Si-Csl（TI）望远镜探测系统用于大动态范围空间重离子鉴别与测量的研究

太阳极轨射电望远镜（SPORT）是一颗从事太阳活动研究的卫星。重离子探测仪是其中的高能粒子探测仪的关键组成部分。鉴于重离子探测仪对多种类离子（2 ≤ Z ≤ 26）的鉴别和大范围能段（8～300 MeV/u）的测量需求,中国科学院近代物理研究所设计并研制了一套Si-CsI（Tl）望远镜探测系统样机,这套望远镜系统由1个Si探测器、1个入射面为正六边形的CsI（Tl）晶体及其专用电子学系统构成。利用兰州重离子加速器冷却储存环系统（HIRFL-CSR）提供的高品质束流对这套望远镜探测系统样机进行了在束测试,完成了种类为2 ≤ Z ≤ 18的重离子直接测量与鉴别,利用直接测量的重离子,进行外推得到,最高测量要求的300MeV/u Fe离子也在设计要求的范围内。实验结果显示这套望远镜探测器样机满足空间中对大范围能段重离子探测的设计需求,该套方案为SPORT计划中的重离子探测仪的设计及建造奠定了很好的技术基础。Solar Polar Orbit Radio Telescope (SPORT) project, aimed at solar activities and solar atmosphere, is a satellite-borne apparatus which is composed by many sub-payloads and is under development in China. High Energy Heavy Ion Telescope (HEHIT) is one of most key sub-payloads in this project, and the main purpose of HEHIT is to identify space heavy ions (2 ≤ Z ≤ 26) with a broad energy range (8～300 MeV/u). In this paper, a prototype telescope of HEHIT, which includes a silicon detector, a CsI(Tl) crystal with regular hexagonal incident plane and customized electronic system, has been developed in the Institute of Modern Physics, Chinese Academy of Sciences (IMP, CAS). To obtain the performance of the prototype telescope, this telescope was tested with high quality beams provided by the accelerator of Heavy Ions Facility and Cooler-Storage-Ring in Lanzhou (HIRFL-CSR). The heavy ions ranging from Z =2 to Z =18 were clearly identified and measured from the beam test and an extrapolation was also done reasonably and it showed that the prototype detector could meet the requirement of t Fe(Z =26) with energy up to 300 MeV/u. In a word, this prototype telescope could satisfy the requirements of the measured heavy ions in the future SPORT project and this scheme of telescope will provide a favorable technique in the future design and construction of HEHIT.     

Doping Sumanene with Both Chalcogens and Phosphorus(V): One‐Step Synthesis,Coordination, and Selective Response Toward AgI

Heterasumanenes 4 – 6 containing chalcogen (S, Se, and Te) and phosphorus atoms have been synthesized in a one‐pot reaction from trichalcogenasumanenes 1 – 3 by replacing one chalcogen atom with a P=S unit. The P=S unit makes 4 – 6 almost planar and shrinks the HOMO–LUMO gap as compared to 1 – 3 . The bonding between Ag⁺ and S atom on P=S brings about a distinct change to the optical properties of 4 – 6 ; 4 in particular shows a selective fluorescence response toward Ag⁺ with LOD of 0.21 μm . Compounds 4 – 6 form complexes with AgNO₃ to be ( 4 )₂?AgNO₃, ( 5 )₂?AgNO₃, and ( 6 )₂?(AgNO₃)₃. In complexes, the coordination between Ag⁺ and P=S is observed, which leads to shrinkage of C?P and C?X (X=S, Se, Te) bond lengths. As a result, 4 , 5 , and 6 are all bowl‐shaped in complexes with bowl‐depths reaching to 0.66 Å, 0.42 Å, and 0.40 Å, respectively. There are Ag?Te dative bonds between Ag⁺ and Te atom on telluorophene in ( 6 )₂?(AgNO₃)₃.     

磷钨杂多酸类离子液体催化环戊烯选择性氧化制备戊二醛

以H_2O_2为氧化剂,将一系列磷钨杂多酸类离子液体用于催化环戊烯(CPE)选择性氧化制备戊二醛(GA)反应,筛选出催化活性最高的催化剂为[π-C_5H_5NC_(16)H_(33)]_3PW_4O_(16).分别探讨了溶剂种类、用量、催化剂用量、H_2O_2用量、反应温度和反应时间等因素对反应的影响.确定了优化的反应条件:5 mL乙酸乙酯,n(Cat.)∶n(H_2O_2)∶n(CPE)=0.03∶50∶33,35℃,18 h,环戊烯的转化率达100%,戊二醛的选择性达87%.催化剂[π-C_5H_5NC_(16)H_(33)]_3PW_4O_(16)循环使用7次后,戊二醛的选择性仍保持在80%以上.     

The selective hydrogenation of rosin to hydroabietic content using Pd/SBA-15 as catalysts

Research on Chemical Intermediates - Well-dispersed Pd particles supported on ordered mesoporous SBA-15 were synthesized by the incipient wetness impregnation of SBA-15 with PdCl2 as precursor. The...     

Preparation of trimetallic electrocatalysts by one-step co-electrodeposition and efficient CO2 reduction to ethylene

Use of multi-metallic catalysts to enhance reactions is an interesting research area, which has attracted much attention. In this work, we carried out the first work to prepare trimetallic electrocatalysts by a one-step co-electrodeposition process. A series of Cu–X–Y (X and Y denote different metals) catalysts were fabricated using this method. It was found that Cu₁₀La₁Cs₁ (the content ratio of Cu²⁺, La³⁺, and Cs⁺ in the electrolyte is 10 : 1 : 1 in the deposition process), which had an elemental composition of Cu₁₀La_0.16Cs_0.14 in the catalyst, formed a composite structure on three dimensional (3D) carbon paper (CP), which showed outstanding performance for CO₂ electroreduction reaction (CO₂RR) to produce ethylene (C₂H₄). The faradaic efficiency (FE) of C₂H₄ could reach 56.9% with a current density of 37.4 mA cm⁻² in an H-type cell, and the partial current density of C₂H₄ was among the highest ones up to date, including those over the catalysts consisting of Cu and noble metals. Moreover, the FE of C₂₊ products (C₂H₄, ethanol, and propanol) over the Cu₁₀La₁Cs₁ catalyst in a flow cell reached 70.5% with a high current density of 486 mA cm⁻². Experimental and theoretical studies suggested that the doping of La and Cs into Cu could efficiently enhance the reaction efficiency via a combination of different effects, such as defects, change of electronic structure, and enhanced charge transfer rate. This work provides a simple method to prepare multi-metallic catalysts and demonstrates a successful example for highly efficient CO₂RR using non-noble metals.

Trimetallic Cu₁₀La₁Cs₁ catalysts prepared via a one-step co-electrodeposition strategy can act as a robust electrocatalyst for CO₂RR to C₂H₄.     

Saddle-Shaped Building Blocks: A New Concept for Designing Fully Conjugated 3D Organic Semiconducting Materials

Currently, most organic semiconducting materials (OSMs) are π-conjugated structures in one or two dimension (2D), where the lack of layer-layer π-conjugation connection greatly blocks their electron delocalization and transport. The 3D fully conjugated materials could solve this issue because they can provide efficient charge-transport pathways throughout the whole 3D skeleton, in which the suitable 3D building block is the key to the development of fully conjugated 3D OSMs. Cyclooctatetraene (COT) and its derivatives are good candidates due to their π-conjugation with 3D saddle-shaped architecture. In this Concept, we discuss the key features of saddle-shaped COT-based derivatives and their synthetic strategy, then we present the current development of using the COT derivatives as building blocks to construct the 3D fully conjugated organic small compound- and polymer-based OSMs. The properties and perspectives of these OSMs in photovoltaics, electro-catalysis and electrical conductivities are also discussed. These recent advances in the developing 3D fully conjugated materials could potentially open up a new frontier in the design of OSMs.     

Synthesis and rheological property of various modified nano-SiO2/AM/AA hyperbranched polymers for oil displacement

Russian Journal of Applied Chemistry - In this study, various modified nano-SiO2 functional monomers (nano-SiO2-KH540-MAH) were prepared and reacted with acrylamide (AM) and acrylate (AA) to...     

Brnsted-Lewis有机-无机杂多酸催化模拟催化裂化汽油的烷基化脱硫反应

合成了一系列Brnsted-Lewis双酸性有机-无机杂多酸,并将其应用于催化模拟催化裂化(FCC)汽油的烷基化脱硫反应中.筛选出脱硫效果最佳的催化剂为Sm_(0.33)[MIM-PS]HPW_(12)O_(40),考察了该催化剂用量、反应温度及反应时间等因素对模拟油中噻吩类硫化物转化率的影响.获得的最佳反应条件为剂/油质量比1∶50、反应温度125℃及反应时间1 h.在最佳反应条件下,3种硫化物噻吩(T)、2-甲基噻吩(2-MT)和3-甲基噻吩(3-MT)均几乎完全转化,即脱硫率都接近100%.催化剂Sm_(0.33)[MIM-PS]HPW_(12)O_(40)具有良好的循环使用性能,循环使用12次,其催化活性基本保持不变.     

Synthesis of Nipagin Esters Using Acidic Functional Ionic Liquids as Catalysts

Several Brønsted acidic functional ionic liquids (FILs) with an alkane sulfonic acid group were synthesized. These FILs as dual solvent-catalysts for Nipagin esterification reactions were investigated. The results indicated that [HSO₃-pMIM]HSO₄ has the best catalytic activity and recyclability among the various kinds of FILs investigated, and its structure was characterized by infrared and NMR. The [HSO₃-pMIM]HSO₄ could be easily separated from the reaction mixture and reused without noticeably decreasing the catalytic activity.