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排序方式: 共有1339条查询结果,搜索用时 62 毫秒
941.
Hideaki Takayanagi Hirotaka Tanaka Shiro Saito Hayato Nakano 《Superlattices and Microstructures》2002,32(4-6)
The states of a flux qubit with three Josephson junctions were observed with a dc-SQUID. The qubit is an aluminium superconductor loop surrounded by a dc-SQUID for readout. It has two states, which have persistent currents flowing in opposite directions. The system potentially offers the advantage of allowing single-shot/single-system measurements of macroscopic superposition of the two states. We have developed a highly sensitive, low-noise, single-shot detection system, and here we report the first direct observation of a macroscopic quantum superposition. The measured ground and the first excited state showed the same behaviour as the theoretical ones. We also showed that the measured behaviour of the switching current in a dc-SQUID was the same as that of the quantum-mechanically expected value of the switching current in the qubit. 相似文献
942.
Suzuki S Nakatsubo T Umezawa T Shimada M 《Chemical communications (Cambridge, England)》2002,(10):1088-1089
We report for the first time that an enzyme preparation from fungal-elicited Asparagus officinalis cultured cells catalyses the formation of a norlignan, (Z)-hinokiresinol, from two non-identical phenylpropanoid monomers, 4-coumaryl alcohol and 4-coumaroyl CoA, and from a dimer, 4-coumaryl 4-coumarate, without any additional cofactors. 相似文献
943.
944.
Palladium(0)-catalyzed one-atom ring expansion of various hydroxy methoxyallenyl compounds has been achieved in excellent yields without the use of aryl halides. Hydroxy methoxyallenylisoindolinones, -indanones, and -phthalans have been readily converted to the corresponding isoquinolones, naphthoquinones, and isochromanones in the presence of P(o-tolyl)(3). 相似文献
945.
Hiraoka S Yi T Shiro M Shionoya M 《Journal of the American Chemical Society》2002,124(49):14510-14511
A disk-shaped tridentate ligand 1 arranges silver(I) ions in a two-dimensional triangular and a three-dimensional tetrahedral fashion in the metal-ligand ratios, 3:2 and 1:1, respectively. The resulting sandwich-type (Ag312) and tetrahedral (Ag414) architectures are in a dynamic equilibrium in solution. 相似文献
946.
Ropke CD Meirelles RR da Silva VV Sawada TC Barros SB 《Photochemistry and photobiology》2003,78(5):436-439
In this work we evaluated the influence of topical application of P. umbellata root extract gel, containing 0.1% of 4-nerolidylcathecol, on the antioxidant network in UV-induced oxidative damage in hairless mouse skin. The UV-irradiation had no influence on ascorbic acid levels or on the antioxidant enzyme (superoxide dismutase, catalase, glutathione reductase and glutathione peroxidase) activities, but topical P. umbellata treatment protected alpha-tocopherol from being depleted after UV-irradiation. alpha-Tocopherol concentration decreased significantly (approximately 40%, P < 0.01) in the irradiated control groups, whereas in the P. umbellata-treated group, alpha-tocopherol was totally preserved (approximately 100%, P > 0.05). These data demonstrate that P. umbellata may be successfully used as a topical photoprotective agent. 相似文献
947.
Sawada T Nakamura J Nishida Y Kani K Okamoto R Morikawa S Inubushi T 《Magnetic resonance imaging》2003,21(9):1029-1031
Bovine lenses were incubated in a solution containing [1-(13)C]glucose (50 mM) for 1, 2 and 4 days. Spectroscopic images of [1-(13)C]glucose and [1-(13)C]sorbitol were constructed using (1)H-detected gradient-enhanced heteronuclear multiple-quantum coherence (GE-HMQC) in a 2.0-tesla magnetic field. Accumulations of [1-(13)C]glucose and [1-(13)C]sorbitol were mainly observed at the periphery of the lens. Their distributions corresponded to the cortex. (1)H-detected (13)C nuclear magnetic resonance (NMR) spectroscopic imaging by GE-HMQC successfully demonstrated the distribution of [1-(13)C]glucose and [1-(13)C]sorbitol at the periphery of bovine lenses. 相似文献
948.
Honma M Sawada T Fujisawa Y Utsugi M Watanabe H Umino A Matsumura T Hagihara T Takano M Nakada M 《Journal of the American Chemical Society》2003,125(10):2860-2861
This work describes the development of a highly enantioselective asymmetric catalysis on the intramolecular cyclopropanation of alpha-diazo-beta-keto sulfones. We have found that the catalytic asymmetric intramolecular reactions of alpha-diazo-beta-keto sulfones generally proceed with high enantioselectivity when the alpha-diazo-beta-keto mesityl sulfone is used with the newly prepared ligand 2e. The absolute configuration of products has been determined by X-ray crystallographic analysis, and the outcome of the enantioselectivities is explained well by our proposed models A and B. The products possess great potential for natural product synthesis because (1) many different chemistries of cyclopropane, ketone, and sulfone are available, and (2) the products are generally highly crystalline, facilitating the supplies of enantiomerically pure synthetic intermediates. 相似文献
949.
Akiya Karen Michiko Takagi Sawada Fumio Tanaka Noboru Mataga † 《Photochemistry and photobiology》1987,45(1):49-53
Abstract— Molecular mechanism of fluorescence quenching of flavins in flavodoxin from Desulfovibrio vulgaris , strain Miyazaki, and riboflavin binding protein from egg white has been investigated by means of picosecond laser photolysis technique. In the case of flavodoxin, a transient absorption band characteristic of the non-fluorescent exciplex formed by electron transfer from indole to excited flavins in model systems has been observed around 600 nm at the delay time of 33 ps from exciting ps pulse pulse width, 25 ps). In the case of riboflavin binding protein, the transient absorption spectra were different from those of flavin-indole exciplex and rather similar to the spectra of the model system of flavin-phenol. These results suggest that tryptophan residue exists near the isoalloxazine nucleus in flavodoxin, and in riboflavin binding protein, tyrosine residue exists near the flavin. Direct measurements of the ultrafast process of the electron transfer in flavoproteins as developed here could provide useful information for elucidating protein dynamics, associated with redox reaction, in the picosecond time region. 相似文献
950.
Shigeru Maeda Hiroshi Wada Kosuke Kumeda Miyuki Onoue Akira Ohki Shiro Higashi Toshio Takeshita 《应用有机金属化学》1987,1(5):465-472
Five arsenic-resistant freshwater algae which had been isolated from an arsenic-polluted environment were studied for the biotransformation of arsenic compounds accumulated by them from the aqueous phase. The algal cells bioaccumulating arsenic were digested by 2 mol dm?3 NaOH at 95°C, the As? C bonds except for As? CH3 were cleaved by the treatment and the methylated arsenic compounds were reduced to the corresponding arsines by sodium borohydride (hydride generation). The arsines were chromatographically separated on the basis of their boiling-point difference and determined by atomic absorption spectrophotometry. Methylated arsenic compounds were found in all algal cells. The predominant arsenic species in the cells, however, were non-methylated arsenic compounds which were mainly present in the residue of a chloroform–methanol extract. The non-methylated arsenic compounds were found to be not present in the free inorganic arsenic substrate and to be bound strongly with proteins or polysaccharides in the cells. Methylated arsenic compounds were found mainly in the lipid-soluble fractions and the major form was a dimethylarsenic compound. Trimethyl- and monomethyl-arsenic compounds were detected but at very low level. The dimethylarsinic acid was not present in the free form in the lipid-soluble fraction and should be bound with a lipid molecule. It was also found that the accumulation of arsenic by Nostoc occurred only in living cells. 相似文献