the final R of 0.088. There are four independent molecules per unit cell. 相似文献
82.
83.
Chao-Shang Huang Tianjun Li Wei Liao Qi-Shu Yan Shou Hua Zhu 《The European Physical Journal C - Particles and Fields》2000,18(2):393-403
We reconsider the dimension-11 Planck scale, the physical scale of the eleventh dimension, the physical scale of the Calabi–Yau
manifold and the coupling in the hidden sector in M-theory on . Also we discuss reasonable bounds on them. Considering the F-term of the dilaton and moduli SUSY breaking and choosing two
representative points which correspond to the scalar quasi-massless scenario and the dilaton dominant SUSY breaking scenario,
respectively, we analyze experimental constraints on the parameter space. The sparticle spectrum and some phenomenological
predictions are also given.
Received: 9 June 1999 / Revised version: 12 July 2000 / Published online: 27 November 2000 相似文献
84.
描述用单光束激光复活制银盐白光显示反射全息图的技术,本技术的关键:1)母全息图的颜色必须恢复到满足其布拉格条件;2)复制所用的光波与记录母全息图时的参考的相同;(3)复制所用的激光采用平行偏振,以减少界面反射;94)采用白糖溶液作为折射率匹配液,取得极佳效果。 相似文献
85.
86.
Tomohiro Hirano Shuhei Masuda Shou Nasu Koichi Ute Tsuneyuki Sato 《Journal of polymer science. Part A, Polymer chemistry》2009,47(4):1192-1203
Radical polymerization of N,N‐dimethylacrylamide (DMAAm) was investigated in the presence of tartrates, such as diethyl L ‐tartrate, diisopropyl L ‐tartrate, and di‐n‐butyl L ‐tartrate, in toluene at low temperatures. Syndiotactic polymers were obtained in the presence of tartrates, whereas isotactic polymers were obtained in the absence of tartrates. The syndiotactic‐specificity increased with increasing amount of tartrates and with decreasing polymerization temperature. NMR analysis suggested that DMAAm and tartrates formed a 1:1 complex through double hydrogen bonding. A mechanism for the syndiotactic‐specific radical polymerization of DMAAm is proposed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1192–1203, 2009 相似文献
87.
Tomohiro Hirano Shou Nasu Akihiro Morikami Koichi Ute 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6534-6539
Radical polymerization of N‐methylacrylamide (NMAAm), N,N‐dimethylacrylamide (DMAAm), and N‐methyl‐N‐phenylacrylamide (MPhAAm) was investigated in toluene at low temperatures. Atactic, isotactic, and syndiotactic polymers were obtained by the polymerization of NMAAm, DMAAm, and MPhAAm, respectively, indicating that the stereospecificity of the radical polymerization of acrylamide derivatives depended on the N‐substituents of the monomer used. From the viewpoint of monomer structure, the origin of the stereospecificity of radical polymerization of NMAAm derivatives is discussed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6534–6539, 2009 相似文献
88.
A facile method for solid‐phase organic synthesis of 1‐substituted‐4‐vinyl‐1,2,3‐triazoles from polystyrene‐supported but‐3‐ynyl selenide has been developed. This sequential [3+2] cycloaddition and oxidation–elimination reactions could be carried out under mild reaction conditions with straightforward operation and good yield and purity of the products, and broad scope of substrates, and could be applied in this reaction system in generation of a small library of title compounds. 相似文献
89.
90.
In this paper,some properties of quasi-type δ semigroups with an adequate transversal are explored.In particular,abundant semigroups with a cancellative transversal are character-ized.Our results generalize and enrich Saito's results on quasi-orthodox semigroups with an inverse transversal. 相似文献