全文获取类型
收费全文 | 983篇 |
免费 | 21篇 |
专业分类
化学 | 751篇 |
晶体学 | 22篇 |
力学 | 16篇 |
数学 | 24篇 |
物理学 | 191篇 |
出版年
2023年 | 3篇 |
2022年 | 9篇 |
2021年 | 7篇 |
2020年 | 9篇 |
2019年 | 12篇 |
2018年 | 8篇 |
2017年 | 6篇 |
2016年 | 11篇 |
2015年 | 10篇 |
2014年 | 17篇 |
2013年 | 59篇 |
2012年 | 53篇 |
2011年 | 46篇 |
2010年 | 29篇 |
2009年 | 25篇 |
2008年 | 51篇 |
2007年 | 52篇 |
2006年 | 46篇 |
2005年 | 66篇 |
2004年 | 51篇 |
2003年 | 36篇 |
2002年 | 66篇 |
2001年 | 23篇 |
2000年 | 29篇 |
1999年 | 26篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1996年 | 10篇 |
1995年 | 5篇 |
1994年 | 9篇 |
1993年 | 14篇 |
1992年 | 11篇 |
1991年 | 21篇 |
1990年 | 11篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 12篇 |
1985年 | 12篇 |
1984年 | 16篇 |
1983年 | 15篇 |
1982年 | 5篇 |
1981年 | 9篇 |
1980年 | 14篇 |
1979年 | 7篇 |
1978年 | 17篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1974年 | 3篇 |
1972年 | 4篇 |
排序方式: 共有1004条查询结果,搜索用时 31 毫秒
81.
We study the infrared stability of global symmetries. It is shown that small orthogonal groups O(N) (N < 4) are infrared attractive, while their direct products are unstable. We also discuss the stability of simple supersymmetric models and the role of auxiliary fields. 相似文献
82.
Yoshihiro Takahashi Takashi Kitamura Kenji Uchida Masao Tomura 《Journal of luminescence》1980,21(3):269-275
Emission spectra and decay times of the fluorescence excited at the absorption edge region in pyrene crystals were measured. At liquid nitrogen temperature, the fluorescence under the excitation at 390 nm is considered as the excimer emission and its band peak shifts a little to the short wavelength in comparison with that of the excimer emission under the excitation at 360 nm. The emission decay times under the excitation at the 390 nm and 360 nm are about 155 ns and 180 ns, respectively, at liquid nitrogen temperature. The former decay time changes its value abruptly near 127 K. This abrupt change of the decay time may be due to the phase transition in pyrene crystals. 相似文献
83.
Ihara T Fujii T Mukae M Kitamura Y Jyo A 《Journal of the American Chemical Society》2004,126(29):8880-8881
Anthracene readily forms photoadducts, anthracene dimers, and this photodimerization reaction has been well characterized. In general, however, the reaction requires close proximity and certain spatial alignment of both reaction partners. DNA could provide an ideal scaffold for accelerating the photocyclic addition. We synthesized a number of anthracene-DNA conjugates. The sequences of the conjugates, 5'AntODNn and 3'AntODNn (the length of methylene linkers: n = 3 or 6), were designed to bind adjacent sequences of the template with the anthracene units directed such that they stacked with each other. The conjugates were only dimerized in the presence of the template by light irradiation. The efficiency was affected by one-base displacement in the template sequence. 相似文献
84.
85.
Ashihara S Shimura T Kuroda K Yu NE Kurimura S Kitamura K Ro JH Cha M Taira T 《Optics letters》2003,28(16):1442-1444
Large nonlinear phase shifts were generated with femtosecond pulses at 1560 nm through cascaded quadratic interactions in periodically poled MgO-doped LiNbO3. The off-diagonal component of the nonlinear coefficient was utilized for simultaneous quasi phase matching and group-velocity matching. The effective nonlinear refractive index was varied from -2.9 x 10(-14) to +3.3 x 10(-14) cm2/W by tuning the phase-mismatch conditions. 相似文献
86.
We observed a small-signal gain of Ar2* emission at 126 nm by use of a hollow fiber to guide the high-intensity laser propagation in high-pressure Ar. The small-signal gain coefficient was measured to be 0.05 cm(-1) at 126 nm. Kinetic analysis revealed that the electrons produced by the high-intensity laser through an optical-field-induced ionization process initiated the Ar2* production processes. The increase in the emission intensity was measured to be exp(2.5), with an increase in the fiber length. 相似文献
87.
Yamasaki R Tanatani A Azumaya I Saito S Yamaguchi K Kagechika H 《Organic letters》2003,5(8):1265-1267
[reaction: see text] Introduction of an electron-withdrawing group on the aromatic ring of N-methylacetanilide decreased the ratio of the cis conformer, and the ratio correlates well with the Hammett sigma values of the substituents. These steric properties can be applied to achieve amide conformational switching by protonation at the aromatic substituent of 4-[bis(dimethylamino)]-N-methylacetanilide or N-[p-(dimethylamino)phenyl]-N-phenylacetamide. 相似文献
88.
89.
Yuta Kitamura Noriyuki Miyazaki Toshiro Mabuchi Teruhiko Nawata 《Journal of Crystal Growth》2009,311(15):3954-3962
We developed a method for simulating birefringence of an annealed ingot of MgF2 single crystal for lithography optics. This method provides the optical path difference caused by crystal symmetry and residual stress existing in the crystal. The method consists of the heat conduction analysis, the residual stress analysis and the birefringence analysis. Because there exists no experimental data on the inelastic behavior of MgF2 single crystal, the residual stress was estimated with the elastic thermal stress analysis using the finite element method by assuming a stress-free temperature. In this analysis, the temperature dependence of material properties and crystal anisotropy were taken into account. In the birefringence analysis, the distributions of optical path difference were calculated by an approximate method using the result of the residual stress analysis. This approximate method uses the average stress along the wave normal and is equivalent to the exact method in case of low stress dealt with the present study. In this analysis, it is possible to consider both the intrinsic birefringence and the stress birefringence in any crystal orientation. The distribution of the optical path difference in the annealed ingot obtained from the present calculation agrees qualitatively with that of the experiment. Its calculated value also agrees reasonably well with that of the experiment, when a stress-free temperature is adequately selected. 相似文献
90.