High-throughput screening of ferroelectric materials for non-volatile random access memory using multilayer perceptrons

During the last several years, the development of combinatorial technology has enabled synthesis of a huge amount of chemical compounds in a short time. The large number of variables makes the direct human interpretation of data derived from combinatorial experimentation for high-throughput screening (HTS) very difficult. Artificial neural networks using multilayer perceptrons (MLP) have been successfully applied to the regression problems with various material data. In this work, MLP model was applied to HTS of ferroelectric materials including Bi_4−xLa_xTi₃O₁₂ (BLT) and Bi_4−xCe_xTi₃O₁₂ (BCT). The model using MLP was made to predict the ferroelectric properties of whole feasible experimental conditions. Once a neural network model with high accuracy and good generalization performance was established, we could predict the expected optimal reaction conditions with the best characteristics. The highest gradient value obtained using MLP model is higher than the maximum value found from experiments, thereby accelerating the discovery of the optimal compositions and post-annealing time of BCT and BLT.     

单层介质膜保偏全反射直角三棱镜镀膜材料的选择及其微分相位特性研究

入射角、基底玻璃折射率、膜介质折射率、膜厚等因素会影响单层介质膜保偏全反射直角三棱镜的保偏特性，且各因素的影响程度并不相同。本文分析了上述各因素的微小变化对保偏特性的影响，并提出了选择膜介质的方法     

Solution synthesis of ZnO nanotubes via a template-free hydrothermal route

ZnO nanotubes were successfully synthesized by a simple template-free hydrothermal method. X-ray powder diffraction and transmission electron microscopy were used to characterize the as-prepared ZnO nanotubes. The average size of the nanotubes is 200-500 nm in length and 20-30 nm in diameter. In addition, a further investigation of the optimized synthetic conditions has been carried out.     

Superconducting energy gap distribution in c-axis oriented MgB2 thin film from point contact study

We have analyzed about a hundred voltage-dependent differential resistance dV/dI(V) curves of metallic point contacts between c-axis-oriented MgB₂ thin film and Ag, which exhibit clear Andreev reflection features connected with the superconducting gap. About one half of the curves show the presence of a second larger gap. The histogram of the double gap distribution reveals distinct maxima at 2.4 and 7 meV, while curves with single-gap features result in a more broad maximum at 3.5 meV. The double-gap distribution is in qualitative agreement with the distribution of gap values over the Fermi surface calculated by H. J. Choi et al. (cond-mat/0111183). The data unequivocally show the presence of two gaps: Δ_S=2.45±0.15 meV and Δ_L=7.0±0.45 meV in MgB₂ with the gap ratio Δ_L/Δ_S=2.85±0.15. Our observations further prove a widely discussed multigap scenario for MgB₂, where two distinct gaps are seen in the clean limit, while a single averaged gap is present in the dirty one.     

微量元素锌和铁与溃疡性结肠炎关系的探讨

测定了溃疡性结肠炎患者血清、头发中锌和铁含量，结果表明，其含量均明显低于正常对照组，并有显著性差异，提示锌和铁的测定可作为误差溃疡性结肠炎的参考指标之一，还提出适当补充锌与铁制剂是治疗溃疡性结肠炎的辅助手段。     

Restructuring risk in credit default swaps: An empirical analysis

This paper estimates the price for restructuring risk in the US corporate bond market during 1999–2005. Comparing quotes from default swap (CDS) contracts with a restructuring event and without, we find that the average premium for restructuring risk represents 6%–8% of the swap rate without restructuring. We show that the restructuring premium depends on firm-specific balance-sheet and macroeconomic variables. And, when default swap rates without a restructuring event increase, the increase in restructuring premia is higher for low-credit-quality firms than for high-credit-quality firms. We propose a reduced-form arbitrage-free model for pricing default swaps that explicitly incorporates the distinction between restructuring and default events. A case study illustrating the model’s implementation is provided.     

Search for collective transverse flow using particle transverse momentum spectra in relativistic heavy-ion collisions

The particle transverse momentum spectra recently measured in relativistic heavy-ion collisions at CERN and BNL are analysed within an expanding fireball model. All the particle spectra at a given beam energy can be reproduced simultaneously with a single set of intensive parameters for the initial state of the fireball. As typical freeze-out parameters in this beam energy region we find a freeze-out temperatureT _f?110 MeV for most hadrons, and an average transverse expansion velocity at freeze-out of 〈v/c〉?0.4–0.45. The striking enhancement at transverse momentap _T<200 MeV/c in the CERN pion data cannot be fully explained by the existence of transverse flow.     

Study on hypochlorite degradation of aromatic polyamide reverse osmosis membrane

A serious limitation of most commercial polyamide reverse osmosis (RO) membranes is their sensitivity to chlorine attack. By studying the hypochlorite degradation of aromatic polyamide RO membrane, this work was to get some understandings in the prevention of membrane depreciation and develop membranes with improved chlorine resistance. Membrane performances, including water flux and salt rejection, were evaluated before and after hypochlorite exposure under different pH and concentration conditions. The results showed that chlorination destroyed hydrogen bonds in polyamide chains, causing a notable decline of membrane flux especially in acid environment; however, membrane performance was slightly improved after the treatment of alkaline hypochlorite solution for a certain time, which was probably due to the effect of amine groups in barrier layer. Based on the attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) characterizations and performance measurements, the results indicated that N-chlorination reaction of aromatic polyamide was also reversible, in other words, the N-chlorinated intermediate could be regenerated to initial amide with the alkaline treatment before ring-chlorination reaction. This conclusion provided several relative suggestions for membrane cleaning procedures. Finally, a method adopting surface coating was proposed to develop membranes with good chlorine resistance, and the preliminary results showed its potential for applications.     

A Mild and Efficient Synthesis of Chiral N-Boc-α-aminoaldehydes

N-Boc-α-aminoaldehydes, represented by Boc-L-leucinal and its congener Boc-L- phenylalaninal, have received considerable attention in the past four decades1. This interest mainly stems from their wide application as important synthons in the preparation …     

(–)‐α‐Isosparteine copper(II) diazide

In the title complex, [Cu(N₃)₂(C₁₅H₂₆N₂)], the Cu atom is surrounded by the two N atoms of the chelating (?)‐α‐isosparteine ligand and another two N atoms from the two azide anions, forming a distorted CuN₄ tetrahedron. The two azide anions are terminally bound to the Cu^II atom, and the dihedral angle between the N_sparteine—Cu—N_sparteine and N_azide—Cu—N_azide planes is 50.0 (2)°.