全文获取类型
收费全文 | 304篇 |
免费 | 18篇 |
国内免费 | 1篇 |
专业分类
化学 | 191篇 |
晶体学 | 1篇 |
力学 | 22篇 |
数学 | 33篇 |
物理学 | 76篇 |
出版年
2023年 | 2篇 |
2022年 | 12篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 11篇 |
2018年 | 14篇 |
2017年 | 11篇 |
2016年 | 21篇 |
2015年 | 14篇 |
2014年 | 19篇 |
2013年 | 26篇 |
2012年 | 26篇 |
2011年 | 29篇 |
2010年 | 21篇 |
2009年 | 15篇 |
2008年 | 15篇 |
2007年 | 14篇 |
2006年 | 7篇 |
2005年 | 9篇 |
2003年 | 2篇 |
2002年 | 1篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1981年 | 1篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1964年 | 1篇 |
1962年 | 1篇 |
1958年 | 1篇 |
1957年 | 3篇 |
1956年 | 1篇 |
排序方式: 共有323条查询结果,搜索用时 15 毫秒
41.
42.
Dr. Luis M. Mori‐Quiroz Kirk W. Shimkin Dr. Sina Rezazadeh Ryan A. Kozlowski Prof. Dr. Donald A. Watson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(44):15654-15658
The oxidative copper‐catalyzed cross‐coupling of functionalized alkyl boronic esters with primary amides is reported. Through the identification of appropriate diketimine ligands, conditions for efficient coupling of both primary and secondary alkyl boronic esters with diverse primary amides, including acetamide, have been developed. 相似文献
43.
44.
Micro-Raman investigations of mixed gas hydrates 总被引:2,自引:0,他引:2
We report laser Raman spectroscopic measurements on mixed hydrates (clathrates), with guest molecules tetrahydrofuran (THF) and methane (CH4), at ambient pressure and at temperatures from 175 to 280 K. Gas hydrates were synthesized with different concentrations of THF ranging from 5.88 to 1.46 mol%. In all cases THF molecules occupied the large cages of sII hydrate. The present studies demonstrate formation of sII clathrates with CH4 molecules occupying unfilled cages for concentrations of THF ranging from 5.88 to 2.95 mol%. The Raman spectral signature of hydrates with 1.46 mol% THF are distinctly different; hydrate growth was non-uniform and structural transformation occurred from sII to sI prior to clathrate melting. 相似文献
45.
Hydrogen production by PEM water electrolysis is one of the most efficient methods, due to the produced high purity of gases, high efficiency, and devoid of harmful emissions. In this study, phosphorus-doped carbon nanoparticles (P-CNPs) were synthesized by spray pyrolysis method in chemical vapor deposition (CVD). The synthesized P-CNPs were used as electron carrier support materials for the preparation of P-CNPs-supported palladium (Pd/P-CNPs) electrocatalyst and also used as the hydrogen evolution reaction (HER) electrode in PEM water electrolysis. These synthesized Pd/P-CNPs were characterized by field emission scanning electron microscope, energy-dispersive X-ray spectroscopy, X-ray diffraction, and cyclic voltammetry methods. The membrane electrode assemblies (MEAs) were fabricated using Pd/P-CNPs as a cathode catalyst for the HER and RuO2 as the anode for oxygen evolution reaction (OER). The fabricated MEA electrochemical performances along with their corresponding yields of hydrogen production were evaluated in PEM water electrolyzer single cell assemblies at various experimental conditions. The obtained results showed that the synthesized Pd/P-CNPs observed a current density of 1 A cm?2 at 2 V at 80 °C. Further, long-term stability tested for up to 500 h continuously and showed the reasonable stability with similar electrochemical activity compared to commercial Pt/CB. Hence, the synthesized Pd/P-CNPs could be used as the alternative to Pt-based catalysts for HER. 相似文献
46.
A fiber-optic system design with optical backpropagation that uses an optical phase conjugator, high-dispersion fibers, and highly nonlinear fibers is investigated. The proposed technique outperforms the midpoint optical phase conjugation and digital backpropagation with the same step size. 相似文献
47.
Water-distilled essential oils from leaves of Hymenocrater yazdianus Rech.f., flowers of Stachys obtusicrena Boiss., and stems and flowers of Nepeta asterotricha Rech.f., which are endemic to Iran, were analyzed by GC and GC/MS. Fifty-five components of the leaf oil of H. yazdianus were characterized, representing 95.1% of the total components detected. The major constituents were identified as 1,8-cineole (17.6%), beta-caryophyllene (13.9%), alpha-pinene (10.6%) and caryophyllene oxide (10.4%). Germacrene-D (37.5%) and alpha-bisabolol (23.5%) were the main components among the twenty constituents characterized in the flower oil of S. obtusicrena, representing 90.8% of the total components detected. Thirty-five compounds representing 93.0% of the stem oil of N. asterotrica were identified among which terpinen-4-ol (22.8%) and gamma-terpinene (14.1%) were the major ones. The flower oil of the species was characterized by higher amounts of terpinen-4-ol (24.8%), 4a alpha, 7a beta-nepetalactone (18.2%) and 1,8-cineole (11.6%) among the thirty-three components comprising 98.5% of the total oil detected. The antibacterial activity of the stem, leaf and flower oils of Hymenocrater yazdianus, Stachys obtusicrena and Nepeta asterotricha against seven Gram-positive and Gram-negative bacteria were determined using the MIC method. The growth inhibitory zone (mm) was also measured. 相似文献
48.
Bagineni PrasadK. Shiva Kumar P. Vijaya BabuK. Anusha D. RambabuAjit Kandale G.R. VanajaArunasree M. Kalle Manojit Pal 《Tetrahedron letters》2012,53(45):6059-6066
AlCl3 facilitated C-N bond forming reaction between 2,3-dichloroquinoxaline and anilines affording a convenient method for the preparation of N-aryl substituted 3-chloroquinoxalin-2-amines. A related N-benzyl derivative, however, was prepared via a conventional method. These N-alkyl/aryl substituted 3-chloroquinoxalin-2-amines on coupling with terminal alkynes in toluene under Pd/C-Cu catalysis afforded a range of 1,2-disubstituted pyrrolo[2,3-b]quinoxalines within 3-5 h in good to excellent yields. Some of the compounds synthesized showed promising anti-proliferative properties when tested in vitro against two cancer cell lines. Docking studies indicated that these molecules interact well with human Akt in silico. 相似文献
49.
Chian Wen Chan Anke Brems Shiva Mahmoudi Jan Baeyens Jonathan Seville David Parker Thomas Leadbeater Joseph Gargiuli 《Particuology》2010,8(6):623-630
Laboratory and industrial risers are equipped with exits of many different layouts, and numerous publications discuss the influence of riser exit geometry on local and overall solids hydrodynamics in the riser. The present paper reviews literature findings--mostly based upon indirect experimental techniques and often somewhat contradictory, Direct measurement of particle velocity and particle occupancy near and in the riser exit provide a better indication of the effect of riser exit geometry. Positron Emission Particle Tracking (PEPT) was used in this work for the first time to investigate the exit region of the riser, An abrupt or sharp exit causes particles to be knocked out of the gas flow, so forming a recirculation or reflux region in the upper part of the riser. This is much less pronounced with a curved or gradual exit. 相似文献
50.