高功率激光装置中鬼像的模拟-应用实际光线追迹法

高功率固体激光装置中正常光束的残余反射将形成能量较大的鬼点,它们极易对元器件造成损害,因此对一阶及多阶鬼点的位置作定量分析对高功率激光系统设计是非常必要的。采用将近轴分析与实际光线追迹相结合的分析方法,对神光Ⅲ原型装置进行了一套完整的杂散光分析。首先在近轴条件下对系统中可能产生的一阶至多阶鬼点进行了全面的计算和定位,列出其来源和鬼点较集中的区域,如普克尔盒一个窗口的前表面附近鬼点能量比较集中,然后通过大量的实际光线追迹对这些元件进行重点考察,模拟其表面的能量分布,为如何减小鬼点数目,从而避免鬼点能量造成的损伤提供了详尽的数据参考。     

PVA‐encapsulated Palladium Nanoparticles: Eco‐friendly and Highly Selective Catalyst for Hydrogenation of Nitrobenzene in Aqueous Medium

In aqueous medium without any other additives, palladium (Pd) nanoparticles with water‐soluble polyvinyl alcohol (PVA) as stabilizer were synthesized for the catalytic hydrogenation of nitrobenzene. Under the optimum experimental conditions, the nitrobenzene conversion and the selectivity for aniline were 99.3 % and 100 %, respectively. Comprehensive characterization methods, including TEM, UV/Vis, confocal laser scanning microscopy (CLSM), XRD and XPS allowed a better understanding of the role of PVA aggregates and the properties of Pd nanoparticles. The nitrobenzene conversion exceeded 80 % even after 6 cycles without any treatment of the catalyst. A mechanism about the hydrogenation of nitrobenzene catalyzed by Pd/PVA system was proposed. The Pd/PVA catalyst also exhibited excellent activity and selectivity, particularly to ortho‐fluoronitrobenzene and ortho‐nitrotoluene. This research can provide a reference for the environmentally friendly catalysis for hydrogenation of nitrobenzene and other substituted nitrobenzene compounds.     

HIRFL-CSR ETF多层CsI(Tl)望远镜探测器能量刻度方法

在兰州重离子加速器冷却储存环（HIRFL-CSR）的外靶终端（ETF）,设计建造了一套多层CsI（Tl）望远镜探测器,用于对轻质量带电粒子的鉴别。这套探测器由7层CsI（Tl）晶体组成,每一层晶体光输出信号由4个光电倍增管分别在晶体4角读出。由于CsI（Tl）晶体对于重离子的响应是非线性的,且与入射离子的种类有关,这些因素使得对这台探测器的能量刻度需要做专门的研究。利用RIBLL2提供的能量在200 s~300 MeV/u的次级束流对探测器进行了测试,并针对第一片CsI（Tl）晶体的光输出以及所有CsI（Tl）晶体光输出的和的刻度方法分别进行了探索。在此能区下,第一片CsI（Tl）晶体猝灭现象可以近似忽略,即光输出与能量沉积近似呈线性。对于所有晶体光输出的和,利用一个经验公式对其进行刻度,利用这种刻度方法计算得到的光输出的值与实验测量值之间的差别小于5%。A multi-layer CsI(Tl) telescope has been designed and constructed at External Target in Facility (ETF) terminal of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou(HIRFL-CSR), and is used for identifying light charged particles. The detector consists of seven layers of CsI(Tl) crystals, and the signals of each crystal are read out by four photomultipliers at the corners. Since the response of the CsI(Tl) crystal to the heavy ions is non-linear and also depends on the species of the incident ions, the energy calibration method of the telescope must be carefully studied. With the help of the secondary beams selected by RIBLL2 in the energy ranges from 200 to 300 MeV/u, the telescope has been tested and the energy calibration method for the first-layer crystal together with the whole telescope has been investigated. In this energy region, the quench effect in the first-layer crystal can be neglected and a linear expression can be used to represent the relation between the light output and the energy deposition in the crystal. To the total light output of the telescope, an empirical formula is used for the energy calibration. The difference between the calculated results and the experiment data is globally less than 5%.     

A tellura-Baeyer–Villiger oxidation: one-step transformation of tellurophene into chiral tellurinate lactone

Baeyer–Villiger (BV) oxidation is a fundamental organic reaction, whereas the hetero-BV oxidation is uncharted. Herein, a tellura-BV oxidation is discovered. By oxidizing a tellurophene-embedded and electron-rich polycycle (1) with mCPBA or Oxone, an oxygen atom is inserted into the Te–C bond of the tellurophene to form tellurinate lactone mono-2. This reaction proceeds as follows: (i) 1 is oxidized to the tellurophene Te-oxide form (IM-1); (ii) IM-1 undergoes tellura-BV oxidation to give mono-2. Moreover, the hybrid trichalcogenasumanenes 7 and 8 are, respectively, converted to tellurinate lactones mono-9 and mono-10 under the same conditions, indicating that tellura-BV oxidation shows high chemoselectivity. Due to the strong secondary bonding interactions between the Te O groups on tellurinate lactones, mono-2, mono-9, and mono-10 are dimerized to form U-shaped polycycles 2, 9, and 10, respectively. Notably, mono-2, mono-9, mono-10, and their dimers show chirality. This work enables one-step transformation of tellurophene into tellurinate lactone and construction of intricate polycycles.

A tellura-Baeyer–Villiger oxidation is discovered, which enables one-step transformation of tellurophene into chiral tellurinate lactones. The resulting tellurinate lactones are dimerized in the solid state to form U-shaped polycycles.     

Heterogeneous CaO(SrO,BaO)/MCF as highly active and recyclable catalysts for the glycolysis of poly(ethylene terephthalate)

Research on Chemical Intermediates - A new group of basic species, CaO(SrO and BaO), supported on mesocellular siliceous foam (MCF) has been prepared and used for catalyzing glycolysis of...     

One-step synthesis of porous palladium nanostructures by H2+He arc plasma method

Porous palladium nanostructures were prepared on a copper sheet previously fixed over the plasma high-temperature area by H₂+He arc plasma method. However, dispersed palladium nanoparticles with diameters in 50–90 nm were obtained on the inner wall of vacuum chamber. SEM, TEM, EDXA, XRD and BET were employed to characterize the palladium porous materials. SEM images show that porous palladium nanostructures are composed of spherical particles with diameters of 35 ± 3 nm. This special structure with large surface to volume ratio can be recycled easily for application in the field of catalysis.     

From C1 to C3: Copper‐Catalyzed gem‐Bis(trifluoromethyl)olefination of α‐Diazo Esters with TMSCF3

A Cu‐catalyzed gem‐bis(trifluoromethyl)olefination of α‐diazo esters, using TMSCF₃ as the only fluorocarbon source, has been developed and provides an exquisite method to access gem‐bis(trifluoromethyl)alkenes. This unprecedented olefination process involves a carbene migratory insertion into “CuCF₃” to generate the α‐CF₃‐substituted organocopper species, which then undergoes β‐fluoride elimination and two consecutive addition‐elimination processes to give the desired products. The key to this efficient one‐pot C₁‐to‐C₃ synthetic protocol lies in the controllable double (over single and triple) trifluoromethylations of the gem‐difluoroalkene intermediates.     

Recovering of Damping Coefficients for a System of Coupled Wave Equations with Neumann Boundary Conditions: Uniqueness and Stability

The authors study the inverse problem of recovering damping coefficients for two coupled hyperbolic PDEs with Neumann boundary conditions by means of an additional measurement of Dirichlet boundary traces of the two solutions on a suitable, explicit subportion Γ1 of the boundary Γ, and over a computable time interval T > 0. Under sharp conditions on Γ0 = ΓnΓ1, T > 0, the uniqueness and stability of the damping coefficients are established. The proof uses critically the Carleman estimate due to Lasiecka et al. in 2000, together with a convenient tactical route “post-Carleman estimates” suggested by Isakov in 2006.     

Asymptotic behavior of a stochastic virus dynamics model with intracellular delay and humoral immunity

In this paper, we formulate a stochastic virus dynamics model with intracellular delay and humoral immunity. By constructing some suitable Lyapunov functions, we show that the solution of stochastic model is going around each of the steady states of the corresponding deterministic model under some conditions. Then, numerical simulations are given to support the theoretical results. Finally, we propose several more effective way to control the spread of the virus by analyzing the sensitivity of the threshold of spread.